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ON THE QUESTION OF THE INFLUENCE OF MIGRATING FLUIDS ON THE FORMATION CONDITIONS OF VEIN MINERALS OF THE UKRAINIAN CARPATHIANS

Home > Archive > No. 2 (202) 2026 > 98–110


Geology & Geochemistry of Combustible Minerals No. 2 (202) 2026, 98–110

ISSN 0869-0774 (Print), ISSN 2786-8621 (Online)

https://doi.org/10.15407/ggcm2026.202.098

Dina HOLOVCHENKO

State institution “Scientific Center of Mining Geology, Geoecology and infrastructure development of National Academy of Sciences of Ukraine”, Kyiv, Ukraine

e-mail: dinka666999@gmail.com, https://orcid.org/0009-0004-6206-6651


Abstract

Research on fluid migration, particularly hydrocarbon fluids, in various geological structures of Ukraine is one of the leading directions for determining their influence on the development and genesis of mineral deposits. The formation of vein mineral complexes is one of the indicators of post-formational processes of fluid transfer of matter and mechanisms of fracture healing in sedimentary rocks, and it is characteristic of the terrigenous flysch deposits of the Dukla and Krosno structural-facial units of the Ukrainian Carpathians. The formation of mineral veins represented by calcite and quartz, including the “Marmarosh diamonds” type, in the deposits of the region’s flysch formation during the Oligocene-Miocene period was influenced by regional fluid-dynamic processes. The formation of several generations of secondary inclusions in “Marmarosh diamonds” indicates that the transverse Rakhiv-Tysia deep fault, within the zone of influence of which the studied veins are located, developed under conditions of periodic stress release, resulting in the formation of fault dislocations. Considering the cyclical (stage-by-stage) process of filling fault dislocations with mineral matter, quartz crystals formed during the final stages of the vein structure development within the zone of influence of the Rakhiv-Tysia transverse deep fault. The results obtained allow for the determination of specific local and regional mineral formation trends characteristic of the Krosno and Dukla structural-tectonic zones. The data obtained from complex precision studies should be applied as a prospecting criterion for hydrocarbon accumulations within the region.

Keywords

vein minerals, fluid inclusions, hydrocarbons, Krosno zone, Dukla nappe, Rakhiv-Tysia deep fault, Ukrainian Carpathians

Referenses

Bratus, M. D., & Lomov, S. B. (1996). Umovy mineraloutvorennia ta izotopna pryroda komponentiv fliuidiv u zhylakh sered osadochnykh porid Skladchastykh Karpat. Heolohiia i heokhimiia horiuchykh kopalyn, 1–2(94–95), 85–95. [in Ukrainian]

Deer, W. A., Howie, R. A., & Zussman, J. (1966). An introduction to the rock-forming minerals (1st ed.). Harlow, UK: Longman Scientific and Technical Publishing.

Dudok, I. V. (1996). Hazovyi sklad vkliuchen u zhylnykh mineralakh z flishu Ukrainskykh Karpat. Heolohiia i heokhimiia horiuchykh kopalyn, 3–4(96–97), 98–104. [in Ukrainian]

Dudok, I. V., & Vovniuk, S. V. (2000). Heokhimiia izotopiv vuhletsiu i kysniu u zhylnykh utvorenniakh flishu Ukrainskykh Karpat. Heolohiia i heokhimiia horiuchykh kopalyn, 4, 30–37. [in Ukrainian]

Hnylko, O. M. (2012). Tektonichne raionuvannia Karpat u svitli tereinovoi tektoniky. Stattia 2. Flishovi Karpaty – davnia akretsiina pryzma. Heodynamika, 1(12), 67–78. https://doi.org/10.23939/jgd2012.01.067 [in Ukrainian]

Hnylko, O., Hnylko, S., Heneralova, L., Murovskaya, A., Bohdanova, M., Dvorzhak, O., & Navarivska, K. (2025). Junction area between the Western and Eastern Outer Carpathians (Ukraine) as the contact of two accretionary prisms: geological structure, sedimentary features and stratigraphy based on foraminifera. Geological Quarterly, 69(3), 29. https://doi.org/10.7306/gq.1802

