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ON THE SIGNIFICANCE OF NATURAL CARBONATES IN THE PROCESSES OF SYNTHESIS AND GENESIS OF HYDROCARBONS IN THE EARTH’S LITHOSPHERE

Home > Archive > No. 3–4 (191–192) 2023 > 135–142

Geology & Geochemistry of Combustible Minerals No. 3–4 (191–192) 2023, 135–142

https://doi.org/10.15407/ggcm2023.191-192.135

Josyp SVOREN’

Institute of Geology and Geochemistry of Combustible Minerals of National Academy of Sciences of Ukraine, Lviv, Ukraine, e-mail: igggk@mail.lviv.ua

Abstract

The fundamental importance of studies of the processes of synthesis and genesis of hydrocarbons in the Earth’s lithosphere has been confirmed and the prospects of the chosen direction for advanced research have been demonstrated, as well as for the thorough development of genetic principles of physical and chemical conditions of the formation of hydrocarbons deposits in various geological minds, focusing on the role of natural carbonate formation in this process. It is shown in this connection that one of the most striking natural phenomena of the Earth’s lithosphere is the obvious manifestations of veinlet-impregnated carbonate mineralization. This has been discussed in detail in the case of some areas of the Ukrainian Carpathians and Pre-Сarpathians, where the original carbonate veinlets of hydrothermal origin with traces of hydrocarbons migration are often happened, but industrial research works is rarely carried out because of their low (as expected) prospects for gas and oil deposits. We pay attention to the areas of development of the calcite veinlets with rare, perfectly faceted crystals of quartz – “Marmarosh diamonds” among the Cretaceous and Paleogene deposits of the South-Western slope of the Carpathians.

As a result, supporting materials on the importance of natural carbonates in the processes of synthesis and genesis of hydrocarbons in the Earth’s lithosphere are given. It consists in the revealed previously unknown property of natural carbonates, mainly calcium carbonate, under the action of abiogenic high-thermobaric deep fluid to decompose and be an additional source of carbon with different isotopic compositions in the processes of synthesis and genesis of hydrocarbons: gas, oil, bitumen as well as a carrier of these compounds in time of their migration and conservation in new creations in the deposits of oil and gas-bearing areas and metallogenic provinces: deposits-fields, veins, fluid inclusions, veinlet-impregnated mineralization.

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Keywords

fluid inclusions, carbonates, veins, hydrocarbons, deposits, gas and oil, mass spectrometric studies, supposed scientific discovery

Referenses

Biletskyi, V. C. (Red.). (2004). Mala hirnycha entsyklopediia: Vol. 1. A–K. Donetsk: Donbas. [in Ukrainian]

Bratus, M. D., Davydenko, M. M., Zinchuk, I. M., Kaliuzhnyi, V. A., Matviienko, O. D., Naumko, I. M., Pirozhyk, N. E., Redko, L. R., & Svoren, Y. M. (1994). Fliuidnyi rezhym mineraloutvorennia v litosferi (v zviazku z prohnozuvanniam korysnykh kopalyn). Kyiv: Naukova dumka. [in Ukrainian]

Lazarenko, Ye. K., & Vynar, O. M. (1975). Mineralohichnyi slovnyk. Kyiv: Naukova dumka. [in Ukrainian]

Matkovskyi, O. I. (Hol. red.). (2003). Mineraly Ukrainskykh Karpat. Boraty, arsenaty, fosfaty, molibdaty, sulfaty, karbonaty, orhanichni mineraly i mineraloidy. Lviv: Vydavnychyi tsentr LNU im. Ivana Franka. [in Ukrainian]

Matkovskyi, O., Naumko, I., Pav lun, M., & Slyvko, Ye. (2021). Termobaroheokhimiia v Ukraini. Lviv: Prostir-M. [in Ukrainian]

Naumko, I. M. (2006). Fliuidnyi rezhym mineralohenezu porodno-rudnykh kompleksiv Ukrainy (za vkliuchenniamy u mineralakh typovykh parahenezysiv) [Extended abstract of Doctorʼs thesis, Institute of Geology and Geochemistry of Combustible Minerals of National Academy of Sciences of Ukraine]. Lviv. [in Ukrainian]

