Posted on

NON-ORE MINERALS OF VEINLET-IMPREGNATED MINERALIZATION IN THE DEPOSITS OF THE KROSNO ZONE OF THE UKRAINIAN CARPATHIANS (district of the new Beskydy railway tunnel)

Home > Archive > No. 1–2 (187–188) 2022 > 103–114


Geology & Geochemistry of Combustible Minerals No. 1–2 (187–188) 2022, 103–114.

https://doi.org/10.15407/ggcm2022.01-02.103

Ihor NAUMKO1, Halyna ZANKOVYCH1, Oksana KOКHAN1, Olexandеr VOVK2, Yaroslav KUZEMKO1, Bohdan SAКHNO1, Roman SERKIZ3

1 Institute of Geology and Geochemistry of Combustible Minerals of National Academy of Sciences of Ukraine, Lviv, Ukraine, e-mail: igggk@mail.lviv.ua
2 Lesya Ukrainka Volyn National University, Lutsk, Ukraine, е-mail: geologygeochemistry@gmail.com
3 Ivan Franko National University of Lviv, Lviv, Ukraine, е-mail: rserkiz@gmail.com

Abstract

The construction of the new Beskydy railway tunnel, which revealed the indigenous deposits of the Krosno formation of the Ukrainian Carpathians, provided an opportunity to obtain new results from the study of another prospective oil and gas-bearing areas of the flysch formation within the Krosno structural-facies unit. There is a second tunnel in length in Ukraine and passes under the Verkhovyna watershed ridge of the Ukrainian Carpathians. Its section is represented by the rocks of the Krosno formation, namely the stratification of sandstones, argillites and silt stones. There are two fracture zones have been indentified here, in which developed veinle-impregnated mineralization of ore (sulfides) and non-ore (calcite and quartz type of the “Marmarosh diamonds”) minerals. Calcite and quartz formas monominerals veins and in paragenesis calcite-quartz type of the “Marmarosh diamonds” ‒ sulfides. Quartz occurs in the form of splice sand well-faceted crystals, transparent, in yellow, brown, black, green colour. Calcite of a milky, translucent colour in the form of veins, veinlets, impregnation, powder on quartz, druz. Contains significant impurities of magnesium, manganese and iron which means the presence of a rhodochrosite-magnesite-siderite component. Hydrocarbon fluids are present in all calcite and quartz crystals of the “Marmarosh diamonds” type. By chemical composition, it is methane with impurities of higher hydrocarbons (up to hexane). Sometimes the manifestations of the outflow of a black substance with the smell of oil from the cracks in the veinlet-impregnated mineralization are recorded studied rock complexes of the flysch formation of the Krosno zone of the Ukrainian Carpathians (construction area of the new branch of the Beskydy railway tunnel), which acquires an important genetic significance.

Keywords

veinlet-impregnated mineralization, calcite, “Marmarosh diamonds”, new Beskydy railway tunnel, Krosno zone, Ukrainian Carpathians

Referenses

Beskydskyi tunel. (2021, 9 hrudnia). In Vikipediia. https://uk.wikipedia.org/wiki/Beskydskyi_tunel [in Ukrainian]

Hnylko, O. (2010). Pro pivnichno-skhidnu hranytsiu Krosnenskoi tektonichnoi zony v Ukrainskykh Karpatakh. Heolohiia i heokhimiia horiuchykh kopalyn, 2(151), 44–57. [in Ukrainian]

Hulii, V., Kuzemko, Ya., Stepanov, V., Petruniak, H., Menshov, O., & Ohorilko, R. (2015). Heoloho-strukturni osoblyvosti ta rechovynnyi sklad porid Krosnenskoi zony v raioni novoho Beskydskoho tuneliu. In Fundamentalne znachennia i prykladna rol heolohichnoi osvity i nauky: tezy dopovidei Mizhnarodnoi naukovoi konferentsii, prysviachenoi 70-richchiu heolohichnoho fakultetu Lvivskoho natsionalnoho universytetu imeni Ivana Franka (Lviv, 7–9 zhovtnia 2015 r.) (pp. 69–71). Lviv: Vydavnychyi tsentr LNU imeni Ivana Franka. [in Ukrainian]

