fluid inclusions – Geology and Geochemistry of Combustible Minerals

Posted on December 2023February 2024 by GGCMJournal

ON THE SIGNIFICANCE OF NATURAL CARBONATES IN THE PROCESSES OF SYNTHESIS AND GENESIS OF HYDROCARBONS IN THE EARTH’S LITHOSPHERE

Home > Archive > No. 3–4 (191–192) 2023 > 135–142

Geology & Geochemistry of Combustible Minerals No. 3–4 (191–192) 2023, 135–142

https://doi.org/10.15407/ggcm2023.191-192.135

Josyp SVOREN’
Institute of Geology and Geochemistry of Combustible Minerals of National Academy of Sciences of Ukraine, Lviv, Ukraine, e-mail: igggk@mail.lviv.ua

Abstract

The fundamental importance of studies of the processes of synthesis and genesis of hydrocarbons in the Earth’s lithosphere has been confirmed and the prospects of the chosen direction for advanced research have been demonstrated, as well as for the thorough development of genetic principles of physical and chemical conditions of the formation of hydrocarbons deposits in various geological minds, focusing on the role of natural carbonate formation in this process. It is shown in this connection that one of the most striking natural phenomena of the Earth’s lithosphere is the obvious manifestations of veinlet-impregnated carbonate mineralization. This has been discussed in detail in the case of some areas of the Ukrainian Carpathians and Pre-Сarpathians, where the original carbonate veinlets of hydrothermal origin with traces of hydrocarbons migration are often happened, but industrial research works is rarely carried out because of their low (as expected) prospects for gas and oil deposits. We pay attention to the areas of development of the calcite veinlets with rare, perfectly faceted crystals of quartz – “Marmarosh diamonds” among the Cretaceous and Paleogene deposits of the South-Western slope of the Carpathians.

As a result, supporting materials on the importance of natural carbonates in the processes of synthesis and genesis of hydrocarbons in the Earth’s lithosphere are given. It consists in the revealed previously unknown property of natural carbonates, mainly calcium carbonate, under the action of abiogenic high-thermobaric deep fluid to decompose and be an additional source of carbon with different isotopic compositions in the processes of synthesis and genesis of hydrocarbons: gas, oil, bitumen as well as a carrier of these compounds in time of their migration and conservation in new creations in the deposits of oil and gas-bearing areas and metallogenic provinces: deposits-fields, veins, fluid inclusions, veinlet-impregnated mineralization.

Full Text

Keywords

fluid inclusions, carbonates, veins, hydrocarbons, deposits, gas and oil, mass spectrometric studies, supposed scientific discovery

Referenses

Biletskyi, V. C. (Red.). (2004). Mala hirnycha entsyklopediia: Vol. 1. A–K. Donetsk: Donbas. [in Ukrainian]

Bratus, M. D., Davydenko, M. M., Zinchuk, I. M., Kaliuzhnyi, V. A., Matviienko, O. D., Naumko, I. M., Pirozhyk, N. E., Redko, L. R., & Svoren, Y. M. (1994). Fliuidnyi rezhym mineraloutvorennia v litosferi (v zviazku z prohnozuvanniam korysnykh kopalyn). Kyiv: Naukova dumka. [in Ukrainian]

Lazarenko, Ye. K., & Vynar, O. M. (1975). Mineralohichnyi slovnyk. Kyiv: Naukova dumka. [in Ukrainian]

Matkovskyi, O. I. (Hol. red.). (2003). Mineraly Ukrainskykh Karpat. Boraty, arsenaty, fosfaty, molibdaty, sulfaty, karbonaty, orhanichni mineraly i mineraloidy. Lviv: Vydavnychyi tsentr LNU im. Ivana Franka. [in Ukrainian]

Matkovskyi, O., Naumko, I., Pav lun, M., & Slyvko, Ye. (2021). Termobaroheokhimiia v Ukraini. Lviv: Prostir-M. [in Ukrainian]

Naumko, I. M. (2006). Fliuidnyi rezhym mineralohenezu porodno-rudnykh kompleksiv Ukrainy (za vkliuchenniamy u mineralakh typovykh parahenezysiv) [Extended abstract of Doctorʼs thesis, Institute of Geology and Geochemistry of Combustible Minerals of National Academy of Sciences of Ukraine]. Lviv. [in Ukrainian]