Naumko I., Bratus M., Dudok I., Kaliuzhnyi V., Kovalyshyn Z., Sakhno B., Svoren Y., & Telepko L. (2004). Fliuidnyi rezhym katahenno-hidrotermalnoho protsesu periodu formuvannia zhylnoi, prozhylkovoi i prozhylkovo-vkraplenoi mineralizatsii v osadovykh tovshchakh. In V. V. Kolodii (Ed.), Karpatska naftohazonosna provintsiia (pp. 308–345). Lviv; Kyiv: Ukrainskyi vydavnychyi tsentr. [in Ukrainian]

Naumko, I. M., & Svoren, Y. M. (2008). Pro shliakhy vtilennia hlybynnoho vysokotemperaturnoho fliuidu v zemnu koru. Dopovidi NAN Ukrainy, 9, 112–114. [in Ukrainian]

Svoren, I. M. (1984). Primesi gazov v kristallakh mineralov i drugikh tverdykh telakh, ikh sposoby izvlecheniya, sostav, forma nakhozhdeniya i vliyaniye na svoystva veshchestv [Extended abstract of Candidateʼs thesis. Institute of Geology and Geochemistry of Combustible Minerals of National Academy of Sciences of Ukraine]. Lvov. [in Russian]

Svoren, I. M. (1988). Formy nakhozhdeniya vodoroda v nekotorykh tverdykh materialakh razlichnogo proiskhozhdeniya soglasno fiziko-khimicheskoy modeli navodorozhivaniya tverdykh tel. In Geokhimiya i termobarometriya endogennykh flyuidov (pp. 95–103). Kiev: Naukova dumka. [in Russian]

Svoren, Y. M. (1992). Pytannia teorii henezysu pryrodnykh vuhlevodniv ta shliakhy poshuku yikh pokladiv. In Tektohenez i naftohazonosnist nadr Ukrainy (pp. 143–145). Lviv. [in Ukrainian]

Svoren, Y. (2020a). Nadra Zemli – pryrodnyi fizyko-khimichnyi reaktor: pryroda vody naftovykh i hazovykh rodovyshch. In Naftohazova haluz: Perspektyvy naroshchuvannia resursnoi bazy: materialy dopovidei Mizhnarodnoi naukovo-tekhnichnoi konferentsii (Ivano-Frankivsk, 8–9 hrudnia 2020 r.) (pp. 158–160). Ivano-Frankivsk: IFNTUNH. [in Ukrainian]

Svoren, J. M. (2020b). Various Chemical Properties of Carbon Isotopes in Natural Synthesis of Different Compounds. Journal of Geological Resource and Engineering, 8, 20–23. https://doi.org/10.17265/2328-2193/2020.01.002

Svoren, Y. M., & Davydenko, M. M. (1995). Termobarometriia i heokhimiia haziv prozhylkovo-vkraplenoi mineralizatsii u vidkladakh naftohazonosnykh oblastei i metalohenichnykh provintsii. Dopovidi NAN Ukrainy, 9, 72–73. [in Ukrainian]

Svoren, Y. M., Davydenko, M. M., Haievskyi, V. H., Krupskyi, Yu. Z., & Pelypchak, B. P. (1994). Perspektyvy termobarometrii i heokhimii haziv prozhylkovo-vkraplenoi mineralizatsii u vidkladakh naftohazonosnykh oblastei i metalohenichnykh provintsii. Heolohiia i heokhimiia horiuchykh kopalyn, 3–4(88–89), 54–63. [in Ukrainian]

Svoren, Y. M., & Naumko, I. M. (2003). Nova teoriia syntezu i henezysu vuhlevodniv u litosferi Zemli: abiohenno-biohennyi dualizm. In Mezhdunarodnaya konferentsiya “Krym–2003” (pp. 75–77). Simferopol. [in Ukrainian]

