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ON THE SIGNIFICANCE OF NATURAL CARBONATES IN THE PROCESSES OF SYNTHESIS AND GENESIS OF HYDROCARBONS IN THE EARTH’S LITHOSPHERE

Home > Archive > No. 3–4 (191–192) 2023 > 135–142


Geology & Geochemistry of Combustible Minerals No. 3–4 (191–192) 2023, 135–142

https://doi.org/10.15407/ggcm2023.191-192.135

Josyp SVOREN’

Institute of Geology and Geochemistry of Combustible Minerals of National Academy of Sciences of Ukraine, Lviv, Ukraine, e-mail: igggk@mail.lviv.ua

Abstract

The fundamental importance of studies of the processes of synthesis and genesis of hydrocarbons in the Earth’s lithosphere has been confirmed and the prospects of the chosen direction for advanced research have been demonstrated, as well as for the thorough development of genetic principles of physical and chemical conditions of the formation of hydrocarbons deposits in various geological minds, focusing on the role of natural carbonate formation in this process. It is shown in this connection that one of the most striking natural phenomena of the Earth’s lithosphere is the obvious manifestations of veinlet-impregnated carbonate mineralization. This has been discussed in detail in the case of some areas of the Ukrainian Carpathians and Pre-Сarpathians, where the original carbonate veinlets of hydrothermal origin with traces of hydrocarbons migration are often happened, but industrial research works is rarely carried out because of their low (as expected) prospects for gas and oil deposits. We pay attention to the areas of development of the calcite veinlets with rare, perfectly faceted crystals of quartz – “Marmarosh diamonds” among the Cretaceous and Paleogene deposits of the South-Western slope of the Carpathians.

As a result, supporting materials on the importance of natural carbonates in the processes of synthesis and genesis of hydrocarbons in the Earth’s lithosphere are given. It consists in the revealed previously unknown property of natural carbonates, mainly calcium carbonate, under the action of abiogenic high-thermobaric deep fluid to decompose and be an additional source of carbon with different isotopic compositions in the processes of synthesis and genesis of hydrocarbons: gas, oil, bitumen as well as a carrier of these compounds in time of their migration and conservation in new creations in the deposits of oil and gas-bearing areas and metallogenic provinces: deposits-fields, veins, fluid inclusions, veinlet-impregnated mineralization.

Keywords

fluid inclusions, carbonates, veins, hydrocarbons, deposits, gas and oil, mass spectrometric studies, supposed scientific discovery

Referenses

Biletskyi, V. C. (Red.). (2004). Mala hirnycha entsyklopediia: Vol. 1. A–K. Donetsk: Donbas. [in Ukrainian]

Bratus, M. D., Davydenko, M. M., Zinchuk, I. M., Kaliuzhnyi, V. A., Matviienko, O. D., Naumko, I. M., Pirozhyk, N. E., Redko, L. R., & Svoren, Y. M. (1994). Fliuidnyi rezhym mineraloutvorennia v litosferi (v zviazku z prohnozuvanniam korysnykh kopalyn). Kyiv: Naukova dumka. [in Ukrainian]

Lazarenko, Ye. K., & Vynar, O. M. (1975). Mineralohichnyi slovnyk. Kyiv: Naukova dumka. [in Ukrainian]

Matkovskyi, O. I. (Hol. red.). (2003). Mineraly Ukrainskykh Karpat. Boraty, arsenaty, fosfaty, molibdaty, sulfaty, karbonaty, orhanichni mineraly i mineraloidy. Lviv: Vydavnychyi tsentr LNU im. Ivana Franka. [in Ukrainian]

Matkovskyi, O., Naumko, I., Pav lun, M., & Slyvko, Ye. (2021). Termobaroheokhimiia v Ukraini. Lviv: Prostir-M. [in Ukrainian]

Naumko, I. M. (2006). Fliuidnyi rezhym mineralohenezu porodno-rudnykh kompleksiv Ukrainy (za vkliuchenniamy u mineralakh typovykh parahenezysiv) [Extended abstract of Doctorʼs thesis, Institute of Geology and Geochemistry of Combustible Minerals of National Academy of Sciences of Ukraine]. Lviv. [in Ukrainian]

Naumko I., Bratus M., Dudok I., Kaliuzhnyi V., Kovalyshyn Z., Sakhno B., Svoren Y., & Telepko L. (2004). Fliuidnyi rezhym katahenno-hidrotermalnoho protsesu periodu formuvannia zhylnoi, prozhylkovoi i prozhylkovo-vkraplenoi mineralizatsii v osadovykh tovshchakh. In V. V. Kolodii (Ed.), Karpatska naftohazonosna provintsiia (pp. 308–345). Lviv; Kyiv: Ukrainskyi vydavnychyi tsentr. [in Ukrainian]

Naumko, I. M., & Svoren, Y. M. (2008). Pro shliakhy vtilennia hlybynnoho vysokotemperaturnoho fliuidu v zemnu koru. Dopovidi NAN Ukrainy, 9, 112–114. [in Ukrainian]

Svoren, I. M. (1984). Primesi gazov v kristallakh mineralov i drugikh tverdykh telakh, ikh sposoby izvlecheniya, sostav, forma nakhozhdeniya i vliyaniye na svoystva veshchestv [Extended abstract of Candidateʼs thesis. Institute of Geology and Geochemistry of Combustible Minerals of National Academy of Sciences of Ukraine]. Lvov. [in Russian]

Svoren, I. M. (1988). Formy nakhozhdeniya vodoroda v nekotorykh tverdykh materialakh razlichnogo proiskhozhdeniya soglasno fiziko-khimicheskoy modeli navodorozhivaniya tverdykh tel. In Geokhimiya i termobarometriya endogennykh flyuidov (pp. 95–103). Kiev: Naukova dumka. [in Russian]

Svoren, Y. M. (1992). Pytannia teorii henezysu pryrodnykh vuhlevodniv ta shliakhy poshuku yikh pokladiv. In Tektohenez i naftohazonosnist nadr Ukrainy (pp. 143–145). Lviv. [in Ukrainian]