Naumko I., Bratus M., Dudok I., Kaliuzhnyi V., Kovalyshyn Z., Sakhno B., Svoren Y., & Telepko L. (2004). Fliuidnyi rezhym katahenno-hidrotermalnoho protsesu periodu formuvannia zhylnoi, prozhylkovoi i prozhylkovo-vkraplenoi mineralizatsii v osadovykh tovshchakh. In V. V. Kolodii (Ed.), Karpatska naftohazonosna provintsiia (pp. 308–345). Lviv; Kyiv: Ukrainskyi vydavnychyi tsentr. [in Ukrainian]

Naumko, I. M., & Svoren, Y. M. (2008). Pro shliakhy vtilennia hlybynnoho vysokotemperaturnoho fliuidu v zemnu koru. Dopovidi NAN Ukrainy, 9, 112–114. [in Ukrainian]

Svoren, I. M. (1984). Primesi gazov v kristallakh mineralov i drugikh tverdykh telakh, ikh sposoby izvlecheniya, sostav, forma nakhozhdeniya i vliyaniye na svoystva veshchestv [Extended abstract of Candidateʼs thesis. Institute of Geology and Geochemistry of Combustible Minerals of National Academy of Sciences of Ukraine]. Lvov. [in Russian]

Svoren, I. M. (1988). Formy nakhozhdeniya vodoroda v nekotorykh tverdykh materialakh razlichnogo proiskhozhdeniya soglasno fiziko-khimicheskoy modeli navodorozhivaniya tverdykh tel. In Geokhimiya i termobarometriya endogennykh flyuidov (pp. 95–103). Kiev: Naukova dumka. [in Russian]

Svoren, Y. M. (1992). Pytannia teorii henezysu pryrodnykh vuhlevodniv ta shliakhy poshuku yikh pokladiv. In Tektohenez i naftohazonosnist nadr Ukrainy (pp. 143–145). Lviv. [in Ukrainian]

Svoren, Y. (2020a). Nadra Zemli – pryrodnyi fizyko-khimichnyi reaktor: pryroda vody naftovykh i hazovykh rodovyshch. In Naftohazova haluz: Perspektyvy naroshchuvannia resursnoi bazy: materialy dopovidei Mizhnarodnoi naukovo-tekhnichnoi konferentsii (Ivano-Frankivsk, 8–9 hrudnia 2020 r.) (pp. 158–160). Ivano-Frankivsk: IFNTUNH. [in Ukrainian]

Svoren, J. M. (2020b). Various Chemical Properties of Carbon Isotopes in Natural Synthesis of Different Compounds. Journal of Geological Resource and Engineering, 8, 20–23. https://doi.org/10.17265/2328-2193/2020.01.002

Svoren, Y. M., & Davydenko, M. M. (1995). Termobarometriia i heokhimiia haziv prozhylkovo-vkraplenoi mineralizatsii u vidkladakh naftohazonosnykh oblastei i metalohenichnykh provintsii. Dopovidi NAN Ukrainy, 9, 72–73. [in Ukrainian]

Svoren, Y. M., Davydenko, M. M., Haievskyi, V. H., Krupskyi, Yu. Z., & Pelypchak, B. P. (1994). Perspektyvy termobarometrii i heokhimii haziv prozhylkovo-vkraplenoi mineralizatsii u vidkladakh naftohazonosnykh oblastei i metalohenichnykh provintsii. Heolohiia i heokhimiia horiuchykh kopalyn, 3–4(88–89), 54–63. [in Ukrainian]

Svoren, Y. M., & Naumko, I. M. (2003). Nova teoriia syntezu i henezysu vuhlevodniv u litosferi Zemli: abiohenno-biohennyi dualizm. In Mezhdunarodnaya konferentsiya “Krym–2003” (pp. 75–77). Simferopol. [in Ukrainian]

Svoren, Y., & Naumko, I. (2004). Termobarometriia i heokhimiia haziv prozhylkovo-vkraplenoi mineralizatsii u vidkladakh naftohazonosnykh oblastei i metalohenichnykh provintsii: henezys i syntez prozhylkovykh karbonatnykh porid. In Mineralohiia: istoriia, teoriia i praktyka: tezy dopovidei Mizhnarodnoi naukovoi konferentsii, prysviachenoi 140-richchiu kafedry mineralohii Lvivskoho natsionalnoho universytetu imeni Ivana Franka (Lviv–Shatsk, 3–6 veresnia 2004 r.) (pp. 63–65). Lviv: Vydavnychyi tsentr LNU imeni Ivana Franka. [in Ukrainian]

