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ON THE REGULARITY OF NATURAL PROCESSES OF SYNTHESIS AND GENESIS HYDROCARBONS AND WATER OF OIL AND GAS FIELDS: ABIOGENIC-BIOGENIC DUALISM

Home > Archive > No. 1–2 (189–190) 2023 > 81–91


Geology & Geochemistry of Combustible Minerals No. 1–2 (189–190) 2023, 81–91

https://doi.org/10.15407/ggcm2023.189-190.081

Yosyp SVOREN’

Institute of Geology and Geochemistry of Combustible Minerals of National Academy of Sciences of Ukraine, Lviv, Ukraine, e-mail: igggk@mail.lviv.ua

Abstract

It is shown that the problem of the nature of water in oil and gas fields must be solved in an inextricable connection with the genesis and synthesis of natural hydrocarbons in the Earth’s bowels. The work offers an original solution, based on a new theory of the synthesis and genesis of hydrocarbons (oil, gas, etc.): abiogenic-biogenic dualism, which asserts that giant and supergiant oil and gas fields were formed from inorganic and organic original hydrocarbon-containing substances under the influence of abiogenic high-thermobaric deep fluid in harsh physical, physicochemical and geological conditions of the earth’s crust. Since the abiogenic high-thermobaric deep fluid contains hydrogen H+ and OH-containing anions, the described mechanism for the interaction of positively charged ions: C+, H+, CnHm+-radicals with the formation-synthesis of a complex hydrocarbon mixture such as gas, oil, bitumen, etc. must be logically supplemented by a reaction: Н2О → Н+ + ОН. As a result of this complex physical and chemical process, the maximum concentration of (OH) anions accumulated in the oxidation zone, which after the disappearance of the electric field become neutral and interact with each other according to the scheme: ОН + ОН = Н2О2 – hydrogen peroxide, which is an unstable compound, which decomposes into Н2О + О. Oxygen atoms became the starting substances for the formation of macro- and microcracks in these cavities under harsh conditions of rocks of the carbonate or quartz-carbonate type, etc., much less often – perfect mineral crystals, which with their defects in the process of growth (synthesis) captivate and preserve substances in the system (proper hydrocarbons and water). Тherefore, it was established for the first time that the natural water of oil and gas fields has a dual lithospheric-asthenospheric nature, while the lithospheric part is dominant, the isotopic composition is a mixture of these waters, and the deuterium isotope is more chemically active in complex physical and chemical processes, which run through the bowels of the planet. The obtained original data will contribute to the solution of Ukraine’s serious problem with energy carriers: natural gas, oil, coal and drinking water.

Keywords

fluid inclusions, hydrocarbons, drinking water, energy carriers, oil and gas industry, fundamental science, scientific discoveries

Referenses

Bratus, M. D., Davydenko, M. M., Zinchuk, I. M., Kaliuzhnyi, V. A., Matviienko, O. D., Naumko, I. M., Pirozhyk, N. E., Redko, L. R., & Svoren, Y. M. (1994). Fliuidnyi rezhym mineraloutvorennia v litosferi (v zviazku z prohnozuvanniam korysnykh kopalyn). Kyiv: Naukova dumka. [in Ukrainian]

Dolenko, G. N. (1975). Sovremennoye sostoyaniye problemy proiskhozhdeniya nefti i gaza i formirovaniya ikh promyshlennykh zalezhey. In Zakonomernosti obrazovaniya i razmeshcheniya promyshlennykh mestorozhdeniy nefti i gaza (pp. 3–17). Kiev: Naukova dumka. [in Russian]

Naumko, I. M. (2006). Fliuidnyi rezhym mineralohenezu porodno-rudnykh kompleksiv Ukrainy (za vkliuchenniamy u mineralakh typovykh parahenezysiv) [Extended abstract of Doctorʼs thesis]. Instytut heolohii i heokhimii horiuchykh kopalyn NAN Ukrainy. Lviv. [in Ukrainian]

Naumko, I., & Svoren, Y. (2021). Innovatsiini tekhnolohii poshukiv korysnykh kopalyn, osnovani na doslidzhenniakh fliuidnykh vkliuchen u mineralakh. Heolohiia i heokhimiia horiuchykh kopalyn, 3–4(185–186), 92–108. https://doi.org/10.15407/ggcm2021.03-04.092 [in Ukrainian]

Pavliuk, I., Naumko, I., & Stefanyk, Yu. (2007, December 13). Heolohy-naukovtsi proty metanu-vbyvtsi. U Lvovi na Naukovii taky ye nauka. Ukraina i Chas, 50(286), 7.

