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GEOCHEMISTRY AND THERMOBAROMOMETRY OF MINERAL-FORMING FLUIDS AND THERMOBAROGEOCHEMISTRY OF EVAPORITES – WORLD-FAMOUS SCIENTIFIC SCHOOLS

Home > Archive > No. 1 (182) 2020 > 76-86


Geology & Geochemistry of Combustible Minerals No. 1 (182) 2020, 76-86.

цифровий ідентифікатор DOI цієї статті

Ihor NAUMKO, Myroslav PAVLYUK, Andriy POBEREZHSKYY

Institute of Geology and Geochemistry of Combustible Minerals of National Academy of Sciences of Ukraine, Lviv, e-mail: igggk@mail.lviv.ua

Abstract

Fundamental and applied achievements in the fields of geochemistry and thermobarometry of mineral-forming fluids and thermobarogeochemistry of evaporites are summarized as the basis of the corresponding world-famous scientific thermobarogeochemical schools established by professors V. A. Kalyuzhny and O. Yo. Petrychenko at the Institute of Geology and Geochemistry of Combustible Minerals of the Academy of Sciences of Ukraine on the basis of creative development of ideas of predecessors with the support of academicians Ye. K. Lazarenko, V. S. Sobolyev, H. N. Dolenko. Emphasis is placed on the contribution of schools to geological science, which is determined by the formed knowledge base on geochemical and thermobaric parameters of fluid environments of mineral-ore- naphthidogenesis in the Earth’s lithosphere (according to data of fluid inclusions research). In this context, in view of the enormous array of available data, the composition, physicochemical properties, genesis of fluids of the upper mantle and crust are briefly discussed and it is shown that the course of processes of petro-, mineral-, ore-, naphthidogenesis and formation fields of hydrocarbon, ore and non-ore minerals is determined by the peculiarities of degassing (defluidization) of the Earth and its influence on the conversion of carbon compounds during terrigenous, organogenic, hemogenic sedimentation and on the processes of diagenesis of sediments of various origins. The obtained data on the reproduction of the evolution of the fluid regime of rock complexes contribute to solving the fundamental problem of geochemistry of carbon and hydrogen (hydrocarbon-hydrogen matter) and deep (endogenous) fluid flows in the Earth’s lithosphere as an important basis for mineralofluidological model of the planet. They played a decisive role in substantiating at the Institute on the basis of abiogenic-biogenic dualism universal approaches to the processes of synthesis and genesis of natural hydrocarbons in the form of a new fundamental paradigm of oil and gas geology and geochemistry, the polygenesis of natural hydrocarbons in the Earth’s bowels, which increases the potential of oil and gas resources of promising regions, including Ukraine. This creates the preconditions for the identification of promising rock complexes for hydrocarbon, ore and non-ore minerals by applying the obtained fundamental thermobarogeochemical data in forecasting, exploration and operational practice on the basis of developing of new non-traditional geotechnologies for assessment and exploration of hydrocarbons and minerals.

Keywords

fluid inclusions, geochemistry, thermobarometry, fluids, fluid media, mineral-ore-naphthidogenesis, Earth’s lithosphere.

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BOWELS OF THE EARTH – NATURAL PHYSICAL-CHEMICAL REACTOR: IS THE SEARCH FOR NATURAL METHANE A FUNDAMENTAL SCIENCE OR A TECHNICAL PROBLEM?

Home > Archive > No. 4 (181) 2019 > 104-115


Geology & Geochemistry of Combustible Minerals No. 4 (181) 2019, 104-115.

цифровий ідентифікатор DOI цієї статті

Yosyp Svoren

Institute of Geology and Geochemistry of Combustible Minerals of National Academy of Sciences of Ukraine, Lviv, Ukraine,
e-mail: igggk@mail.lviv.ua

Abstract

It is shown that the hypothesis of organic origin of hydrocarbons doesn’t respond to the presence of a dominant concentration of methane in sediments, deposits, “shale’ series and so on, hence prospecting and exploration for hydrocarbon deposits in them are conducted in most cases intuitively, but not on the fundamental scientific basis.