Svoren, Y. (2020a). Nadra Zemli – pryrodnyi fizyko-khimichnyi reaktor: pryroda vody naftovykh i hazovykh rodovyshch. In Naftohazova haluz: Perspektyvy naroshchuvannia resursnoi bazy: materialy dopovidei Mizhnarodnoi naukovo-tekhnichnoi konferentsii (Ivano-Frankivsk, 8–9 hrudnia 2020 r.) (pp. 158–160). Ivano-Frankivsk: IFNTUNH. [in Ukrainian]

Svoren, J. M. (2020b). Various Chemical Properties of Carbon Isotopes in Natural Synthesis of Different Compounds. Journal of Geological Resource and Engineering, 8, 20–23. https://doi.org/10.17265/2328-2193/2020.01.002

Svoren, Y. M., & Davydenko, M. M. (1995). Termobarometriia i heokhimiia haziv prozhylkovo-vkraplenoi mineralizatsii u vidkladakh naftohazonosnykh oblastei i metalohenichnykh provintsii. Dopovidi NAN Ukrainy, 9, 72–73. [in Ukrainian]

Svoren, Y. M., Davydenko, M. M., Haievskyi, V. H., Krupskyi, Yu. Z., & Pelypchak, B. P. (1994). Perspektyvy termobarometrii i heokhimii haziv prozhylkovo-vkraplenoi mineralizatsii u vidkladakh naftohazonosnykh oblastei i metalohenichnykh provintsii. Heolohiia i heokhimiia horiuchykh kopalyn, 3–4(88–89), 54–63. [in Ukrainian]

Svoren, Y. M., & Naumko, I. M. (2003). Nova teoriia syntezu i henezysu vuhlevodniv u litosferi Zemli: abiohenno-biohennyi dualizm. In Mezhdunarodnaya konferentsiya “Krym–2003” (pp. 75–77). Simferopol. [in Ukrainian]

Svoren, Y., & Naumko, I. (2004). Termobarometriia i heokhimiia haziv prozhylkovo-vkraplenoi mineralizatsii u vidkladakh naftohazonosnykh oblastei i metalohenichnykh provintsii: henezys i syntez prozhylkovykh karbonatnykh porid. In Mineralohiia: istoriia, teoriia i praktyka: tezy dopovidei Mizhnarodnoi naukovoi konferentsii, prysviachenoi 140-richchiu kafedry mineralohii Lvivskoho natsionalnoho universytetu imeni Ivana Franka (Lviv–Shatsk, 3–6 veresnia 2004 r.) (pp. 63–65). Lviv: Vydavnychyi tsentr LNU imeni Ivana Franka. [in Ukrainian]

Svoren, Y. M., & Naumko, I. M. (2005). Termobarometriia i heokhimiia haziv prozhylkovo-vkraplenoi mineralizatsii u vidkladakh naftohazonosnykh oblastei i metalohenichnykh provintsii – pryrodnyi fenomen litosfery Zemli. Dopovidi NAN Ukrainy, 2, 109–113. [in Ukrainian]

Svoren, Y. M., & Naumko, I. M. (2006). Nova teoriia syntezu i henezysu pryrodnykh vuhlevodniv: abiohenno-biohennyi dualizm. Dopovidi NAN Ukrainy, 2, 111–116. [in Ukrainian]


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ON THE REGULARITY OF NATURAL PROCESSES OF SYNTHESIS AND GENESIS HYDROCARBONS AND WATER OF OIL AND GAS FIELDS: ABIOGENIC-BIOGENIC DUALISM

Home > Archive > No. 1–2 (189–190) 2023 > 81–91


Geology & Geochemistry of Combustible Minerals No. 1–2 (189–190) 2023, 81–91

https://doi.org/10.15407/ggcm2023.189-190.081

Yosyp SVOREN’

Institute of Geology and Geochemistry of Combustible Minerals of National Academy of Sciences of Ukraine, Lviv, Ukraine, e-mail: igggk@mail.lviv.ua

Abstract

It is shown that the problem of the nature of water in oil and gas fields must be solved in an inextricable connection with the genesis and synthesis of natural hydrocarbons in the Earth’s bowels. The work offers an original solution, based on a new theory of the synthesis and genesis of hydrocarbons (oil, gas, etc.): abiogenic-biogenic dualism, which asserts that giant and supergiant oil and gas fields were formed from inorganic and organic original hydrocarbon-containing substances under the influence of abiogenic high-thermobaric deep fluid in harsh physical, physicochemical and geological conditions of the earth’s crust. Since the abiogenic high-thermobaric deep fluid contains hydrogen H+ and OH-containing anions, the described mechanism for the interaction of positively charged ions: C+, H+, CnHm+-radicals with the formation-synthesis of a complex hydrocarbon mixture such as gas, oil, bitumen, etc. must be logically supplemented by a reaction: Н2О → Н+ + ОН. As a result of this complex physical and chemical process, the maximum concentration of (OH) anions accumulated in the oxidation zone, which after the disappearance of the electric field become neutral and interact with each other according to the scheme: ОН + ОН = Н2О2 – hydrogen peroxide, which is an unstable compound, which decomposes into Н2О + О. Oxygen atoms became the starting substances for the formation of macro- and microcracks in these cavities under harsh conditions of rocks of the carbonate or quartz-carbonate type, etc., much less often – perfect mineral crystals, which with their defects in the process of growth (synthesis) captivate and preserve substances in the system (proper hydrocarbons and water). Тherefore, it was established for the first time that the natural water of oil and gas fields has a dual lithospheric-asthenospheric nature, while the lithospheric part is dominant, the isotopic composition is a mixture of these waters, and the deuterium isotope is more chemically active in complex physical and chemical processes, which run through the bowels of the planet. The obtained original data will contribute to the solution of Ukraine’s serious problem with energy carriers: natural gas, oil, coal and drinking water.