Svoren, Y., & Naumko, I. (2004). Termobarometriia i heokhimiia haziv prozhylkovo-vkraplenoi mineralizatsii u vidkladakh naftohazonosnykh oblastei i metalohenichnykh provintsii: henezys i syntez prozhylkovykh karbonatnykh porid. In Mineralohiia: istoriia, teoriia i praktyka: tezy dopovidei Mizhnarodnoi naukovoi konferentsii, prysviachenoi 140-richchiu kafedry mineralohii Lvivskoho natsionalnoho universytetu imeni Ivana Franka (Lviv–Shatsk, 3–6 veresnia 2004 r.) (pp. 63–65). Lviv: Vydavnychyi tsentr LNU imeni Ivana Franka. [in Ukrainian]

Svoren, Y. M., & Naumko, I. M. (2005). Termobarometriia i heokhimiia haziv prozhylkovo-vkraplenoi mineralizatsii u vidkladakh naftohazonosnykh oblastei i metalohenichnykh provintsii – pryrodnyi fenomen litosfery Zemli. Dopovidi NAN Ukrainy, 2, 109–113. [in Ukrainian]

Svoren, Y. M., & Naumko, I. M. (2006). Nova teoriia syntezu i henezysu pryrodnykh vuhlevodniv: abiohenno-biohennyi dualizm. Dopovidi NAN Ukrainy, 2, 111–116. [in Ukrainian]

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DISTRIBUTION AND ORIGIN OF HYDROCARBON GASES IN COAL-BEARING DEPOSITS OF THE LVIV-VOLYN COAL BASIN

Home > Archive > No. 3-4 (172-173) 2017 > 87-105

Geology & Geochemistry of Combustible Minerals No. 1-2 (174-175) 2018, 87-105.

Mykhailo MATROFAILO, Iryna BUCHYNSKA, Andriy POBEREZHSKYY

Institute of Geology and Geochemistry of Combustible Minerals of National Academy of Sciences of Ukraine, Lviv, e-mail:igggk@mail.lviv.ua

Abstract

After sufficient study, generalizations of all the data available as to stratigraphy, tectonics, lithological composition of coal-bearing series of the basin from the point of view of its potential for gas presence was possible. The composition, nature of coal gases, forms of occurrence and the mode of their burial have been considered. Problems of generation of hydrocarbon gases in the process of coalification of organic substance and their abiogenic origin connected with subsurface processes of the Earth have been studied. The influence of reservoir properties of coal and coal-enclosing rocks, the composition and physical-mechanical features of the immediate roof and the foot of coal seams have been analysed, the dependence of the gas distribution in coal seams and coal-enclosing rocks upon disjunctive tectonic dislocations has been ascertained. The influence of intraformational and epigene washouts upon degassing of coal seams has been investigated. On the basis of construction of schemes of the gas presence in coal seams of some mine fields and on the whole basin the conclusions have been made about the methane distribution in coal-bearing series.
Materials on the assessment of methane resources of the gas-coal fields have been accumulated and systematized as well as the prospects of the modern natural gas presence in coal seams of the deep levels of the basin have been outlined. Optimum conditions of the formation of hydrocarbon gases accumulations have been cited. The conclusions have been made as to the modern extractive potential of gases of coal-bearing series of the Lviv-Volyn Basin as possible source of the improvement of the up-to-date state of the fuel-power complex of the Ukraine.

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Keywords

methane, gas presence, generation, migration, deposits, coal seam, gas-coal fields, resources, Lviv-Volyn coal basin.

Referenses

Bagrintseva, K. I., Vasil’ev, V. G., & Ermakov, V. I. (1968). Rol’ uglenosnykh tolshch v protsessakh generatsii prirodnogo gaza. Geologiya nefti i gaza, 6, 7–11. [in Russian]

Bartoshinskaya, E. S., & Byk, S. I. (1989). Vzaimosvyaz’ mekhanicheskogo sostoyaniya veshchestva ugol’nogo plasta i ego gazonasyshchennosti. In Problemy geologii i geokhimii goryuchikh iskopaemykh: tezisy dokladov Respublikanskoi konferentsii (p. 20). L’vov. [in Russian]