Svoren, Y. M., & Naumko, I. M. (2005). Termobarometriia i heokhimiia haziv prozhylkovo-vkraplenoi mineralizatsii u vidkladakh naftohazonosnykh oblastei i metalohenichnykh provintsii – pryrodnyi fenomen litosfery Zemli. Dopovidi NAN Ukrainy, 2, 109–113. [in Ukrainian]

Svoren, Y. M., & Naumko, I. M. (2006). Nova teoriia syntezu i henezysu pryrodnykh vuhlevodniv: abiohenno-biohennyi dualizm. Dopovidi NAN Ukrainy, 2, 111–116. [in Ukrainian]

Posted on June 2023October 2023 by GGCMJournal

ON THE REGULARITY OF NATURAL PROCESSES OF SYNTHESIS AND GENESIS HYDROCARBONS AND WATER OF OIL AND GAS FIELDS: ABIOGENIC-BIOGENIC DUALISM

Home > Archive > No. 1–2 (189–190) 2023 > 81–91

Geology & Geochemistry of Combustible Minerals No. 1–2 (189–190) 2023, 81–91

https://doi.org/10.15407/ggcm2023.189-190.081

Yosyp SVOREN’
Institute of Geology and Geochemistry of Combustible Minerals of National Academy of Sciences of Ukraine, Lviv, Ukraine, e-mail: igggk@mail.lviv.ua

Abstract

It is shown that the problem of the nature of water in oil and gas fields must be solved in an inextricable connection with the genesis and synthesis of natural hydrocarbons in the Earth’s bowels. The work offers an original solution, based on a new theory of the synthesis and genesis of hydrocarbons (oil, gas, etc.): abiogenic-biogenic dualism, which asserts that giant and supergiant oil and gas fields were formed from inorganic and organic original hydrocarbon-containing substances under the influence of abiogenic high-thermobaric deep fluid in harsh physical, physicochemical and geological conditions of the earth’s crust. Since the abiogenic high-thermobaric deep fluid contains hydrogen H⁺ and OH-containing anions, the described mechanism for the interaction of positively charged ions: C⁺, H⁺, C_nH_m⁺-radicals with the formation-synthesis of a complex hydrocarbon mixture such as gas, oil, bitumen, etc. must be logically supplemented by a reaction: Н₂О → Н⁺ + ОН⁻. As a result of this complex physical and chemical process, the maximum concentration of (OH⁻) anions accumulated in the oxidation zone, which after the disappearance of the electric field become neutral and interact with each other according to the scheme: ОН + ОН = Н₂О₂ – hydrogen peroxide, which is an unstable compound, which decomposes into Н₂О + О. Oxygen atoms became the starting substances for the formation of macro- and microcracks in these cavities under harsh conditions of rocks of the carbonate or quartz-carbonate type, etc., much less often – perfect mineral crystals, which with their defects in the process of growth (synthesis) captivate and preserve substances in the system (proper hydrocarbons and water). Тherefore, it was established for the first time that the natural water of oil and gas fields has a dual lithospheric-asthenospheric nature, while the lithospheric part is dominant, the isotopic composition is a mixture of these waters, and the deuterium isotope is more chemically active in complex physical and chemical processes, which run through the bowels of the planet. The obtained original data will contribute to the solution of Ukraine’s serious problem with energy carriers: natural gas, oil, coal and drinking water.

Full Text

Keywords

fluid inclusions, hydrocarbons, drinking water, energy carriers, oil and gas industry, fundamental science, scientific discoveries

Referenses

Dolenko, G. N. (1975). Sovremennoye sostoyaniye problemy proiskhozhdeniya nefti i gaza i formirovaniya ikh promyshlennykh zalezhey. In Zakonomernosti obrazovaniya i razmeshcheniya promyshlennykh mestorozhdeniy nefti i gaza (pp. 3–17). Kiev: Naukova dumka. [in Russian]

Naumko, I. M. (2006). Fliuidnyi rezhym mineralohenezu porodno-rudnykh kompleksiv Ukrainy (za vkliuchenniamy u mineralakh typovykh parahenezysiv) [Extended abstract of Doctorʼs thesis]. Instytut heolohii i heokhimii horiuchykh kopalyn NAN Ukrainy. Lviv. [in Ukrainian]