Keywords

fluid inclusions, hydrocarbons, drinking water, energy carriers, oil and gas industry, fundamental science, scientific discoveries

Referenses

Bratus, M. D., Davydenko, M. M., Zinchuk, I. M., Kaliuzhnyi, V. A., Matviienko, O. D., Naumko, I. M., Pirozhyk, N. E., Redko, L. R., & Svoren, Y. M. (1994). Fliuidnyi rezhym mineraloutvorennia v litosferi (v zviazku z prohnozuvanniam korysnykh kopalyn). Kyiv: Naukova dumka. [in Ukrainian]

Dolenko, G. N. (1975). Sovremennoye sostoyaniye problemy proiskhozhdeniya nefti i gaza i formirovaniya ikh promyshlennykh zalezhey. In Zakonomernosti obrazovaniya i razmeshcheniya promyshlennykh mestorozhdeniy nefti i gaza (pp. 3–17). Kiev: Naukova dumka. [in Russian]

Naumko, I. M. (2006). Fliuidnyi rezhym mineralohenezu porodno-rudnykh kompleksiv Ukrainy (za vkliuchenniamy u mineralakh typovykh parahenezysiv) [Extended abstract of Doctorʼs thesis]. Instytut heolohii i heokhimii horiuchykh kopalyn NAN Ukrainy. Lviv. [in Ukrainian]

Naumko, I., & Svoren, Y. (2021). Innovatsiini tekhnolohii poshukiv korysnykh kopalyn, osnovani na doslidzhenniakh fliuidnykh vkliuchen u mineralakh. Heolohiia i heokhimiia horiuchykh kopalyn, 3–4(185–186), 92–108. https://doi.org/10.15407/ggcm2021.03-04.092 [in Ukrainian]

Pavliuk, I., Naumko, I., & Stefanyk, Yu. (2007, December 13). Heolohy-naukovtsi proty metanu-vbyvtsi. U Lvovi na Naukovii taky ye nauka. Ukraina i Chas, 50(286), 7.

Svoren, Y. M. (1975). Istochniki uglerodsoderzhashchikh gazov vklyucheniy. In Uglerod i ego soyedineniya v endogennykh protsessakh mineraloobrazovaniya (po dannym izucheniya flyuidnykh vklyucheniy v mineralakh): tezisy Respublikanskogo soveshchaniya (Lvov, sentyabr 1975 g.) (pp. 104–106). Lvov. [in Russian]

Svoren, I. M. (1984). Primesi gazov v kristallakh mineralov i drugikh tverdykh telakh, ikh sposoby izvlecheniya, sostav, forma nakhozhdeniya i vliyaniye na svoystva veshchestv [Extended abstract of Candidateʼs thesis]. Institut geologii i geokhimii goryuchikh iskopayemykh AN USSR. Lvov. [in Russian]

Svoren. I. M. (1988). Formy nakhozhdeniya vodoroda v nekotorykh tverdykh materialakh razlichnogo proiskhozhdeniya soglasno fiziko-khimicheskoy modeli navodorozhivaniya tverdykh tel. In Geokhimiya i termobarometriya endogennykh flyuidov (pp. 95–103). Kiev: Naukova dumka. [in Russian]

Svoren, Y. M. (1992). Pytannia teorii henezysu pryrodnykh vuhlevodniv ta shliakhy poshuku yikh pokladiv. In Tektohenez i naftohazonosnist nadr Ukrainy (pp. 143–145). Lviv. [in Ukrainian]

Svoren, Y. (2011). Nadra Zemli – pryrodnyi fizyko-khimichnyi reaktor: izotopy vuhletsiu pro pokhodzhennia planety Zemlia. Heolohiia i heokhimiia horiuchykh kopalyn, 1–2(154–155), 158–159. [in Ukrainian]

Svoren, Y. (2018). Vlastyvist hlybynnoho abiohennoho metanovmisnoho vysokotermobarnoho fliuidu utvoriuvaty vuhillia. Heolohiia i heokhimiia horiuchykh kopalyn, 3–4(176–177), 105–109. [in Ukrainian]

Svoren, Y. (2019). Nadra Zemli – pryrodnyi fizyko-khimichnyi reaktor: rizna khimichna vlastyvist izotopiv vuhletsiu u pryrodnykh protsesakh syntezu riznykh spoluk. In Problemy heolohii fanerozoiu Ukrainy: materialy X Vseukrainskoi naukovoi konferentsii (do 95-richchia kafedry istorychnoi heolohii ta paleontolohii i 120-richchia vid narodzhennia Severyna Ivanovycha Pasternaka (Lviv, 9–11 zhovtnia 2019 r.) (pp. 64–67). Lviv: LNU imeni Ivana Franka. [in Ukrainian]

Svoren, Y. (2020a). Nadra Zemli – pryrodnyi fizyko-khimichnyi reaktor: pryroda vody naftovykh i hazovykh rodovyshch. In Naftohazova haluz: Perspektyvy naroshchuvannia resursnoi bazy: materialy dopovidei Mizhnarodnoi naukovo-tekhnichnoi konferentsii (Ivano-Frankivsk, 8–9 hrudnia 2020 r.) (pp. 158–160). Ivano-Frankivsk: IFNTUNH. [in Ukrainian]

Svoren, J. M. (2020b). Subsoil Natural Physico-Chemical Reactor: Regularity of Natural Processes of Synthesis of Perfect Diamond Crystals. Journal of Geological Resource and Engineering, 8(4), 133–136. https://doi.org/10.17265/2328-2193/2020.04.005

Svoren, J. M. (2021). Subsoil Natural Physico-chemical Reactor: The Property of Deep Abiogenic Methane-Containing High-Thermobaric Fluid to Form Coal Seams. Journal of Geological Resource and Engineering, 9(1), 25–28. https://doi.org/10.17265/2328-2193/2021.01.003