Naumko, I. M., Zankovych, H. O., Kuzemko, Ya. D., Diakiv, V. O., Sakhno, B. E. (2017). Vuhlevodnevi hazy fliuidnykh vkliuchen u “marmaroskykh diamantakh” z zhyl u vidkladakh flishovoi formatsii raionu novoho Beskydskoho tuneliu (Krosnenska zona Ukrainskykh Karpat). Dopovidi NAN Ukrainy, 10, 70–77. https://doi.org/10.15407/dopovidi2017.10.070 [in Ukrainian]

Svoren, Y. M., & Naumko, I. M. (2005). Termobarometriia i heokhimiia haziv prozhylkovo-vkraplenoi mineralizatsii u vidkladakh naftohazonosnykh oblastei i metalohenichnykh provintsii – pryrodnyi fenomen litosfery Zemli. Dopovidi NAN Ukrainy, 2, 109–113. [in Ukrainian]

Vovk, O., Zankovych, H., & Naumko I. (2018). Osoblyvosti krystalomorfolohii marmaroskykh «diamantiv» iz zhyl u flishovykh vidkladakh Krosnenskoi strukturno-fatsialnoi odynytsi Ukrainskykh Karpat (raion novoho Beskydskoho tuneliu). Mineralohichnyi zbirnyk, 68(1), 72–75. [in Ukrainian]

Vovk, O. P., Zankovych, H. O., & Naumko, I. M. (2019). Materialy do porivnialnoi kharakterystyky krystalomorfolohii “marmaroskykh diamantiv” Ukrainskykh i Slovatskykh Karpat. In Zdobutky i perspektyvy rozvytku heolohichnoi nauky v Ukraini: zbirnyk tez naukovoi konferentsii, prysviachenoi 50-richchiu Instytutu heokhimii, mineralohii ta rudoutvorennia imeni M. P. Semenenka NAN Ukrainy (Kyiv, 14–16 travnia 2019 r.) (Vol. 1, pp. 130–131). Kyiv. [in Ukrainian]

Zankovych, H. O. (2016). Heokhimiia fliuidiv prozhylkovo-vkraplenoi mineralizatsii perspektyvno naftohazonosnykh kompleksiv pivnichno-zakhidnoi chastyny Krosnenskoi zony Ukrainskykh Karpat [Extended abstract of Candidateʼs thesis]. Instytut heolohii i heokhimii horiuchykh kopalyn NAN Ukrainy. Lviv. [in Ukrainian]

Zankovych, H. O., & Cheremisska, O. M. (2021). Typy vtorynnoi mineralizatsii v kreidovo-paleohen-neohenovykh vidkladakh Krosnenskoi zony Ukrainskykh Karpat. In Scientific Trends and Trends in the Context of Clobalization: III International Scientific and Practical Conference (Umea, Kingdom of Sweden, December 21–22, 2021) (pp.  74–379). Umea. [in Ukrainian]

Zankovych, H. O., & Kokhan, O. M. (2021). Nerudni mineraly prozhylkovo-vkraplenoi mineralizatsii Beskydskoho tuneliu Krosnenskoi zony Ukrainskykh Karpat. In Heolohichna nauka v nezalezhnii Ukraini: zbirnyk tez naukovoi konferentsii (Kyiv, 8–9 veresnia 2021 r.) (pp. 282–284). Kyiv. [in Ukrainian]


Posted on

GEOCHEMISTRY Of FLUIDS: INNOVATIVE SOLUTION OF THE FUNDAMENTAL PROBLEM

Home > Archive > No. 1–2 (183–184) 2021 > 130–148


Geology & Geochemistry of Combustible Minerals No. 1–2 (183–184) 2021, 130–148.

https://doi.org/10.15407/ggcm2021.01-02.130

Josyp SVOREN

Institute of Geology and Geochemistry of Combustible Minerals of National Academy of Sciences of Ukraine, Lviv, e-mail: igggk@mail.lviv.ua