Naumko, I., & Svoren, Y. (2021). Innovatsiini tekhnolohii poshukiv korysnykh kopalyn, osnovani na doslidzhenniakh fliuidnykh vkliuchen u mineralakh. Heolohiia i heokhimiia horiuchykh kopalyn, 3–4(185–186), 92–108. https://doi.org/10.15407/ggcm2021.03-04.092 [in Ukrainian]

Pavliuk, I., Naumko, I., & Stefanyk, Yu. (2007, December 13). Heolohy-naukovtsi proty metanu-vbyvtsi. U Lvovi na Naukovii taky ye nauka. Ukraina i Chas, 50(286), 7.

Svoren, Y. M. (1975). Istochniki uglerodsoderzhashchikh gazov vklyucheniy. In Uglerod i ego soyedineniya v endogennykh protsessakh mineraloobrazovaniya (po dannym izucheniya flyuidnykh vklyucheniy v mineralakh): tezisy Respublikanskogo soveshchaniya (Lvov, sentyabr 1975 g.) (pp. 104–106). Lvov. [in Russian]

Svoren, I. M. (1984). Primesi gazov v kristallakh mineralov i drugikh tverdykh telakh, ikh sposoby izvlecheniya, sostav, forma nakhozhdeniya i vliyaniye na svoystva veshchestv [Extended abstract of Candidateʼs thesis]. Institut geologii i geokhimii goryuchikh iskopayemykh AN USSR. Lvov. [in Russian]

Svoren. I. M. (1988). Formy nakhozhdeniya vodoroda v nekotorykh tverdykh materialakh razlichnogo proiskhozhdeniya soglasno fiziko-khimicheskoy modeli navodorozhivaniya tverdykh tel. In Geokhimiya i termobarometriya endogennykh flyuidov (pp. 95–103). Kiev: Naukova dumka. [in Russian]

Svoren, Y. M. (1992). Pytannia teorii henezysu pryrodnykh vuhlevodniv ta shliakhy poshuku yikh pokladiv. In Tektohenez i naftohazonosnist nadr Ukrainy (pp. 143–145). Lviv. [in Ukrainian]

Svoren, Y. (2011). Nadra Zemli – pryrodnyi fizyko-khimichnyi reaktor: izotopy vuhletsiu pro pokhodzhennia planety Zemlia. Heolohiia i heokhimiia horiuchykh kopalyn, 1–2(154–155), 158–159. [in Ukrainian]

Svoren, Y. (2018). Vlastyvist hlybynnoho abiohennoho metanovmisnoho vysokotermobarnoho fliuidu utvoriuvaty vuhillia. Heolohiia i heokhimiia horiuchykh kopalyn, 3–4(176–177), 105–109. [in Ukrainian]

Svoren, Y. (2019). Nadra Zemli – pryrodnyi fizyko-khimichnyi reaktor: rizna khimichna vlastyvist izotopiv vuhletsiu u pryrodnykh protsesakh syntezu riznykh spoluk. In Problemy heolohii fanerozoiu Ukrainy: materialy X Vseukrainskoi naukovoi konferentsii (do 95-richchia kafedry istorychnoi heolohii ta paleontolohii i 120-richchia vid narodzhennia Severyna Ivanovycha Pasternaka (Lviv, 9–11 zhovtnia 2019 r.) (pp. 64–67). Lviv: LNU imeni Ivana Franka. [in Ukrainian]

Svoren, Y. (2020a). Nadra Zemli – pryrodnyi fizyko-khimichnyi reaktor: pryroda vody naftovykh i hazovykh rodovyshch. In Naftohazova haluz: Perspektyvy naroshchuvannia resursnoi bazy: materialy dopovidei Mizhnarodnoi naukovo-tekhnichnoi konferentsii (Ivano-Frankivsk, 8–9 hrudnia 2020 r.) (pp. 158–160). Ivano-Frankivsk: IFNTUNH. [in Ukrainian]

Svoren, J. M. (2020b). Subsoil Natural Physico-Chemical Reactor: Regularity of Natural Processes of Synthesis of Perfect Diamond Crystals. Journal of Geological Resource and Engineering, 8(4), 133–136. https://doi.org/10.17265/2328-2193/2020.04.005