Svoren, Y. M., & Davydenko, M. M. (1995). Termobarometriia i heokhimiia haziv prozhylkovo-vkraplenoi mineralizatsii u vidkladakh naftohazonosnykh oblastei i metalohenichnykh provintsii. Dopovidi NAN Ukrainy, 9, 72–73. [in Ukrainian]

Svoren, Y. M., Davydenko, M. M., Haievskyi, V. H., Krupskyi, Yu. Z., & Pelypchak, B. P. (1994). Perspektyvy termobarometrii i heokhimii haziv prozhylkovo-vkraplenoi mineralizatsii u vidkladakh naftohazonosnykh oblastei i metalohenichnykh provintsii. Heolohiia i heokhimiia horiuchykh kopalyn, 3–4(88–89), 54–63. [in Ukrainian]

Svoren, Y. M., & Naumko, I. M. (2003). Nova teoriia syntezu i henezysu vuhlevodniv u litosferi Zemli: abiohenno-biohennyi dualizm. In Mezhdunarodnaya konferentsiya “Krym–2003” (pp. 75–77). Simferopol. [in Ukrainian]

Svoren, Y. M., & Naumko, I. M. (2006). Nova teoriia syntezu i henezysu pryrodnykh vuhlevodniv: abiohenno-biohennyi dualizm. Dopovidi NAN Ukrainy, 2, 111–116. [in Ukrainian]


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THERMOMETRICAL STUDIES OF FLUID INCLUSIONS IN THE BADENIAN HALITE OF THE CARPATHIAN REGION IN THE CONTEXT OF DETERMINING THE DEPTH OF THE SALT BASIN

Home > Archive > No. 1–2 (189–190) 2023 > 54–65


Geology & Geochemistry of Combustible Minerals No. 1–2 (189–190) 2023, 54–65

https://doi.org/10.15407/ggcm2023.189-190.054

Anatoliy GALAMAY, Ihor ZINCHUK, Daria SYDOR

Institute of Geology and Geochemistry of Combustible Minerals of National Academy of Sciences of Ukraine, Lviv, Ukraine, e-mail: galamaytolik@ukr.net

Abstract

It was established that in order to avoid errors in the interpretation of paleotectonic conditions of salt formation based on fluid inclusions in halite, the primary stage of the research should be the genetic identification of the sedimentation textures of halite and fluid inclusions in this mineral. For the thermometric study of inclusions and to determine the depth of the sedimentation basin based on the obtained data, only thermal test chambers are suitable which provide the possibility of observing groups of inclusions in different zones of sedimentary halite, as, for example, in the micro thermal test chamber designed by Prof. V. A. Kalyuzhny.

In the course of the research, the equipment of the thermometric method, which is based on the use of a microthermal test chamber designed by V. A. Kalyuzhny, was modernized. In particular, the material of the thermal chamber (stainless steel) was replaced with copper, which made it possible to avoid excessive thermal gradients into chamber and to increase the permissible heating rate by 20 times due to the higher thermal conductivity of copper. For the same purpose, the glass optical windows of the camera were replaced with leukosapphire windows, which have a much higher thermal conductivity. The measuring system of the installation is made on a miniature platinum resistance thermometer with an electronic measuring unit. These improvements made it possible to achieve high system stability and good reproducibility of measurement results.

Using the thermometric method, it was established that the temperature of sedimentation at the bottom of the Badenian salt basin of the Carpathian region was 19.5–20.5; 20.0–22.0; 24.0–26.0 °C, and on the surface of the brine was 34.0–36.0 °C. On this basis, a model of the basin with a pronounced thermocline and a total thickness of the water column of up to 30 meters was built, which is the most likely to establish the features of sedimentation. Crystallization of halite at different depths in basins with a thermocline can explain the presence of so-called “low-temperature” (24.0–25.0 °C) and “high-temperature” (37.8–42.6 °C) bottom halite in a number of ancient salt-bearing basins.

Keywords

halite, fluid inclusions, thermometric method, thermal chamber, homogenization temperature

Referenses

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Galamay, A. R., Bukowski, K., Sydor, D. V., & Meng, F. (2020). The ultramicrochemical analyses (UMCA) of fluid inclusions in halite and experimental research to improve the accuracy of measurement. Minerals, 10(9), 823. https://doi.org/10.3390/min10090823

Galamay, A. R., Meng, F., Bukowski, K., Lyubchak, A., Zhang, Y., & Ni, P. (2019). Calculation of salt basin depth using fluid inclusions in halite from the Ordovician Ordos Basin in China. Geological Quarterly, 63(3), 619–628. https://doi.org/10.7306/gq.1490

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INNOVATIVE TECHNOLOGIES OF THE PROSPECTING FOR MINERAL DEPOSITS BASED ON DATA OF FLUID INCLUSIONS RESEARCH

Home > Archive > No. 3–4 (185–186) 2021 > 92–108


Geology & Geochemistry of Combustible Minerals No. 3–4 (185–186) 2021, 92–108.

https://doi.org/10.15407/ggcm2021.03-04.092

Ihor NAUMKO, Yosyp SVOREN

Institute of Geology and Geochemistry of Combustible Minerals of National Academy of Sciences of Ukraine, Lviv, Ukraine, e-mail: igggk@mail.lviv.ua

Abstract

The innovative approach to the development of prospective technologies (methods) was substantiated on crystallogenic and physicochemical principles of the knowledge of mineral forming environments (fluids) (thermobarogeochemistry – mineralofluidology – fluid inclusions) as a new branch of geological knowledge within the framework of the new scientific direction in the geology – thermobarometry and geochemistry of gases of veinlet-impregnated mineralization in deposits of oil- and gas-bearing areas and metallogenic provinces” as a natural phenomenon of the Earth’s lithosphere. According to him, the creation of radically new technologies and realization of prospecting for mineral deposits (first of all hydrocarbons and gold) simultaneously with the elucidation of the problem of genesis and synthesis of hydrocarbons at the atomic-molecular level fixed by such defects in the mineral crystals as fluid inclusions. Developed technologies, namely: determination of genesis of hydrocarbon gases; determination of prospects of oil and gas presence of a local area; local forecast of enriched areas of gold ore fields; express determination of potassium ions in inclusions for identification of gold-enriched and barren veinlet formations, – belong to the branch of the exploration geology and geochemistry and are used to ascertain genetic guestions, to solve tasks of the mineralogical-geochemical prediction and prospecting for mineral deposits in the local structures of oil- and gas-bearing areas and metallogenic provinces. The comparison of fluid inclusions of veinlets and host rocks based on the sections of a number of wells has shown the considerable possibilities of the developed technologies and prospects of the usage of thermobarogeochemical-mineralofluidological indicators in the complex with the geochemical and geophysical (petrophysical) methods, data of geological survey, deep-seated drilling while predicting hydrocarbon deposits in the local structures of the sedimentary strata promising for oil and gas and making necessary amendments in the directions of the following geological-prospecting works.