Bartoshinskaya, E. S., Byk, S. I., Muromtseva, A. A. et al. (1983). Uglenosnye formatsii karbona yugo-zapadnoi okrainy Vostochno-Evropeiskoi platformy. Kiev: Naukova dumka. [in Russian]

Bartoshynska, Ye. S., & Buchynska, I. V. (2003). Zonalne rozmishchennia haziv u vuhilnykh pokladakh za danymy vuhlepetrohrafichnykh i litoloho-fatsialnykh doslidzhen. Zbirnyk naukovykh prats Natsionalnoho hirnychoho universytetu, 7 (1), 515–519. [in Ukrainian]

Bartoshynska, Ye. S., & Byk, S. I. (2000). Evoliutsiia orhanichnoi rechovyny u metamorfichnomu riadi vuhillia (porohy vuhlefikatsii). In Suchasni problemy litolohii: materialy naukovoi konferentsii, prysviachenoi 100-richchiu vid dnia narodzhennia D. P. Bobrovnyka (Lviv, 20–22 hrudnia 2000 r.) (pp. 4–5). Lviv: Vydavnychyi tsentr LNU im. I. Franka. [in Ukrainian]

Bartoshynska, Ye. S., & Matrofailo, M. M., Byk, S. I. (2011). Metan u vidkladakh Lvivskoho paleozoiskoho prohynu. Heoloh Ukrainy, 2 (34), 20–23. [in Ukrainian]

Bartoshynska, Ye. S., Uziiuk, V. I., Byk, S. I., & Ilchyshyn, A. V. (2002). Rol henetychnykh faktoriv u formuvanni hazonosnosti vuhilnykh pokladiv. Heolohiia i heokhimiia horiuchykh kopalyn, 4, 46–50. [in Ukrainian]

Boiko, G. Yu., Kozachok, V. I., & Gaivanovich, O. P. (1975). Sostav, klassifikatsiya i genezis gazov litosfery. In Referaty nauchno-issledovatel’skikh rabot IGGGI AN USSR (1973 g.) (pp. 65–68). Kiev. [in Russian]

Buchynska, I., Shevchuk, O., & Kruhlova, R. (2007). Porystist pishchanykh porid vuhlevmisnoi tovshchi na prykladi Tiahlivskoho rodovyshcha Lvivsko-Volynskoho baseinu. Heolohiia i heokhimiia horiuchykh kopalyn, 4, 45–49. [in Ukrainian]

Buchynska, I. V., & Yavnyi, P. M. (2012). Metanonosnist vuhlenosnoi tovshchi Lvivsko-Volynskoho baseinu. Heolohiia i heokhimiia horiuchykh kopalyn, 3–4, 17–28. [in Ukrainian]

Buchynska, I. V., Yavnyi, P. M., Knysh, I. B., & Shevchuk, O. M. (2011). Vuhlenosnist i rozpodil vuhilnykh haziv u rozrizi nyzhnoho karbonu Liubelskoho rodovyshcha Lvivsko-Volynskoho baseinu. Heolohiia i heokhimiia horiuchykh kopalyn, 3–4, 57–67. [in Ukrainian]

Byk, S. I., Buchynska, I. V., Yavnyi, P. M., & Knysh, I. B. (2009). Metanonosnist polia shakhty “Stepova” Lvivsko-Volynskoho baseinu. Heoloh Ukrainy, 3, 23–26. [in Ukrainian]

Dolenko, G. N. (1978). Sovremennoe sostoyanie problemy proiskhozhdeniya nefti i gaza i zakonomernostei obrazovaniya i razmeshcheniya ikh zalezhei. In Proiskhozhdenie i migratsiya nefti i gaza (pp. 3–14). Kiev: Naukova dumka. [in Russian]

Dolenko, G. N., Boichevskaya, L. T., Galabuda, N. I. et al. (1984). Geologicheskie formatsii neftegazonosnykh provintsii Ukrainy. Kiev: Naukova dumka. [in Russian]

Ermakov, V. I., & Skorobogatov, V. A. (1984). Obrazovanie uglevodorodnykh gazov v uglenosnykh i subuglenosnykh formatsiyakh. Moskva: Nedra. [in Russian]