Svoren, J. M. (2021). Subsoil Natural Physico-chemical Reactor: The Property of Deep Abiogenic Methane-Containing High-Thermobaric Fluid to Form Coal Seams. Journal of Geological Resource and Engineering, 9(1), 25–28. https://doi.org/10.17265/2328-2193/2021.01.003

Svoren, Y. M., & Naumko, I. M. (2006). Nova teoriia syntezu i henezysu pryrodnykh vuhlevodniv: abiohenno-biohennyi dualizm. Dopovidi NAN Ukrainy, 2, 111–116. [in Ukrainian]

Posted on June 2023October 2023 by GGCMJournal

THERMOMETRICAL STUDIES OF FLUID INCLUSIONS IN THE BADENIAN HALITE OF THE CARPATHIAN REGION IN THE CONTEXT OF DETERMINING THE DEPTH OF THE SALT BASIN

Home > Archive > No. 1–2 (189–190) 2023 > 54–65

Geology & Geochemistry of Combustible Minerals No. 1–2 (189–190) 2023, 54–65

https://doi.org/10.15407/ggcm2023.189-190.054

Anatoliy GALAMAY, Ihor ZINCHUK, Daria SYDOR
Institute of Geology and Geochemistry of Combustible Minerals of National Academy of Sciences of Ukraine, Lviv, Ukraine, e-mail: galamaytolik@ukr.net

Abstract

It was established that in order to avoid errors in the interpretation of paleotectonic conditions of salt formation based on fluid inclusions in halite, the primary stage of the research should be the genetic identification of the sedimentation textures of halite and fluid inclusions in this mineral. For the thermometric study of inclusions and to determine the depth of the sedimentation basin based on the obtained data, only thermal test chambers are suitable which provide the possibility of observing groups of inclusions in different zones of sedimentary halite, as, for example, in the micro thermal test chamber designed by Prof. V. A. Kalyuzhny.

In the course of the research, the equipment of the thermometric method, which is based on the use of a microthermal test chamber designed by V. A. Kalyuzhny, was modernized. In particular, the material of the thermal chamber (stainless steel) was replaced with copper, which made it possible to avoid excessive thermal gradients into chamber and to increase the permissible heating rate by 20 times due to the higher thermal conductivity of copper. For the same purpose, the glass optical windows of the camera were replaced with leukosapphire windows, which have a much higher thermal conductivity. The measuring system of the installation is made on a miniature platinum resistance thermometer with an electronic measuring unit. These improvements made it possible to achieve high system stability and good reproducibility of measurement results.

Using the thermometric method, it was established that the temperature of sedimentation at the bottom of the Badenian salt basin of the Carpathian region was 19.5–20.5; 20.0–22.0; 24.0–26.0 °C, and on the surface of the brine was 34.0–36.0 °C. On this basis, a model of the basin with a pronounced thermocline and a total thickness of the water column of up to 30 meters was built, which is the most likely to establish the features of sedimentation. Crystallization of halite at different depths in basins with a thermocline can explain the presence of so-called “low-temperature” (24.0–25.0 °C) and “high-temperature” (37.8–42.6 °C) bottom halite in a number of ancient salt-bearing basins.

Full Text

Keywords

halite, fluid inclusions, thermometric method, thermal chamber, homogenization temperature

Referenses

Acros, D., & Ayora, C. (1997). The use of fluid inclusions in halite as environmental thermometer: an experimental study. In XIV ECROFI: proceedings of the XIVth European Current Research on Fluid Inclusions (Nancy, France, July 1–4, 1997) (pp. 10–11). CNRS-CREGU.

Benison, K. C., & Goldstein, R. H. (1999). Permian paleoclimate data from fluid inclusions in halite. Chemical Geology, 154(1–4), 113–132. https://doi.org/10.1016/S0009-2541(98)00127-2

Galamay, A. R., Bukowski, K., Sydor, D. V., & Meng, F. (2020). The ultramicrochemical analyses (UMCA) of fluid inclusions in halite and experimental research to improve the accuracy of measurement. Minerals, 10(9), 823. https://doi.org/10.3390/min10090823

Galamay, A. R., Meng, F., Bukowski, K., Lyubchak, A., Zhang, Y., & Ni, P. (2019). Calculation of salt basin depth using fluid inclusions in halite from the Ordovician Ordos Basin in China. Geological Quarterly, 63(3), 619–628. https://doi.org/10.7306/gq.1490