Holovchenko, D. (2003). Typomorfni osoblyvosti kaltsytu z zhylnykh utvoren olihotsenovoho flishu Krosnenskoi zony Ukrainskykh Karpat. In Tezy dopovidei do VIII naukovoi konferentsii molodykh vchenykh ta spetsialistiv Instytutu heolohii i heokhimii horiuchykh kopalyn NAN Ukrainy ta NAK “Naftohaz Ukrainy” (pp. 47–50). Lviv. [in Ukrainian]

Holovchenko, D. M. (2004). Do pytannia pro mozhlyvist zastosuvannia deiakykh termobaroheokhimichnykh metodiv dlia vyrishennia problem poshukovoi heokhimii (na prykladi termobaroheokhimichnykh doslidzhen zhylnykh utvoren z flishovykh vidkladiv Krosnenskoi ta Duklianskoi strukturno-tektonichnykh odynyts Ukrainskykh Karpat). Poshukova ta ekolohichna heokhimiia, 4, 69–72. [in Ukrainian]

Holovchenko, D. M., & Kshanovska, T. O. (2004). Mineralnyi sklad ta poshyrennia karbonatnykh utvoren krosnenskoi svity Ukrainskykh Karpat. Mineralohichnyi zbirnyk, 54(2), 230–234. [in Ukrainian]

Holovchenko, D. M., Marusiak, V. P., & Popivniak, I. V. (2003). Marmaroski “diamanty” z karbonatnykh zhyl sela Kvasy (Rakhivskyi rudnyi raion, Zakarpattia). In Suchasni problemy heolohichnoi nauky: zbirnyk naukovykh prats Instytutu heolohichnykh nauk NAN Ukrainy (s. 202–204). Kyiv. [in Ukrainian]

Holovchenko, D., & Popivniak, I. (2009). Osoblyvosti mineralnoho skladu hidrotermalnykh zhyl u piskovykakh z okolyts s. Kvasy (Rakhivskyi rudnyi raion, Zakarpattia). Mineralohichnyi zbirnyk, 59(2), 143–148. [in Ukrainian]

Hopko, L. M., Datsiuk, Yu. R., Popivniak, I. V., Tsikhon, S. I., & Holovchenko, D. M. (2004). Doslidzhennia vuhletsmistiachykh teryhennykh porid luhivskoi svity (Rakhivskyi raion, Zakarpattia). Mineralohichnyi zbirnyk, 54(1), 137–142. [in Ukrainian]

Ivaniuta, M. M. (Ed.). (1998). Atlas rodovyshch nafty i hazu Ukrainy (Vol. 1–6). Lviv: Tsentr Yevropy. [in Ukrainian]

Kaliuzhnyi, V. A., & Sakhno, B. E. (1998). Perspektyvy prohnozuvannia korysnykh kopalyn za typomorfnymy oznakamy fliuidnykh vkliuchen vuhlevodniv ta vuhlets-dioksydu (Zakarpatskyi prohyn, Skladchasti Karpaty. Ukraina). Heolohiia i heokhimiia horiuchykh kopalyn, 3(104), 133–147. [in Ukrainian]

Kolodii, V. V. (Ed.). (2004). Karpatska naftohazonosna provintsiia. Lviv; Kyiv: Ukrainskyi vydavnychyi tsentr. [in Ukrainian]

Kruhlov, S. S., Arsirii, Yu. O., Velikanov, V. Ya., Znamenska, T. O., Lysak, A. M., Lukin, O. Yu., Shashkevych, I. K., Popadiuk, I. V., Radzivill, A. Ya., & Kholodnykh, A. B. (2007). Tektonichna karta Ukrainy. Masshtab 1 : 1 000 000. Poiasniuvalna zapyska (Part 1). Kyiv: UkrDHRI. [in Ukrainian]

Matkovskyi, O. I. (Ed.). (2003). Mineraly Ukrainskykh Karpat. Boraty, arsenaty, fosfaty, molibdaty, sulfaty, karbonaty, orhanichni mineraly i mineraloidy. Lviv: Vydavnychyi tsentr LNU imeni Ivana Franka. [in Ukrainian]

Matkovskyi, O. I. (Ed.). (2011). Mineraly Ukrainskykh Karpat. Sylikaty. Lviv: LNU imeni Ivana Franka. [in Ukrainian]