Fedushchak, M. Yu., Kushniruk, V. O., & Bartoshynska, Ye. S. (1974). Atlas mikrostruktur vuhillia Lvivsko-Volynskoho baseinu. Kyiv: Naukova dumka. [in Ukrainian]

Hrinberh, Y. V., & Shabo, Z. V. (1971). Do metodyky doslidzhen elementarnoho ta izotopnoho skladu vuhletsiu 12S/13S hrafitiv. Heolohiia i heokhimiia horiuchykh kopalyn, 24, 88–90. [in Ukrainian]

Kasatochkin, V. I. (1955). Rentgenograficheskie i elektronno-mikroskopicheskie issledovaniya kamennykh uglei na raznykh stadiyakh metamorfizma. In II ugol’noe soveshchanie pri laboratorii uglya (pp. 84–85). Moskva; Leningrad: Izdatel’stvo AN SSSR. [in Russian]

Khokha, Yu. V. (2009). Termodynamichni umovy utvorennia naftopodibnykh system v nadrakh Zemli za spivvidnoshenniam stabilnykh izotopiv vuhletsiu v indyvidualnykh vuhlevodniakh. (Extended abstract of candidateʼs thesis). Lviv. [in Ukrainian]

Kostyk, I. O., Matrofailo, M. M., Korol, M. D., & Shulha, V. F. (2015). Perspektyvy promyslovoi vuhlenosnosti hlybokykh horyzontiv Lvivsko-Volynskoho kamianovuhilnoho baseinu. Stattia 3. Petrohrafichnyi sklad, yakist, zapasy vuhillia i resursy metanu serpukhovskoho vuhilnoho plasta υ6. Heolohiia i heokhimiia horiuchykh kopalyn, 1–2 (166–167), 40–63. [in Ukrainian]

Kostyk, I., Matrofailo, M., Lelyk, B., & Korol, M. (2016). Vuhleutvorennia na pochatkovomu etapi formuvannia kamʼianovuhilnoi formatsii Lvivsko-Volynskoho baseinu. Naukovyi visnyk Natsionalnoho hirnychoho universytetu, 1, 19–31. [in Ukrainian]

Kostyk, I. O., Matrofailo, M. M., & Korol, M. D. (2013). Perspektyvy suchasnoi pryrodnoi hazonosnosti vuhilnykh plastiv hlybokykh horyzontiv Lvivsko-Volynskoho baseinu. Heoloh Ukrainy, 3 (43), 50–59. [in Ukrainian]

Kostyk, I. O., Matrofailo, M. M., Shulha, V. F., & Korol, M. D. (2010). Perspektyvy promyslovoi vuhlenosnosti hlybokykh horyzontiv Lvivsko-Volynskoho kamianovuhilnoho baseinu. Stattia 1. Morfolohiia serpukhovskoho vuhilnoho plasta υ6 Lvivsko-Volynskoho baseinu i osoblyvosti yoho utvorennia. Heolohiia i heokhimiia horiuchykh kopalyn, 3–4 (152–153), 27–44. [in Ukrainian]

Kostyk, I. O., Matrofailo, M. M., & Sokorenko, S. S. (2007). Perspektyvy promyslovoi vuhlenosnosti nyzhnoi chastyny kamianovuhilnoi formatsii Lvivsko-Volynskoho baseinu. Heolohiia i heokhimiia horiuchykh kopalyn, 1, 27–44. [in Ukrainian]

Kozlov, V. P., & Tokarev, L. V. (1961). Masshtaby gazoobrazovaniya v osadochnykh tolshchakh (na primere Donetskogo basseina). Sovetskaya geologiya, 7, 19–33. [in Russian]

Lidin, G. D. (1963). Gazoobil’nost’ kamennougol’nykh shakht SSSR (Vol. 3). Moskva: Izdatel’stvo AN SSSR. [in Russian]

Lukinov, V. V., Pimonenko, A. P., & Pigunovskii, P. I. (2005). Vliyanie veshchestvennogo sostava i sostoyanie verkhnei mantii na gazonosnost’ osadochnoi tolshchi Donbassa. Geotekhnicheskaya mekhanika, 54, 96–100. [in Russian]