Experimental studies based on the heating of slightly modified organic matter (peat) show that up to 200 °C in the process of its decomposition the following gases were delivered (vol. %): CO2 = 49.5; H2O = 49.3; CH4, C2H6, C3H8, N2, H2, SO2, H2S within 1.2 % in total.

It is confirmed that there is no coal methane, there is no shale gas-methane, but there is methane of one genesis with slightly different isotope composition of carbon, but synthesized according to the same mechanism in the high-thermobaric processes that after migration into the earth’s crust accumulated in the form of deposits in cavities of coal seams, terrigenous units, sandstones and so on.

Prospecting for pool-deposits of hydrocarbons should be carried out in conformity with developed “new technology of determination of prospects for oil and gas presence in the local area”, “physical-chemical model of synthesis of hydrocarbons and the way of geochemical searching for their occurrences”, “new theory of hydrocarbon synthesis and genesis in the earth’s lithosphere: abiogenic-biogenic dualism”.

Keywords

fluid inclusions, minerals, methane, origin of hydrocarbons, exploration, pool-deposits, new technologies.

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Naumko, І. М., Кurovets’, І. М., Zubyk, М. І., Batsevych, N. V., Sakhno, B. Е., & Chepusenko, P. S. (2017). Hydrocarbon compounds and plausible mechanism of gas generation in “shale” gas prospective Silurian deposits of Lviv Paleozoic depression. Geodynamics, 1 (22), 26–41.

Naumko, I. M., Pavliuk, M. I., Svoren, I. M., Zubyk, M. I. (2016). Hazy vuhilnykh rodovyshch: nove vyrishennia problemy syntezu–henezysu metanu. Dopovidi NAN Ukrainy, 3, 61–68. [in Ukrainian]

Naumko, I. M., & Svoren, I. M. (2003). O vazhnosti glubinnogo vysokotemperaturnogo flyuida v sozdanii usloviy dlya formirovaniya mestorozhdeniy prirodnykh uglevodorodov v zemnoy kore. In Novyye idei v naukakh o Zemle: Materialy VI Mezhdunarodnoy konferentsii (Moskva. 8–12 aprelya 2003 g.) (T. 1. s. 249). Moskva. [in Russian]

Naumko, I., & Svoren, I. (2014). Novi tekhnolohii poshukiv korysnykh kopalyn, osnovani na doslidzhenniakh fliuidnykh vkliuchen u mineralakh. In Aktualnyye problemy poiskovoy i ekologicheskoy geokhimii: Sbornik tezisov Mezhdunarodnoy nauchnoy konferentsii (Kiyev. 1–2 iyulya 2014 g.) (s. 23–25). Kiev: Interservis. [in Ukrainian]

Svoren, I. M. (1984). Primesi gazov v kristallakh mineralov i drugikh tverdykh telakh, ikh sposoby izvlecheniya, sostav, forma nakhozhdeniya i vliyaniye na svoystva veshchestv. (Extended abstract of candidateʼs thesis). Institut geologii i geokhimii goryuchikh iskopayemykh AN USSR, Lvov. [in Russian]

Svoren, Y. M. (1992). Pytannia teorii henezysu pryrodnykh vuhlevodniv ta shliakhy poshuku yikh pokladiv. In Tektohenez i naftohazonosnist nadr Ukrainy: tezy dopovidei naukovoi narady (20–22 zhovtnia 1992 r.) (s. 143–145). Lviv. [in Ukrainian]

Svoren, Y. M. (2008). Termobarometriia i heokhimiia haziv prozhylkovo-vkraplenoi mineralizatsii u vidkladakh naftohazonosnykh oblastei i metalohenichnykh provintsii: pryroda vuhilnoho metanu. Ugol Ukrainy, 8 (620), 42–46. [in Ukrainian]

Svoren, Y. (2013). Termobarometriia ta heokhimiia haziv prozhylkovo-vkraplenoi mineralizatsii u vidkladakh naftohazonosnykh oblastei i metalohenichnykh provintsii: defekty v mineralakh – dzherelo informatsii pro protsesy mineraloutvorennia. Mineralohichnyi zbirnyk, 63 (2), 91–97. [in Ukrainian]