Keywords

innovative technologies, fluid inclusions, geochemistry, thermobarometry, fluids, hydrocarbons, gold, mineral-ore-naphthidogenesis, Earth’s lithosphere

Referenses

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GEOCHEMICAL FEATURES OF EURASIAN EVAPORITES IN THE CONTEXT OF THE CHEMICAL EVOLUTION OF SEAWATER IN PHANEROZOIC

Home > Archive > No. 1–2 (183–184) 2021 > 110–129


Geology & Geochemistry of Combustible Minerals No. 1–2 (183–184) 2021, 110–129.

https://doi.org/10.15407/ggcm2021.01-02.110

Аnatoliy GALAMAY, Andriy POBEREZHSKYY, Sofiya HRYNIV, Serhiy VOVNYUK, Dariya SYDOR, Iaroslava IAREMCHUK, Sofiya MAKSYMUK, Oksana OLIYOVYCH-HLADKA, Lyudmila BILYK

Institute of Geology and Geochemistry of Combustible Minerals of National Academy of Sciences of Ukraine, Lviv, e-mail: igggk@mail.lviv.ua

Abstract

Studies of evaporites provide new data to characterize the seawater chemistry in the Early Paleozoic and Middle Mesozoic. In particular, we studied the fluid inclusions in halite from Ordovician (China) and Cretaceous (Laos) evaporites. The corresponding sections on the plot of Ca/SO4 oscillations curve in the Phanerozoic seawater are updated. The calcium content in seawater concentrated to halite precipitation stage was 45.6 mol %, 485 million years ago and 24.3 mol % 112.2–93.5 million years ago.

By analyzing the previously published and new factual material, it is established that in Permian evaporites the sulfur isotopic composition is inversely correlated with the sulfate ion content in evaporite basin brines. Thus, the evolution of seawater chemistry in Permian is confirmed by the evolution of the isotopic composition of dissolved seawater sulfate.

According to the generalization of 38 Phanerozoic marine evaporite formations, it was found that the peculiarities of the clay minerals associations correlate with the change of the seawater chemical type. Clay minerals associations precipitated from the SO4-rich seawater are characterized by a larger set of minerals, among which smectite and mixed- layered minerals often occur; Mg-rich clay minerals (corensite, paligorskite, sepiolite, talc) also occur. Instead, in the associations of evaporite clay minerals formed from the Ca-rich seawater are represented by the smaller amount of minerals, and Mg-rich minerals are extremely rare. The increased content of magnesium in seawater of SO4-rich type is the main factor in the formation of Mg-rich silicates in evaporites.

The composition of clay minerals associations depends on the evaporate basin brine concentration; with its increase, unstable minerals are transformed, which theoretically leads to a decrease in the number of minerals in the associations. However, it was found that evaporite deposits of higher stages of brine concentration often still contain unstable clay minerals – products of incomplete transformation of a significant amount of pyroclastic material from coeval volcanic activity.

The main factor determining the composition of clay minerals associations of Phanerozoic evaporites was the seawater (and basin brines) chemical type.

Geochemical studies of scattered organic matter and fluid inclusions with hydrocarbon phase in evaporites of the Upper Pechora Basin (overlying oil and gas deposits) indicate the presence of allochthonous bitumoids and allow to use this method to predict oil and gas potential of other areas. Analysis of the results of oil and gas exploration in a number of areas of the Transcarpathian Trough indicates the presence of fluid-saturated reservoirs and the prospects for the discovery of new accumulations of hydrocarbons. Geochemical studies proved the effectiveness of gas-flow survey method for oil and gas exploration, assessing the prospects for fluid saturation of seismic structures.

Keywords

fluid inclusions, halit, salt Basin, seawater.

Referenses

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GEOCHEMISTRY Of FLUIDS: INNOVATIVE SOLUTION OF THE FUNDAMENTAL PROBLEM

Home > Archive > No. 1–2 (183–184) 2021 > 130–148


Geology & Geochemistry of Combustible Minerals No. 1–2 (183–184) 2021, 130–148.

https://doi.org/10.15407/ggcm2021.01-02.130

Josyp SVOREN

Institute of Geology and Geochemistry of Combustible Minerals of National Academy of Sciences of Ukraine, Lviv, e-mail: igggk@mail.lviv.ua

Abstract

First of all, has developed a reliable mass spectrometric method for studying fluid inclusions in minerals (on the basis of the author’s certificate of the USSR No. 454446 of 1974 for the invention of the “device for cleaning the content inclusions of solid materials”). Were created and published new scientific directions: 1. Thermobarometry and geochemistry of gases of veinlet-impregnated mineralization in sediments of oil and gas regions and metallogenic provinces. 2. Bowels of the Earth – natural physicochemical reactor. Was developed a “method (technology) for determining the prospects of oil and gas bearing of the local area” and “a method (technology) of local forecasting of enriched areas of gold-ore fields” (together with M. M. Davydenko). Was established unknown before, but objectively existing phenomenon of the material world: 1) “lack of molecular hydrogen in inclusions in minerals in the bowels of the planet Earth” (together with V. A. Kaliuzhny). Independently were established: 2) previously unknown “property of deep abiogenic methane-termobar high-temperature fluid decompose-convert natural organic residues into layers of coal with their simultaneous methane saturation and its conservation in the earth’s crust of the planet Earth”; 3) previously unknown natural “phenomenon of arbitrary formation of natural carbon methane in the coal layers of the earth’s crust of the planet Earth under the influence of abiogenic methane-containing high-temperature fluid with their conservation in them”; 4) previously unknown different chemical properties of carbon isotopes in natural processes of synthesis-formation of various carbon-containing compounds …; 5) “previously unknown pattern of natural processes of synthesis of perfect diamond crystals from astenospheric carbon dioxide ions…”. Was justified “a new way to determine the calorification of natural gas supplied to consumers and its cubic-metre barometry”.