Maiboroda, A. A., & Antsiferov, V. A. (2007). Gazogeneriruyushchee rasseyanoe organicheskoe veshchestvo i ego raspreddelenie v uglenosnykh formatsiyakh Donbassa. Naukovi pratsi UkrNDMI NAN Ukrainy, 1, 21–38. [in Russian]

Moisyshyn, V. M., Naumko, I. M., Pylypets, V. I., Radchenko, V. V., Khalimendikov, Ye. M., Kozhushok, O. D., Zinchenko, S. A., Sheveliev, L. V., Yushkov, Ye. O., & Turchyn, V. A. (2013). Kompleksne osvoiennia hazovuhilnykh rodovyshch na osnovi potokovykh tekhnolohii burinnia sverdlovyn. Kyiv: Naukova dumka. [in Ukrainian]

Matrofailo M. M., Shulha V. F., Kostyk I. O., & Korol M. D. (2012). Perspektyvy promyslovoi vuhlenosnosti hlybokykh horyzontiv Lvivsko-Volynskoho kamianovuhilnoho baseinu. Stattia 2. Morfolohiia vizeiskoho vuhilnoho plasta υ03 i osoblyvosti yoho utvorennia (Kovelska ploshcha). Heolohiia i heokhimiia horiuchykh kopalyn, 3–4 (160–161), 29–48. [in Ukrainian]

Naumko, I. M., Bekesha, S. M., & Svoren, Y. M. (2008). Fliuidy hlybynnykh horyzontiv litosfery i zviazok z rodovyshchamy nafty i hazu v zemnii kori (za danymy vyvchennia vkliuchen u mineralakh hlybynnoho pokhodzhennia). Dopovidi Natsionalnoi akademii nauk Ukrainy, 8, 117–120. [in Ukrainian]

Naumko, I. M., Pavliuk, M. I., Svoren, Y. M., & Zubyk, M. I. (2015). Metan hazovuhilnykh rodovyshch – potuzhne dodatkove dzherelo vuhlevodniv v Ukraini. Visnyk Natsionalnoi akademii nauk Ukrainy, 6, 43–54. [in Ukrainian]

Naumko, I. M., Pavliuk, M. I., Svoren, Y. M., & Zubyk, M. I. (2016). Hazy vuhilnykh rodovyshch: nove vyrishennia problemy syntezu-henezysu metanu. Dopovidi Natsionalnoi akademii nauk Ukrainy, 3, 61–68. [in Ukrainian]

Pavliuk, I. M., Byk, S. I., & Naumko, I. M. (2006). Lvivsko-Volynskyi kamianovuhilnyi basein – perspektyvnyi hazonosnyi (metanonosnyi) rehion Ukrainy. Heotekhnichna mekhanika, 67, 103–108. [in Ukrainian]

Pavliuk, M., Dudok, I., Naumko, I., Byk, S., & Bartoshynska, Ye. (2008). Hazonosnist vidkladiv kamianovuhilnoho viku Lvivsko-Volynskoho baseinu. Heolohiia i heokhimiia horiuchykh kopalyn, 4 (145), 11–20. [in Ukrainian]

Pavliuk, M. I., Naumko, I. M., Bartoshynska, Ye. S., & Matrofailo, M. M. (2012). Osnovni prychyny dehazatsii vuhleporodnykh masyviv Lvivsko-Volynskoho baseinu. Geotekhnicheskaya mekhanika, 102, 277–284. [in Ukrainian]

Petrikovskaya M. E., Ivanov A. K., Kushniruk V. A., & Grinberg I. V. (1969). Issledovaniya izotopnogo sostava metanovykh gazov Mezhrechenskogo kamennougol’nogo mestorozhdeniya v svyazi s ego gazonosnost’yu. Geologiya i geokhimiya goryuchikh iskopaemykh, 18, 38–45. [in Russian]