Matkovskyi, O. I. (Ed.). (2014). Mineraly Ukrainskykh Karpat. Protsesy mineraloutvorennia. Lviv: LNU imeni Ivana Franka. [in Ukrainian]

Matkovskyi, O., Naumko, I., Pavlun, M., & Slyvko, Ye. (2021). Termobaroheokhimiia v Ukraini. Lviv. [in Ukrainian]

Matskiv, B. V., Pukach, B. D., Vorobkanych, V. M., Pastukhanova, S. V., & Hnylko, O. M. (2009). Derzhavna heolohichna karta Ukrainy masshtabu 1 : 200 000, arkushi M 34 XXXVI (Khust), L 34 VI (Baia-Mare), M 35 XXXI (Nadvirna), L 35 I (Visheu-De-Sus). Karpatska seriia. Poiasniuvalna zapyska. Kyiv: UkrDHRI. [in Ukrainian]

Naumko, I. M. (2006). Fliuidnyi rezhym mineralohenezu porodno-rudnykh kompleksiv Ukrainy (za vkliuchenniamy u mineralakh typovykh parahenezysiv) [Extended abstract of Doctorʼs thesis, Institute of Geology and Geochemistry of Combustible Minerals of National Academy of Sciences of Ukraine]. Lviv. [in Ukrainian]

Naumko, I., Zankovych, H., Kokhan, O., Kuzemko, Ya., Sakhno, B., & Serkiz, R. (2022). Nerudni mineraly prozhylkovo-vkraplenoi mineralizatsii u vidkladakh Krosnenskoi zony Ukrainskykh Karpat (raion novoho Beskydskoho zaliznychnoho tuneliu). Heolohiia i heokhimiia horiuchykh kopalyn, 1–2(187–188), 103–114. https://doi.org/10.15407/ggcm2022.01-02.103 [in Ukrainian]

Naumko, I. M., Zankovych, H. O., Kuzemko, Ya. D., Diakiv, V. O., & Sakhno, B. E. (2017). Vuhlevodnevi hazy fliuidnykh vkliuchen u “marmaroskykh diamantakh” z zhyl u vidkladakh flishovoi formatsii raionu novoho Beskydskoho tuneliu (Krosnenska zona Ukrainskykh Karpat). Dopovidi NAN Ukrainy, 10, 70–77. https://doi.org/10.15407/dopovidi2017.10.070 [in Ukrainian]

Shlapinskyi, V. (2022). Deiaki pytannia tektoniky Ukrainskykh Karpat. Pratsi Naukovoho tovarystva  imeni Shevchenka. Heolohichnyi zbirnyk, 30, 100–118. [in Ukrainian]

Svoren, Y. M., & Naumko, I. M. (2005). Termobarometriia i heokhimiia haziv prozhylkovo-vkraplenoi mineralizatsii u vidkladakh naftohazonosnykh oblastei i metalohenichnykh provintsii – pryrodnyi fenomen litosfery Zemli. Dopovidi NAN Ukrainy, 2, 109–113. [in Ukrainian]

Tretiak, K. R., Maksymchuk, V. Yu., Kutas, R. I., Rokytianskyi, I. I., Hnylko, O. M., Kendzera, O. V., Pronyshyn, R. S., Klymkovych, T. A., Kuznietsova, V. H., Marchenko, D. O., Smirnova, O. M., Serant, O. V., Babak, V. I., Vovk, A. I., Romaniuk, V. V., & Tereshyn, A. V. (2015). Suchasna heodynamika i heofizychni polia Karpat ta sumizhnykh terytorii. Lviv: Vydavnytstvo Lvivskoi politekhniky. [in Ukrainian]

Vovk, O. P., Naumko, I. M., & Zankovych, H. O. (2025). Psevdosymetriia krystaliv kvartsu ta yii mineraloho-henetychne znachennia. Mineralohichnyi zhurnal, 47(1), 33–44. https://doi.org/10.15407/mineraljournal.47.01.033 [in Ukrainian]