Svoren, Y. M. (1975). Istochniki uglerodsoderzhashchikh gazov vklyucheniy. In Uglerod i ego soyedineniya v endogennykh protsessakh mineraloobrazovaniya (po dannym izucheniya flyuidnykh vklyucheniy v mineralakh): tezisy Respublikanskogo soveshchaniya (Lvov, sentyabr 1975 g.) (pp. 104–106). Lvov. [in Russian]

Svoren, I. M. (1984). Primesi gazov v kristallakh mineralov i drugikh tverdykh telakh, ikh sposoby izvlecheniya, sostav, forma nakhozhdeniya i vliyaniye na svoystva veshchestv [Extended abstract of Candidateʼs thesis]. Institut geologii i geokhimii goryuchikh iskopayemykh AN USSR. Lvov. [in Russian]

Svoren. I. M. (1988). Formy nakhozhdeniya vodoroda v nekotorykh tverdykh materialakh razlichnogo proiskhozhdeniya soglasno fiziko-khimicheskoy modeli navodorozhivaniya tverdykh tel. In Geokhimiya i termobarometriya endogennykh flyuidov (pp. 95–103). Kiev: Naukova dumka. [in Russian]

Svoren, Y. M. (1992). Pytannia teorii henezysu pryrodnykh vuhlevodniv ta shliakhy poshuku yikh pokladiv. In Tektohenez i naftohazonosnist nadr Ukrainy (pp. 143–145). Lviv. [in Ukrainian]

Svoren, Y. (2011). Nadra Zemli – pryrodnyi fizyko-khimichnyi reaktor: izotopy vuhletsiu pro pokhodzhennia planety Zemlia. Heolohiia i heokhimiia horiuchykh kopalyn, 1–2(154–155), 158–159. [in Ukrainian]

Svoren, Y. (2018). Vlastyvist hlybynnoho abiohennoho metanovmisnoho vysokotermobarnoho fliuidu utvoriuvaty vuhillia. Heolohiia i heokhimiia horiuchykh kopalyn, 3–4(176–177), 105–109. [in Ukrainian]

Svoren, Y. (2019). Nadra Zemli – pryrodnyi fizyko-khimichnyi reaktor: rizna khimichna vlastyvist izotopiv vuhletsiu u pryrodnykh protsesakh syntezu riznykh spoluk. In Problemy heolohii fanerozoiu Ukrainy: materialy X Vseukrainskoi naukovoi konferentsii (do 95-richchia kafedry istorychnoi heolohii ta paleontolohii i 120-richchia vid narodzhennia Severyna Ivanovycha Pasternaka (Lviv, 9–11 zhovtnia 2019 r.) (pp. 64–67). Lviv: LNU imeni Ivana Franka. [in Ukrainian]

Svoren, Y. (2020a). Nadra Zemli – pryrodnyi fizyko-khimichnyi reaktor: pryroda vody naftovykh i hazovykh rodovyshch. In Naftohazova haluz: Perspektyvy naroshchuvannia resursnoi bazy: materialy dopovidei Mizhnarodnoi naukovo-tekhnichnoi konferentsii (Ivano-Frankivsk, 8–9 hrudnia 2020 r.) (pp. 158–160). Ivano-Frankivsk: IFNTUNH. [in Ukrainian]

Svoren, J. M. (2020b). Subsoil Natural Physico-Chemical Reactor: Regularity of Natural Processes of Synthesis of Perfect Diamond Crystals. Journal of Geological Resource and Engineering, 8(4), 133–136. https://doi.org/10.17265/2328-2193/2020.04.005

Svoren, J. M. (2021). Subsoil Natural Physico-chemical Reactor: The Property of Deep Abiogenic Methane-Containing High-Thermobaric Fluid to Form Coal Seams. Journal of Geological Resource and Engineering, 9(1), 25–28. https://doi.org/10.17265/2328-2193/2021.01.003

Svoren, Y. M., & Davydenko, M. M. (1995). Termobarometriia i heokhimiia haziv prozhylkovo-vkraplenoi mineralizatsii u vidkladakh naftohazonosnykh oblastei i metalohenichnykh provintsii. Dopovidi NAN Ukrainy, 9, 72–73. [in Ukrainian]

Svoren, Y. M., Davydenko, M. M., Haievskyi, V. H., Krupskyi, Yu. Z., & Pelypchak, B. P. (1994). Perspektyvy termobarometrii i heokhimii haziv prozhylkovo-vkraplenoi mineralizatsii u vidkladakh naftohazonosnykh oblastei i metalohenichnykh provintsii. Heolohiia i heokhimiia horiuchykh kopalyn, 3–4(88–89), 54–63. [in Ukrainian]