Keywords

geochemistry, fluid inclusions, veinlet-impregnated mineralization, deep abiogenic methane-bearing high-termobaric fluid, searches, new technologies, cubic-metre-barometry, scientific discovery.

Referenses

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Naumko, I. M., Bekesha, S. M., & Svoren, Y. M. (2008). Fliuidy hlybynnykh horyzontiv litosfery: zviazok z rodovyshchamy nafty i hazu u zemnii kori (za danymy vyvchennia vkliuchen u mineralakh hlybynnoho pokhodzhennia). Dopovidi Natsionalnoi akademii nauk Ukrainy, 8, 117–120. [in Ukrainian]

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Svoren’, I. M. (1984). Primesi gazov v kristallakh mineralov i drugikh tverdykh telakh, ikh sposoby izvlecheniya, sostav, forma nakhozhdeniya i vliyanie na svoistva veshchestv [Extended abstract of сandidateʼs thesis]. Institut geologii i geokhimii goryuchikh iskopaemykh AN USSR. L’vov. [in Russian]

Svoren, Y. M. (1992). Pytannia teorii henezysu pryrodnykh vuhlevodniv ta shliakhy poshuku yikh pokladiv. In Tektohenez i naftohazonosnist nadr Ukrainy: tezy dopovidei naukovoi narady (20–22 zhovtnia 1992 r.) (pp. 143–145). Lviv. [in Ukrainian]

Svoren, Y. M. (2008). Termobarometriia i heokhimiia haziv prozhylkovo-vkraplenoi mineralizatsii u vidkladakh naftohazonosnykh oblastei i metalohenichnykh provintsii: pryroda vuhilnoho metanu. Ugol’ Ukrainy, 8(620), 42–46. [in Ukrainian]

Svoren, Y. (2011a). Nadra Zemli – pryrodnyi fizyko-khimichnyi reaktor: izotopy vuhletsiu pro pokhodzhennia planety Zemlia. Heolohiia i heokhimiia horiuchykh kopalyn, 1–2(154–155), 158–159. [in Ukrainian]

Svoren, Y. (2011b). Nadra Zemli – pryrodnyi fizyko-khimichnyi reaktor: pryroda zemletrusu. Heolohiia i heokhimiia horiuchykh kopalyn, 1–2(154–155), 160–162. [in Ukrainian]

Svoren, Y. (2017a). Nadra Zemli – pryrodnyi fizyko-khimichnyi reaktor: pryrodnyi vuhlevodnevyi fenomen. Heolohiia i heokhimiia horiuchykh kopalyn, 1–2(170–171), 157–160. [in Ukrainian]

Svoren, Y. (2017b). Yavyshche utvorennia pryrodnykh vuhlemetaniv pid diieiu abiohennoho metanovmistnoho vysokotermobarnoho hlybynnoho fliuidu. In Heolohiia horiuchykh kopalyn: dosiahnennia ta perspektyvy: materialy II Mizhnarodnoi naukovoi konferentsii (Kyiv, 6–8 veresnia 2017 r.) (pp. 225–229). Kyiv. [in Ukrainian]

Svoren, Y. (2019a). Nadra Zemli – pryrodnyi fizyko-khimichnyi reaktor: poshuk pryrodnoho metanu – fundamentalna nauka chy tekhnichna problema? Heolohiia i heokhimiia horiuchykh kopalyn, 4(181), 104–115. https://doi.org/10.15407/ggcm2019.04.104 [in Ukrainian]

Svoren, Y. (2019b). Pro novyi pidkhid do vyznachennia teplotvornosti pryrodnoho hazu, yakyi postachaiut spozhyvacham ta yoho kubometrobarometriiu. Heolohiia i heokhimiia horiuchykh kopalyn, 2(179), 84–89. https://doi.org/10.15407/ggcm2019.02.084 [in Ukrainian]

Svoren, Y. (2020a). Nadra Zemli – pryrodnyi fizyko-khimichnyi reaktor: pryroda vody naftovykh i hazovykh rodovyshch. In Naftohazova haluz: Perspektyvy naroshchuvannia resursnoi bazy: materialy dopovidei Mizhnarodnoi naukovo-tekhnichnoi konferentsii (Ivano-Frankivsk, 08–09 hrudnia 2020 r.) (pp. 158–160). [in Ukrainian]

Svoren, Y. (2020b). Pro znachennia kubometrobarometrii pryrodnoho hazu, yakyi postachaiut spozhyvacham. In Naftohazova haluz: Perspektyvy naroshchuvannia resursnoi bazy: materialy dopovidei Mizhnarodnoi naukovo-tekhnichnoi konferentsii (Ivano-Frankivsk, 08–09 hrudnia 2020 r.) (pp. 91–94). [in Ukrainian]

Svoren’, J. M. (2020c). Subsoil Natural Physico-Chemical Reactor: Regularity of Natural Processes of Synthesis of Perfect Diamond Crystals. Journal of Geological Resource and Engineering, 8, 133–136. https://doi.org/10.17265/2328-2193/2020.04.005

Svoren’, J. M. (2020d). Various Chemical Properties of Carbon Isotopes in Natural Synthesis of Different Compounds. Journal of Geological Resource and Engineering, 8, 20–23. https://doi.org/10.17265/2328-2193/2020.01.002