Svoren, Y. (2018). Vlastyvist hlybynnoho abiohennoho metanovmisnoho vysokotermobarnoho fliuidu utvoriuvaty vuhillia. Heolohiia i heokhimiia horiuchykh kopalyn, 3–4 (176–177), 105–109. [in Ukrainian]

Svoren, I. (2019). Pro novyi pidkhid do vyznachennia teplotvornosti pryrodnoho hazu, yakyi postachaiut spozhyvacham, ta yoho kubometrobarometriiu. Heolohiia i heokhimiia horiuchykh kopalyn, 2 (179), 84–89. [in Ukrainian]

Svoren, Y. M., & Davydenko, M. M. (1994). Sposib vyznachennia perspektyvy naftohazonosnosti lokalnoi ploshchi. Promyslova vlasnist. Ofitsiinyi biuleten, 4. [in Ukrainian]

Svoren, Y. M., & Davydenko, M. M. (1995). Termobarometriia i heokhimiia haziv prozhylkovo-vkraplenoi mineralizatsii u vidkladakh naftohazonosnykh oblastei i metalohenichnykh provintsii. Dopovidi NAN Ukrainy, 9, 72–73. [in Ukrainian]

Svoren, Y. M., Davydenko, M. M., Haievskyi, V. H., Krupskyi, Yu. Z., & Pelypchak, B. P. (1994). Perspektyvy termobarometrii i heokhimii haziv prozhylkovo-vkraplenoi mineralizatsii u vidkladakh naftohazonosnykh oblastei i metalohenichnykh provintsii (novyi naukovyi napriamok v heolohii). Heolohiia i heokhimiia horiuchykh kopalyn, 3–4 (88–89), 54–63. [in Ukrainian]

Svoren, Y. M., & Naumko, I. M. (2000). Nova tekhnolohiia vyznachennia henezysu vuhlevodnevykh haziv. In Nafta i haz Ukrainy (T. 1, s. 118). Ivano-Frankivsk: UNHA. [in Ukrainian]

Svoren, I. M., & Naumko, I. M. (2003). Rol adiabaticheskikh yavleniy v protsessakh nakopleniya-kontsentratsii i prevrashcheniya uglevodorodsoderzhashchikh veshchestv v litosfere Zemli. In Novyye idei v naukakh o Zemle: Materialy VI Mezhdunarodnoy konferentsii (Moskva. 8–12 aprelya 2003 g.) (T. 1. s. 257). Moskva. [in Russian]

Svoren, Y. M., & Naumko, I. M. (2006). Nova teoriia syntezu i henezysu pryrodnykh vuhlevodniv: abiohenno-biohennyi dualizm. Dopovidi NAN Ukrainy, 2, 111–116. [in Ukrainian]

Svoren, Y., & Naumko, I. (2012). Boryslavske vuhlevodneve rodovyshche: problemy dlia rozdumiv. In Stan, problemy ta perspektyvy naftohazovoi promyslovosti Ukrainy: Zbirnyk tez dopovidei Mizhnarodnoi naukovo-praktychnoi konferentsii (Lviv, 7–9 veresnia 2012 r.) (s. 16). Lviv: Vydavnytstvo Lvivskoi politekhniky. [in Ukrainian]

Svoren, I. M., Naumko, I. M., & Davydenko, M. M. (1998). Nova tekhnolohiia vyznachennia perspektyvy naftohazonosnosti lokalnoi ploshchi. In Nafta–Haz Ukrainy – 1998: Materialy V Mizhnarodnoi konferentsii (Poltava, 15–17 veresnia 1998 r.) (T. 1, s. 111–112). Poltava: UNHA. [in Ukrainian]

Svoren’, J. M., Naumko, І. М., Kovalyshyn, Z. I., Bratus’, M. D., & Davydenko, M. M. (1999). New technology of local forecast of enriched areas of gold ore fields. In Naukovi osnovy prohnozuvannia, poshukiv ta otsinky rodovyshch zolota: Materialy Mizhnarodnoi naukovoi konferentsii (Lviv, 27–30 veresnia 1999 r.) (s. 121–125). Lviv: Vydavnychyi tsentr LDU im. I. Franka.