Svoren, Y. M., & Naumko, I. M. (2003). Nova teoriia syntezu i henezysu vuhlevodniv u litosferi Zemli: abiohenno-biohennyi dualizm. In Mezhdunarodnaya konferentsiya “Krym–2003” (pp. 75–77). Simferopol. [in Ukrainian]

Svoren, Y. M., & Naumko, I. M. (2006). Nova teoriia syntezu i henezysu pryrodnykh vuhlevodniv: abiohenno-biohennyi dualizm. Dopovidi NAN Ukrainy, 2, 111–116. [in Ukrainian]


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GEOCHEMICAL PECULIARITIES OF NATURAL WATERS OF SE “SANATORIUM-RESORT MEDICAL CENTER “SHKLO” (LVIV REGION)

Home > Archive > No. 1 (178) 2019 > 74-82


Geology & Geochemistry of Combustible Minerals No. 1 (178) 2019, 74-82.

https://doi.org/10.15407/ggcm2019.01.074

Mariya KOST’, Halyna MEDVID, Vasyl HARASYMCHUK, Olha TELEGUZ, Iryna SAKHNYUK, Orysia MAJKUT

Institute of Geology and Geochemistry of Combustible Minerals of National Academy of Sciences of Ukraine, Lviv,
e-mail: igggk@mail.lviv.ua

Abstract

The geochemical features of natural waters of the SE “Sanatorium-resort medical center “Shklo” are established by researches of their ecological-geochemical composition and anthropogenic influence.
The mineral water “Naftusya-Shklo” from the pump room in the territory of the sanatorium is selected and analyzed, which is recognized as an analogous to water “Naftusya” by the biological action. The composition of water is hydrocarbonate sodium, having mine-ralization of 0.76 g/dm3, the total hardness of 0.55 mg-eq/dm3, sulfate content of 0.64 g/dm3, and Eh – −79 mV.
The sample of water from baths, which is fed from a depth of 129.0 m, is investigated. Therapeutic hydrogen sulfide water is classified as sodium salt-calcium sulfate with mineralization of 2.97 g/dm3 and high sulfate content (1.76 g/dm3). The balneological active component of the therapeutic water is hydrogen sulfide, the content of which is set at 101.75 mg/dm3. The common feature of these waters is the negative values of the oxidation-reduction potential, which is due to the presence of relatively high content of H2S and HS−.
In addition to the mineral, a sample of water from the water pipe (drinking water from the Opillia suite of the Lower Neogene) was studied. According to the salt composition, it refers to sulfate-hydrocarbonate sodium-calcium with mineralization of 0.53 g/dm3. The content of the determined macro- and microcomponents do not exceed the maximum permissible concentrations for drinking water, which indicates the absence of influence of the lower horizons.
The water sample was also selected from the largest lake of the park, the sanatorium “Shklo”, which is not related to reservoirs with a special regime of protection, therefore access to it is free. The salinity of water refers to chloride-sulfate-hydro carbonate sodium-calcium with mineralization of 0.35 g/dm3.
Two samples of water from the Shklo River after its leak from Yavoriv lake showed that these waters are weakly mineralized, weakly alkaline, calcium hydro carbonate sulfate or sulfate calcium. Quantitatively, sulfate ions are 2–3 times more than hydrocarbons. The content of sulfates, Sodium, Calcium, Magnesium is also high, indicating their contamination. Further down the salt content decreases as a result of mixing with the water of droplets. Several sources of supply of sulfate-ion can be named: karst waters formed on gypsum anhydrite; reservoir waters of the Upper Badenian limestones, hydrogen sulfur of the formation waters of the Badenian horizon; hydrogensulfur, formed as a result of reduction of sulfate at the bottom of Yavoriv lake. Ecological and geochemical parameters of water of surface water reservoirs and watercourses generally also correspond to state standards for their use as recreational.

Keywords

drinking water, ecological-geochemical parameters, anthropogen influence.

REFERENCES

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Derzhavne pidpryiemstvo “Sanatorno-kurortnyi likuvalnyi tsentr “Shklo”. (2018). Vziato z https://dsa.court.gov.ua/dsa/about_dsa/456/54675656. [in Ukrainian]

Haidin, A. M., Zozulia, I. I. (2007). Yavorivske ozero. Lviv: Afisha. [in Ukrainian]

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Pankiv, R. et al. (2009). Hidrokhimichna kharakterystyka transkordonnykh richok Yavorivshchyny. Heolohiia i heokhimiia horiuchykh kopalyn, 2 (147), 84–89. [in Ukrainian]

Shtohryn, O. D., & Havrylenko, K. S. (1968). Pidzemni vody zakhidnykh oblastei Ukrainy. Kyiv: Naukova dumka. [in Ukrainian]