Svoren’, J. M. (2021). Subsoil Natural Physico-chemical Reactor: The Property of Deep Abiogenic Methane-Containing High-Thermobaric Fluid to Form Coal Seams. Journal of Geological Resource and Engineering, 9, 25–28. https://doi.org/10.17265/2328-2193/2021.01.003

Svoren, Y. M., & Davydenko, M. M. (1994). Sposib vyznachennia perspektyvy naftohazonosnosti lokalnoi ploshchi (Patent Ukrainy № 5G01V9/00). Promyslova vlasnist, 4. [in Ukrainian]

Svoren, Y. M., Davydenko, M. M., Haievskyi, V. H., Krupskyi, Yu. Z., & Pelypchak, B. P. (1994). Perspektyvy termobarometrii i heokhimii haziv prozhylkovo-vkraplenoi mineralizatsii u vidkladakh naftohazonosnykh oblastei i metalohenichnykh provintsii (novyi naukovyi napriamok v heolohii). Heolohiia i heokhimiia horiuchykh kopalyn, 3–4(88–89), 54–63. [in Ukrainian]

Svoren, Y. M., & Naumko, I. M. (2000). Nova tekhnolohiia vyznachennia henezysu vuhlevodnevykh haziv. In Nafta i haz Ukrainy–2000: materialy VI Mizhnarodnoi naukovo-praktychnoi konferentsii (Ivano-Frankivsk, 31 zhovtnia–3 lystopada 2000 r.) (Vol. 1, pp. 108). Ivano-Frankivsk: Fakel. [in Ukrainian]

Svoren, Y. M., & Naumko, I. M. (2006a). Nova teoriia syntezu i henezysu pryrodnykh vuhlevodniv: abiohenno-biohennyi dualizm. Dopovidi Natsionalnoi akademii nauk Ukrainy, 2, 111–116. [in Ukrainian]

Svoren, Y. M., & Naumko, I. M. (2006b). Rol riznykh form vodniu ta vuhletsiu v pryrodnykh protsesakh: novyi pohliad na pokhodzhennia vuhlevodniv. Dopovidi Natsionalnoi akademii nauk Ukrainy, 1, 131–134. [in Ukrainian]


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GEOCHEMISTRY AND THERMOBAROMOMETRY OF MINERAL-FORMING FLUIDS AND THERMOBAROGEOCHEMISTRY OF EVAPORITES – WORLD-FAMOUS SCIENTIFIC SCHOOLS

Home > Archive > No. 1 (182) 2020 > 62-75


Geology & Geochemistry of Combustible Minerals No. 1 (182) 2020, 62-75.

https://doi.org/10.15407/ggcm2020.01.062

Ihor NAUMKO, Myroslav PAVLYUK, Andriy POBEREZHSKYY

Institute of Geology and Geochemistry of Combustible Minerals of National Academy of Sciences of Ukraine, Lviv, e-mail: igggk@mail.lviv.ua

Abstract

Fundamental and applied achievements in the fields of geochemistry and thermobarometry of mineral-forming fluids and thermobarogeochemistry of evaporites are summarized as the basis of the corresponding world-famous scientific thermobarogeochemical schools established by professors V. A. Kalyuzhny and O. Yo. Petrychenko at the Institute of Geology and Geochemistry of Combustible Minerals of the Academy of Sciences of Ukraine on the basis of creative development of ideas of predecessors with the support of academicians Ye. K. Lazarenko, V. S. Sobolyev, H. N. Dolenko. Emphasis is placed on the contribution of schools to geological science, which is determined by the formed knowledge base on geochemical and thermobaric parameters of fluid environments of mineral-ore- naphthidogenesis in the Earth’s lithosphere (according to data of fluid inclusions research). In this context, in view of the enormous array of available data, the composition, physicochemical properties, genesis of fluids of the upper mantle and crust are briefly discussed and it is shown that the course of processes of petro-, mineral-, ore-, naphthidogenesis and formation fields of hydrocarbon, ore and non-ore minerals is determined by the peculiarities of degassing (defluidization) of the Earth and its influence on the conversion of carbon compounds during terrigenous, organogenic, hemogenic sedimentation and on the processes of diagenesis of sediments of various origins. The obtained data on the reproduction of the evolution of the fluid regime of rock complexes contribute to solving the fundamental problem of geochemistry of carbon and hydrogen (hydrocarbon-hydrogen matter) and deep (endogenous) fluid flows in the Earth’s lithosphere as an important basis for mineralofluidological model of the planet. They played a decisive role in substantiating at the Institute on the basis of abiogenic-biogenic dualism universal approaches to the processes of synthesis and genesis of natural hydrocarbons in the form of a new fundamental paradigm of oil and gas geology and geochemistry, the polygenesis of natural hydrocarbons in the Earth’s bowels, which increases the potential of oil and gas resources of promising regions, including Ukraine. This creates the preconditions for the identification of promising rock complexes for hydrocarbon, ore and non-ore minerals by applying the obtained fundamental thermobarogeochemical data in forecasting, exploration and operational practice on the basis of developing of new non-traditional geotechnologies for assessment and exploration of hydrocarbons and minerals.

Keywords

fluid inclusions, geochemistry, thermobarometry, fluids, fluid media, mineral-ore-naphthidogenesis, Earth’s lithosphere.

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Geology & Geochemistry of Combustible Minerals No. 4 (181) 2019, 104-115.

https://doi.org/10.15407/ggcm2019.04.104

Yosyp Svoren

Institute of Geology and Geochemistry of Combustible Minerals of National Academy of Sciences of Ukraine, Lviv, Ukraine,
e-mail: igggk@mail.lviv.ua

Abstract

It is shown that the hypothesis of organic origin of hydrocarbons doesn’t respond to the presence of a dominant concentration of methane in sediments, deposits, “shale’ series and so on, hence prospecting and exploration for hydrocarbon deposits in them are conducted in most cases intuitively, but not on the fundamental scientific basis.