Halamai, A. R. (2001). Fizyko-khimichni umovy formuvannia badenskykh evaporytovykh vidkladiv Karpatskoho rehionu [Candidateʼs thesis]. Instytut heolohii i heokhimii horiuchykh kopalyn NAN Ukrainy. Lviv. [in Ukrainian]

Halamai, A., Sydor, D., & Liubchak, O. (2014). Osoblyvosti poiavy hazovoi fazy v odnofazovykh ridkykh vkliuchenniakh u haliti (dlia vyznachennia temperatury yoho krystalizatsii). In Mineralohiia: sohodennia i maibuttia: materialy VIII naukovykh chytan imeni akademika Yevhena Lazarenka (prysviacheno 150-richchiu zasnuvannia kafedry mineralohii u Lvivskomu universyteti) (pp. 34–36). Lviv; Chynadiieve. [in Ukrainian]

Kaliuzhnyi, V. A. (1960). Metody vyvchennia bahatofazovykh vkliuchen u mineralakh. Kyiv: Vydavnytstvo AN URSR. [in Ukrainian]

Khrushchov, D. P. (1980). Litologiya i geokhimiya galogennykh formatsiy Predkarpatskogo progiba. Kiev: Naukova dumka. [in Russian]

Korenevskiy, S. M., Zakharova, V. M., & Shamakhov, V. A. (1977). Miotsenovyye galogennyye formatsii predgoriy Karpat. Leningrad: Nedra. [in Russian]

Kovalevich, V. M. (1978). Fiziko-khimicheskiye usloviya formirovaniya soley Stebnikskogo kaliynogo mestorozhdeniya. Kiev: Naukova dumka. [in Russian]

Kovalevych, V., Paul, J., & Peryt, T. M. (2009). Fluid inclusions in the halite from the Röt (Lower Triassic) salt deposit in Central Germany: evidence for seawater chemistry and conditions of salt deposition and recrystallization. Carbonates and Evaporates, 24(1), 45–57. https://doi.org/10.1007/BF03228056

Lowenstein, T. K., Li, J., & Brown, C. B. (1998). Paleotemperatures from fluid inclusions in halite: method verification and a 100,000 year paleotemperature record, Death Valley, CA. Chemical Geology, 150(3–4), 223–245. https://doi.org/10.1016/S0009-2541(98)00061-8

Meng, F., Ni, P., Schiffbauer, J. D., Yuan, X., Zhou, C., Wang, Y., & Xia, M. (2011). Ediacaran seawater temperature: Evidence from inclusions of Sinian halite. Precambrian Research, 184(1–4), 63–69. https://doi.org/10.1016/j.precamres.2010.10.004

Meng, F., Zhang, Y., Galamay, A. R., Bukowski, K., Ni, P., Xing, E., & Ji, L. (2018). Ordovician seawater composition: evidence from fluid inclusions in halite. Geological Quarterly, 62(2), 344–352. https://doi.org/10.7306/gq.1409

Petrichenko, O. Y. (1988). Fiziko-khimicheskiye usloviya osadkoobrazovaniya v drevnikh solerodnykh basseynakh. Kiev: Naukova dumka. [in Russian]

Petrychenko, O. Y. (1973). Metody doslidzhennia vkliuchen u mineralakh halohennykh porid. Kyiv: Naukova dumka. [in Ukrainian]

Roberts, S. M., & Spencer, R. J. (1995). Paleotemperatures preserved in fluid inclusions in halite. Geochimica et Cosmochimica Acta, 59(19), 3929–3942. https://doi.org/10.1016/0016-7037(95)00253-V

Shanina, S. N., Sokerina, N. V., Galamay, A. R., Ledentsov, V. N., & Onosov, D. V. (2014). Opredeleniye temperatur gomogenizatsii vklyucheniy v galite Yakshinskogo mestorozhdeniya. Vestnik Instituta geologii Komi NTs UrO RAN, 8, 3–6. [in Russian]

Sirota, I., Enzel, Y., & Lensky, N. G. (2017). Temperature seasonality control on modern halite layers in the Dead Sea: In situ observations. GSA Bulletin, 129(9–10), 1181–1194. https://doi.org/10.1130/B31661.1