Abstract

First of all, has developed a reliable mass spectrometric method for studying fluid inclusions in minerals (on the basis of the author’s certificate of the USSR No. 454446 of 1974 for the invention of the “device for cleaning the content inclusions of solid materials”). Were created and published new scientific directions: 1. Thermobarometry and geochemistry of gases of veinlet-impregnated mineralization in sediments of oil and gas regions and metallogenic provinces. 2. Bowels of the Earth – natural physicochemical reactor. Was developed a “method (technology) for determining the prospects of oil and gas bearing of the local area” and “a method (technology) of local forecasting of enriched areas of gold-ore fields” (together with M. M. Davydenko). Was established unknown before, but objectively existing phenomenon of the material world: 1) “lack of molecular hydrogen in inclusions in minerals in the bowels of the planet Earth” (together with V. A. Kaliuzhny). Independently were established: 2) previously unknown “property of deep abiogenic methane-termobar high-temperature fluid decompose-convert natural organic residues into layers of coal with their simultaneous methane saturation and its conservation in the earth’s crust of the planet Earth”; 3) previously unknown natural “phenomenon of arbitrary formation of natural carbon methane in the coal layers of the earth’s crust of the planet Earth under the influence of abiogenic methane-containing high-temperature fluid with their conservation in them”; 4) previously unknown different chemical properties of carbon isotopes in natural processes of synthesis-formation of various carbon-containing compounds …; 5) “previously unknown pattern of natural processes of synthesis of perfect diamond crystals from astenospheric carbon dioxide ions…”. Was justified “a new way to determine the calorification of natural gas supplied to consumers and its cubic-metre barometry”.

Keywords

geochemistry, fluid inclusions, veinlet-impregnated mineralization, deep abiogenic methane-bearing high-termobaric fluid, searches, new technologies, cubic-metre-barometry, scientific discovery.

Referenses

Davydenko, M. M., & Svoren, Y. M. (1994). Sposib lokalnoho prohnozuvannia zbahachenykh dilianok zolotorudnykh poliv (Patent Ukrainy № 5G01V9/00). Promyslova vlasnist, 3, 27. [in Ukrainian]

Naumko, I. M. (2006). Fliuidnyi rezhym mineralohenezu porodno-rudnykh kompleksiv Ukrainy (za vkliuchenniamy u mineralakh typovykh parahenezysiv) [Extended abstract of Doctorʼs thesis]. Instytut heolohii i heokhimii horiuchykh kopalyn NAN Ukrainy. Lviv. [in Ukrainian]

Naumko, I. M., Bekesha, S. M., & Svoren, Y. M. (2008). Fliuidy hlybynnykh horyzontiv litosfery: zviazok z rodovyshchamy nafty i hazu u zemnii kori (za danymy vyvchennia vkliuchen u mineralakh hlybynnoho pokhodzhennia). Dopovidi Natsionalnoi akademii nauk Ukrainy, 8, 117–120. [in Ukrainian]

Naumko, I. M., & Kaliuzhnyi, V. A. (2001). Pidsumky ta perspektyvy doslidzhen termobarometrii i heokhimii paleofliuidiv litosfery (za vkliuchenniamy u mineralakh). Heolohiia i heokhimiia horiuchykh kopalyn, 2, 162–175. [in Ukrainian]

Naumko, I., Kaliuzhnyi, V., Bratus, M., Zinchuk, I., Kovalyshyn, Z., Matviienko, O., Redko, L., & Svoren, Y. (2000). Uchennia pro mineralotvorni fliuidy: priorytetni zavdannia rozvytku na suchasnomu etapi. Mineralohichnyi zbirnyk, 50(2), 22–30. [in Ukrainian]

Naumko, I., Pavliuk, M., & Poberezhskyi, A. (2020). Heokhimiia i termobarometriia mineraloutvoriuvalnykh fliuidiv ta termobaroheokhimiia evaporytiv – vsesvitno vidomi naukovi shkoly. Heolohiia i heokhimiia horiuchykh kopalyn, 1(182), 62–75. https://doi.org/10.15407/ggcm2020.01.062 [in Ukrainian]