Vovk, O., Naumko, I., Zankovych, H., & Kuzemko, Ya. (2022). Comparison of morphology of guartz crystals – “Marmarosh diamonds” – from Paleogene Flysch sequences of Krosno (Silesian) Zone, Dukla Zone in Ukrainian Carpathians, and Intra-Carpathian sequences of Western Carpathians. Mineralia Slovaca, 54(2), 163–174. https://doi.org/10.56623/ms.2022.54.2.3

Zankovych, H. O. (2016). Heokhimiia fliuidiv prozhylkovo-vkraplenoi mineralizatsii perspektyvno naftohazonosnykh kompleksiv pivnichno-zakhidnoi chastyny Krosnenskoi zony Ukrainskykh Karpat [Extended abstract of Candidateʼs thesis, Institute of Geology and Geochemistry of Combustible Minerals of the National Academy of Sciences of Ukraine]. Lviv. [in Ukrainian]


Received: April 24, 2026
Accepted: May 11, 2026
Published: May 29, 2026

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NON-ORE MINERALS OF VEINLET-IMPREGNATED MINERALIZATION IN THE DEPOSITS OF THE KROSNO ZONE OF THE UKRAINIAN CARPATHIANS (district of the new Beskydy railway tunnel)

Home > Archive > No. 1–2 (187–188) 2022 > 103–114


Geology & Geochemistry of Combustible Minerals No. 1–2 (187–188) 2022, 103–114.

https://doi.org/10.15407/ggcm2022.01-02.103

Ihor NAUMKO1, Halyna ZANKOVYCH1, Oksana KOКHAN1, Olexandеr VOVK2, Yaroslav KUZEMKO1, Bohdan SAКHNO1, Roman SERKIZ3

1 Institute of Geology and Geochemistry of Combustible Minerals of National Academy of Sciences of Ukraine, Lviv, Ukraine, e-mail: igggk@mail.lviv.ua
2 Lesya Ukrainka Volyn National University, Lutsk, Ukraine, е-mail: geologygeochemistry@gmail.com
3 Ivan Franko National University of Lviv, Lviv, Ukraine, е-mail: rserkiz@gmail.com

Abstract

The construction of the new Beskydy railway tunnel, which revealed the indigenous deposits of the Krosno formation of the Ukrainian Carpathians, provided an opportunity to obtain new results from the study of another prospective oil and gas-bearing areas of the flysch formation within the Krosno structural-facies unit. There is a second tunnel in length in Ukraine and passes under the Verkhovyna watershed ridge of the Ukrainian Carpathians. Its section is represented by the rocks of the Krosno formation, namely the stratification of sandstones, argillites and silt stones. There are two fracture zones have been indentified here, in which developed veinle-impregnated mineralization of ore (sulfides) and non-ore (calcite and quartz type of the “Marmarosh diamonds”) minerals. Calcite and quartz formas monominerals veins and in paragenesis calcite-quartz type of the “Marmarosh diamonds” ‒ sulfides. Quartz occurs in the form of splice sand well-faceted crystals, transparent, in yellow, brown, black, green colour. Calcite of a milky, translucent colour in the form of veins, veinlets, impregnation, powder on quartz, druz. Contains significant impurities of magnesium, manganese and iron which means the presence of a rhodochrosite-magnesite-siderite component. Hydrocarbon fluids are present in all calcite and quartz crystals of the “Marmarosh diamonds” type. By chemical composition, it is methane with impurities of higher hydrocarbons (up to hexane). Sometimes the manifestations of the outflow of a black substance with the smell of oil from the cracks in the veinlet-impregnated mineralization are recorded studied rock complexes of the flysch formation of the Krosno zone of the Ukrainian Carpathians (construction area of the new branch of the Beskydy railway tunnel), which acquires an important genetic significance.