Shul’ga, V. F., Kostik, I. E., Matrofailo, M. N., & Korol’, N. D. (2009). O zarozhdenii karbonovoi uglenosnoi formatsii L’vovsko-Volynskogo ugol’nogo baseina. Dopovidi Natsionalnoi akademii nauk Ukrainy, 7, 121–127. [in Russian]

Shul’ga, V. F., Zdanovski, A., Zaitseva, L. B., Ivanova, A. V., Ivanina, A. V., Korol’, N. D., Kotasova, A., Kotas, A., Kostik, I. E., Lelik, B. I., Miger, T., Manichev, V. I., Matrofailo, M. N., Ptak, B., Savchuk, V. S., Sedaeva, G. M., & Stepanenko, Ya. G. (2007). Korrelyatsiya karbonovykh uglenosnykh formatsii L’vovsko-Volynskogo i Lyublinskogo basseinov. Kiev: Varta. [in Russian]

Skovorodnikova, E. A. (1991). Paleogeografiya L’vovsko-Volynskogo kamennougol’nogo basseina v epokhu karbonovogo uglenakopleniya. Geologicheskii zhurnal, i, 28–37. [in Russian]

Sokolov, V. L. (1971). Geokhimiya prirodnykh gazov. Moskva: Nauka. [in Russian]

Sokorenko, S., Kostyk, I., & Matrofailo, M. (2011). Osoblyvosti suchasnoi pryrodnoi hazonosnosti vuhilnykh plastiv ta vuhlevmisnykh porid Liubelskoho rodovyshcha kamianoho vuhillia Lvivsko-Volynskoho baseinu. Heoloh Ukrainy, 2 (34), 81–89. [in Ukrainian]

Sokorenko, S. S., Kostyk, I. O., & Uziiuk, V. I. (2007). Perspektyvy promyslovoi hazonosnosti vuhilnykh porid Tiahlivskoho rodovyshcha kamianoho vuhillia Lvivsko-Volynskoho baseinu. Heolohiia i heokhimiia horiuchykh kopalyn, 2, 34–45. [in Ukrainian]

Sokorenko, S., Kostyk, I., & Uziiuk, V. (2009). Osoblyvosti hazonosnosti vuhilnoho plasta υ6 Lvivsko-Volynskoho baseinu i perspektyvy vykorystannia metanu. Heolohiia i heokhimiia horiuchykh kopalyn, 2 (147), 19–30. [in Ukrainian]

Struev M. I., Isakov V. I. i dr. (1984). L’vovsko-Volynskii kamennougol’nyi bassein: Geologo-promyshlennyi ocherk. Kiev: Naukova dumka. [in Russian]

Teodorovich, G. I. (1958). Uchenie ob osadochnykh porodakh. Primenitel’no k geologii nefti i uglya. Leningrad: Gostoptekhizdat. [in Russian]

Yavnyi, P., Knysh, I., Buchynska, I., & Byk, S. (2009). Prohnoz hazonosnosti vuhilnykh plastiv Tiahlivskoho rodovyshcha Lvivsko-Volynskoho baseinu. Heolohiia i heokhimiia horiuchykh kopalyn, 2, 39–51. [in Ukrainian]

Zabihailo, V. Yu., Karavaiev, V. Ya., & Ivantsiv, O. Ye. (1993). Osoblyvosti poshyrennia ta resursy metanu vuhlenosnykh vidkladiv Lvivsko-Volynskoho baseinu. Heolohiia i heokhimiia horiuchykh kopalyn, 4 (85), 18–23. [in Ukrainian]

Zabigailo, V. E., & Shirokov, A. Z. (1972). Problemy geologii gazov ugol’nykh mestorozhdenii. Kiev: Naukova dumka. [in Russian]

Zabilailo, V. Yu., & Uziiuk V. I. (Heads). (2001). Hazoheneratsiinyi potentsial kamianovuhilnykh baseiniv Ukrainy. Zvit z naukovo-doslidnoi roboty [Research report]. No 0101U005160. Lviv. [in Ukrainian]

Zav’yalova, E. A. (1964). Fatsial’naya kharakteristika kamennougol’nykh otlozhenii L’vovskoi mul’dy. Trudy UkrNIGRI, 9, 60–73. [in Russian]