Naumko, I. M., & Svoren, Y. M. (2008). Pro shliakhy vtilennia hlybynnoho vysokotemperaturnoho fliuidu u zemnu koru. Dopovidi Natsionalnoi akademii nauk Ukrainy, 9, 112–114. [in Ukrainian]

Pavlyshyn, V. I., Bondarenko, S. M., Bryk, O. B., Vozniak, D. K., Yelchenko, K. O., Kalinichenko, A. M., Kvasnytsia, V. M., Kulchytska, H. O., Lupashko, T. M., Naumko, I. M., Semenenko, V. P., Taran, M. M., Tarashchan, A. M., Khomenko, V. M., & Chernysh, D. S. (2018). Mineralohiia u Natsionalnii akademii nauk Ukrainy (do 100-richchia NAN Ukrainy). Mineralohichnyi zhurnal, 40(3), 3–22. https://doi.org/10.15407/mineraljournal.40.03.003 [in Ukrainian]

Svoren’, I. M. (1974). Ustroistvo dlya ochistki soderzhimogo vklyuchenii tverdykh materialov (Avtorskoe svidetel’stvo SSSR № 454446). Byulleten’, 47. [in Russian]

Svoren’, I. M. (1984). Primesi gazov v kristallakh mineralov i drugikh tverdykh telakh, ikh sposoby izvlecheniya, sostav, forma nakhozhdeniya i vliyanie na svoistva veshchestv [Extended abstract of сandidateʼs thesis]. Institut geologii i geokhimii goryuchikh iskopaemykh AN USSR. L’vov. [in Russian]

Svoren, Y. M. (1992). Pytannia teorii henezysu pryrodnykh vuhlevodniv ta shliakhy poshuku yikh pokladiv. In Tektohenez i naftohazonosnist nadr Ukrainy: tezy dopovidei naukovoi narady (20–22 zhovtnia 1992 r.) (pp. 143–145). Lviv. [in Ukrainian]

Svoren, Y. M. (2008). Termobarometriia i heokhimiia haziv prozhylkovo-vkraplenoi mineralizatsii u vidkladakh naftohazonosnykh oblastei i metalohenichnykh provintsii: pryroda vuhilnoho metanu. Ugol’ Ukrainy, 8(620), 42–46. [in Ukrainian]

Svoren, Y. (2011a). Nadra Zemli – pryrodnyi fizyko-khimichnyi reaktor: izotopy vuhletsiu pro pokhodzhennia planety Zemlia. Heolohiia i heokhimiia horiuchykh kopalyn, 1–2(154–155), 158–159. [in Ukrainian]

Svoren, Y. (2011b). Nadra Zemli – pryrodnyi fizyko-khimichnyi reaktor: pryroda zemletrusu. Heolohiia i heokhimiia horiuchykh kopalyn, 1–2(154–155), 160–162. [in Ukrainian]

Svoren, Y. (2017a). Nadra Zemli – pryrodnyi fizyko-khimichnyi reaktor: pryrodnyi vuhlevodnevyi fenomen. Heolohiia i heokhimiia horiuchykh kopalyn, 1–2(170–171), 157–160. [in Ukrainian]

Svoren, Y. (2017b). Yavyshche utvorennia pryrodnykh vuhlemetaniv pid diieiu abiohennoho metanovmistnoho vysokotermobarnoho hlybynnoho fliuidu. In Heolohiia horiuchykh kopalyn: dosiahnennia ta perspektyvy: materialy II Mizhnarodnoi naukovoi konferentsii (Kyiv, 6–8 veresnia 2017 r.) (pp. 225–229). Kyiv. [in Ukrainian]

Svoren, Y. (2019a). Nadra Zemli – pryrodnyi fizyko-khimichnyi reaktor: poshuk pryrodnoho metanu – fundamentalna nauka chy tekhnichna problema? Heolohiia i heokhimiia horiuchykh kopalyn, 4(181), 104–115. https://doi.org/10.15407/ggcm2019.04.104 [in Ukrainian]