Experimental studies based on the heating of slightly modified organic matter (peat) show that up to 200 °C in the process of its decomposition the following gases were delivered (vol. %): CO2 = 49.5; H2O = 49.3; CH4, C2H6, C3H8, N2, H2, SO2, H2S within 1.2 % in total.

It is confirmed that there is no coal methane, there is no shale gas-methane, but there is methane of one genesis with slightly different isotope composition of carbon, but synthesized according to the same mechanism in the high-thermobaric processes that after migration into the earth’s crust accumulated in the form of deposits in cavities of coal seams, terrigenous units, sandstones and so on.

Prospecting for pool-deposits of hydrocarbons should be carried out in conformity with developed “new technology of determination of prospects for oil and gas presence in the local area”, “physical-chemical model of synthesis of hydrocarbons and the way of geochemical searching for their occurrences”, “new theory of hydrocarbon synthesis and genesis in the earth’s lithosphere: abiogenic-biogenic dualism”.

Keywords

fluid inclusions, minerals, methane, origin of hydrocarbons, exploration, pool-deposits, new technologies.

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Svoren, Y. M. (2008). Termobarometriia i heokhimiia haziv prozhylkovo-vkraplenoi mineralizatsii u vidkladakh naftohazonosnykh oblastei i metalohenichnykh provintsii: pryroda vuhilnoho metanu. Ugol Ukrainy, 8 (620), 42-46. [in Ukrainian]
 
Svoren, Y. (2013). Termobarometriia ta heokhimiia haziv prozhylkovo-vkraplenoi mineralizatsii u vidkladakh naftohazonosnykh oblastei i metalohenichnykh provintsii: defekty v mineralakh – dzherelo informatsii pro protsesy mineraloutvorennia. Mineralohichnyi zbirnyk, 63 (2), 91-97. [in Ukrainian]
 
Svoren, Y. (2018). Vlastyvist hlybynnoho abiohennoho metanovmisnoho vysokotermobarnoho fliuidu utvoriuvaty vuhillia. Heolohiia i heokhimiia horiuchykh kopalyn, 3-4 (176-177), 105-109. [in Ukrainian]
 
Svoren, I. (2019). Pro novyi pidkhid do vyznachennia teplotvornosti pryrodnoho hazu, yakyi postachaiut spozhyvacham, ta yoho kubometrobarometriiu. Heolohiia i heokhimiia horiuchykh kopalyn, 2 (179), 84-89. [in Ukrainian]
 
Svoren, Y. M., & Davydenko, M. M. (1994). Sposib vyznachennia perspektyvy naftohazonosnosti lokalnoi ploshchi. Promyslova vlasnist. Ofitsiinyi biuleten, 4. [in Ukrainian]
 
Svoren, Y. M., & Davydenko, M. M. (1995). Termobarometriia i heokhimiia haziv prozhylkovo-vkraplenoi mineralizatsii u vidkladakh naftohazonosnykh oblastei i metalohenichnykh provintsii. Dopovidi NAN Ukrainy, 9, 72-73. [in Ukrainian]
 
Svoren, Y. M., Davydenko, M. M., Haievskyi, V. H., Krupskyi, Yu. Z., & Pelypchak, B. P. (1994). Perspektyvy termobarometrii i heokhimii haziv prozhylkovo-vkraplenoi mineralizatsii u vidkladakh naftohazonosnykh oblastei i metalohenichnykh provintsii (novyi naukovyi napriamok v heolohii). Heolohiia i heokhimiia horiuchykh kopalyn, 3-4 (88-89), 54-63. [in Ukrainian]
 
Svoren, Y. M., & Naumko, I. M. (2000). Nova tekhnolohiia vyznachennia henezysu vuhlevodnevykh haziv. In Nafta i haz Ukrainy (T. 1, s. 118). Ivano-Frankivsk: UNHA. [in Ukrainian]
 
Svoren, I. M., & Naumko, I. M. (2003). Rol adiabaticheskikh yavleniy v protsessakh nakopleniya-kontsentratsii i prevrashcheniya uglevodorodsoderzhashchikh veshchestv v litosfere Zemli. In Novyye idei v naukakh o Zemle: Materialy VI Mezhdunarodnoy konferentsii (Moskva. 8-12 aprelya 2003 g.) (T. 1. s. 257). Moskva. [in Russian]
 
Svoren, Y. M., & Naumko, I. M. (2006). Nova teoriia syntezu i henezysu pryrodnykh vuhlevodniv: abiohenno-biohennyi dualizm. Dopovidi NAN Ukrainy, 2, 111-116. [in Ukrainian]
 
Svoren, Y., & Naumko, I. (2012). Boryslavske vuhlevodneve rodovyshche: problemy dlia rozdumiv. In Stan, problemy ta perspektyvy naftohazovoi promyslovosti Ukrainy: Zbirnyk tez dopovidei Mizhnarodnoi naukovo-praktychnoi konferentsii (Lviv, 7-9 veresnia 2012 r.) (s. 16). Lviv: Vydavnytstvo Lvivskoi politekhniky. [in Ukrainian]
 
Svoren, I. M., Naumko, I. M., & Davydenko, M. M. (1998). Nova tekhnolohiia vyznachennia perspektyvy naftohazonosnosti lokalnoi ploshchi. In Nafta-Haz Ukrainy – 1998: Materialy V Mizhnarodnoi konferentsii (Poltava, 15-17 veresnia 1998 r.) (T. 1, s. 111-112). Poltava: UNHA. [in Ukrainian]
 
Svoren’, J. M., Naumko, І. М., Kovalyshyn, Z. I., Bratus’, M. D., & Davydenko, M. M. (1999). New technology of local forecast of enriched areas of gold ore fields. In Naukovi osnovy prohnozuvannia, poshukiv ta otsinky rodovyshch zolota: Materialy Mizhnarodnoi naukovoi konferentsii (Lviv, 27-30 veresnia 1999 r.) (s. 121-125). Lviv: Vydavnychyi tsentr LDU im. I. Franka.