Keywords

veinlet-impregnated mineralization, calcite, “Marmarosh diamonds”, new Beskydy railway tunnel, Krosno zone, Ukrainian Carpathians

Referenses

Beskydskyi tunel. (2021, 9 hrudnia). In Vikipediia. https://uk.wikipedia.org/wiki/Beskydskyi_tunel [in Ukrainian]

Hnylko, O. (2010). Pro pivnichno-skhidnu hranytsiu Krosnenskoi tektonichnoi zony v Ukrainskykh Karpatakh. Heolohiia i heokhimiia horiuchykh kopalyn, 2(151), 44–57. [in Ukrainian]

Hulii, V., Kuzemko, Ya., Stepanov, V., Petruniak, H., Menshov, O., & Ohorilko, R. (2015). Heoloho-strukturni osoblyvosti ta rechovynnyi sklad porid Krosnenskoi zony v raioni novoho Beskydskoho tuneliu. In Fundamentalne znachennia i prykladna rol heolohichnoi osvity i nauky: tezy dopovidei Mizhnarodnoi naukovoi konferentsii, prysviachenoi 70-richchiu heolohichnoho fakultetu Lvivskoho natsionalnoho universytetu imeni Ivana Franka (Lviv, 7–9 zhovtnia 2015 r.) (pp. 69–71). Lviv: Vydavnychyi tsentr LNU imeni Ivana Franka. [in Ukrainian]

Naumko, I. M., Zankovych, H. O., Kuzemko, Ya. D., Diakiv, V. O., Sakhno, B. E. (2017). Vuhlevodnevi hazy fliuidnykh vkliuchen u “marmaroskykh diamantakh” z zhyl u vidkladakh flishovoi formatsii raionu novoho Beskydskoho tuneliu (Krosnenska zona Ukrainskykh Karpat). Dopovidi NAN Ukrainy, 10, 70–77. https://doi.org/10.15407/dopovidi2017.10.070 [in Ukrainian]

Svoren, Y. M., & Naumko, I. M. (2005). Termobarometriia i heokhimiia haziv prozhylkovo-vkraplenoi mineralizatsii u vidkladakh naftohazonosnykh oblastei i metalohenichnykh provintsii – pryrodnyi fenomen litosfery Zemli. Dopovidi NAN Ukrainy, 2, 109–113. [in Ukrainian]

Vovk, O., Zankovych, H., & Naumko I. (2018). Osoblyvosti krystalomorfolohii marmaroskykh «diamantiv» iz zhyl u flishovykh vidkladakh Krosnenskoi strukturno-fatsialnoi odynytsi Ukrainskykh Karpat (raion novoho Beskydskoho tuneliu). Mineralohichnyi zbirnyk, 68(1), 72–75. [in Ukrainian]

Vovk, O. P., Zankovych, H. O., & Naumko, I. M. (2019). Materialy do porivnialnoi kharakterystyky krystalomorfolohii “marmaroskykh diamantiv” Ukrainskykh i Slovatskykh Karpat. In Zdobutky i perspektyvy rozvytku heolohichnoi nauky v Ukraini: zbirnyk tez naukovoi konferentsii, prysviachenoi 50-richchiu Instytutu heokhimii, mineralohii ta rudoutvorennia imeni M. P. Semenenka NAN Ukrainy (Kyiv, 14–16 travnia 2019 r.) (Vol. 1, pp. 130–131). Kyiv. [in Ukrainian]

Zankovych, H. O. (2016). Heokhimiia fliuidiv prozhylkovo-vkraplenoi mineralizatsii perspektyvno naftohazonosnykh kompleksiv pivnichno-zakhidnoi chastyny Krosnenskoi zony Ukrainskykh Karpat [Extended abstract of Candidateʼs thesis]. Instytut heolohii i heokhimii horiuchykh kopalyn NAN Ukrainy. Lviv. [in Ukrainian]

Zankovych, H. O., & Cheremisska, O. M. (2021). Typy vtorynnoi mineralizatsii v kreidovo-paleohen-neohenovykh vidkladakh Krosnenskoi zony Ukrainskykh Karpat. In Scientific Trends and Trends in the Context of Clobalization: III International Scientific and Practical Conference (Umea, Kingdom of Sweden, December 21–22, 2021) (pp.  74–379). Umea. [in Ukrainian]

Zankovych, H. O., & Kokhan, O. M. (2021). Nerudni mineraly prozhylkovo-vkraplenoi mineralizatsii Beskydskoho tuneliu Krosnenskoi zony Ukrainskykh Karpat. In Heolohichna nauka v nezalezhnii Ukraini: zbirnyk tez naukovoi konferentsii (Kyiv, 8–9 veresnia 2021 r.) (pp. 282–284). Kyiv. [in Ukrainian]