Svoren, Y. (2019b). Pro novyi pidkhid do vyznachennia teplotvornosti pryrodnoho hazu, yakyi postachaiut spozhyvacham ta yoho kubometrobarometriiu. Heolohiia i heokhimiia horiuchykh kopalyn, 2(179), 84–89. https://doi.org/10.15407/ggcm2019.02.084 [in Ukrainian]

Svoren, Y. (2020a). Nadra Zemli – pryrodnyi fizyko-khimichnyi reaktor: pryroda vody naftovykh i hazovykh rodovyshch. In Naftohazova haluz: Perspektyvy naroshchuvannia resursnoi bazy: materialy dopovidei Mizhnarodnoi naukovo-tekhnichnoi konferentsii (Ivano-Frankivsk, 08–09 hrudnia 2020 r.) (pp. 158–160). [in Ukrainian]

Svoren, Y. (2020b). Pro znachennia kubometrobarometrii pryrodnoho hazu, yakyi postachaiut spozhyvacham. In Naftohazova haluz: Perspektyvy naroshchuvannia resursnoi bazy: materialy dopovidei Mizhnarodnoi naukovo-tekhnichnoi konferentsii (Ivano-Frankivsk, 08–09 hrudnia 2020 r.) (pp. 91–94). [in Ukrainian]

Svoren’, J. M. (2020c). Subsoil Natural Physico-Chemical Reactor: Regularity of Natural Processes of Synthesis of Perfect Diamond Crystals. Journal of Geological Resource and Engineering, 8, 133–136. https://doi.org/10.17265/2328-2193/2020.04.005

Svoren’, J. M. (2020d). Various Chemical Properties of Carbon Isotopes in Natural Synthesis of Different Compounds. Journal of Geological Resource and Engineering, 8, 20–23. https://doi.org/10.17265/2328-2193/2020.01.002

Svoren’, J. M. (2021). Subsoil Natural Physico-chemical Reactor: The Property of Deep Abiogenic Methane-Containing High-Thermobaric Fluid to Form Coal Seams. Journal of Geological Resource and Engineering, 9, 25–28. https://doi.org/10.17265/2328-2193/2021.01.003

Svoren, Y. M., & Davydenko, M. M. (1994). Sposib vyznachennia perspektyvy naftohazonosnosti lokalnoi ploshchi (Patent Ukrainy № 5G01V9/00). Promyslova vlasnist, 4. [in Ukrainian]

Svoren, Y. M., Davydenko, M. M., Haievskyi, V. H., Krupskyi, Yu. Z., & Pelypchak, B. P. (1994). Perspektyvy termobarometrii i heokhimii haziv prozhylkovo-vkraplenoi mineralizatsii u vidkladakh naftohazonosnykh oblastei i metalohenichnykh provintsii (novyi naukovyi napriamok v heolohii). Heolohiia i heokhimiia horiuchykh kopalyn, 3–4(88–89), 54–63. [in Ukrainian]

Svoren, Y. M., & Naumko, I. M. (2000). Nova tekhnolohiia vyznachennia henezysu vuhlevodnevykh haziv. In Nafta i haz Ukrainy–2000: materialy VI Mizhnarodnoi naukovo-praktychnoi konferentsii (Ivano-Frankivsk, 31 zhovtnia–3 lystopada 2000 r.) (Vol. 1, pp. 108). Ivano-Frankivsk: Fakel. [in Ukrainian]

Svoren, Y. M., & Naumko, I. M. (2006a). Nova teoriia syntezu i henezysu pryrodnykh vuhlevodniv: abiohenno-biohennyi dualizm. Dopovidi Natsionalnoi akademii nauk Ukrainy, 2, 111–116. [in Ukrainian]

Svoren, Y. M., & Naumko, I. M. (2006b). Rol riznykh form vodniu ta vuhletsiu v pryrodnykh protsesakh: novyi pohliad na pokhodzhennia vuhlevodniv. Dopovidi Natsionalnoi akademii nauk Ukrainy, 1, 131–134. [in Ukrainian]