Sydor, D. V., Halamai, A. R., & Meng, F. (2018). Pirotynova mineralizatsiia u halohennykh vidkladakh Verkhnokamskoho rodovyshcha kaliino-mahniievykh solei (termobaroheokhimichni doslidzhennia). Mineralohichnyi zbirnyk, 68(2), 52–61. [in Ukrainian]

Valyashko, M. G. (1952). Galit, osnovnyye ego raznosti, vstrechayemyye v solyanykh ozerakh, i ikh struktura. Trudy VNIIGalurgii, 23, 25–32. [in Russian]

Vorobyev, Yu. K. (1988). K probleme termometrii po pervichnym vklyucheniyam v mineralakh. Zapiski Vsesoyuznogo mineralogicheskogo obshchestva, 117(1), 125–132. [in Russian]

Warren, J. K. (2006). Evaporites: Sediments, Resources and Hydrocarbons. Springer Berlin, Heidelberg. https://doi.org/10.1007/3-540-32344-9

Xu, Y., Liu, C., Cao, Y., & Zhang, H. (2018). Quantitative temperature recovery from middle Eocene halite fluid inclusions in the easternmost Tethys realm. International Journal of Earth Sciences, 108, 173–182. https://doi.org/10.1007/s00531-018-1648-0

Zambito, J. J., & Benison, K. C. (2013). Extremely high temperatures and paleoclimate trends recorded in Permian ephemeral lake halite. Geology, 41(5), 587–590. https://doi.org/10.1130/G34078.1

Zhang, H., Lü, F., Mischke, S., Fan, M., Zhang, F., & Liu, C. (2017). Halite ﬂuid inclusions and the late Aptian sea surface temperatures of the Congo Basin, northern South Atlantic Ocean. Cretaceous Research, 71, 85–95. https://doi.org/10.1016/j.cretres.2016.11.008

Zhao, X., Zhao, Y., Wang, M., Hu, Y., Liu, C., & Zhang, H. (2022). Estimation of the ambient temperatures during the crystallization of halite in the Oligocene salt deposit in the Shulu Sag, Bohaiwan Basin, China. Minerals, 12(4), 410. https://doi.org/10.3390/min12040410

Zinchuk, I. M. (2003). Heokhimiia mineraloutvoriuiuchykh rozchyniv zoloto-polimetalevykh rudoproiaviv Tsentralnoho Donbasu (za vkliuchenniamy u mineralakh) [Candidateʼs thesis]. Instytut heolohii i heokhimii horiuchykh kopalyn NAN Ukrainy. Lviv. [in Ukrainian]

Posted on November 2021June 2022 by GGCMJournal

INNOVATIVE TECHNOLOGIES OF THE PROSPECTING FOR MINERAL DEPOSITS BASED ON DATA OF FLUID INCLUSIONS RESEARCH

Home > Archive > No. 3–4 (185–186) 2021 > 92–108

Geology & Geochemistry of Combustible Minerals No. 3–4 (185–186) 2021, 92–108.

https://doi.org/10.15407/ggcm2021.03-04.092

Ihor NAUMKO, Yosyp SVOREN
Institute of Geology and Geochemistry of Combustible Minerals of National Academy of Sciences of Ukraine, Lviv, Ukraine, e-mail: igggk@mail.lviv.ua

Abstract

The innovative approach to the development of prospective technologies (methods) was substantiated on crystallogenic and physicochemical principles of the knowledge of mineral forming environments (fluids) (thermobarogeochemistry – mineralofluidology – fluid inclusions) as a new branch of geological knowledge within the framework of the new scientific direction in the geology – “thermobarometry and geochemistry of gases of veinlet-impregnated mineralization in deposits of oil- and gas-bearing areas and metallogenic provinces” as a natural phenomenon of the Earth’s lithosphere. According to him, the creation of radically new technologies and realization of prospecting for mineral deposits (first of all hydrocarbons and gold) simultaneously with the elucidation of the problem of genesis and synthesis of hydrocarbons at the atomic-molecular level fixed by such defects in the mineral crystals as fluid inclusions. Developed technologies, namely: determination of genesis of hydrocarbon gases; determination of prospects of oil and gas presence of a local area; local forecast of enriched areas of gold ore fields; express determination of potassium ions in inclusions for identification of gold-enriched and barren veinlet formations, – belong to the branch of the exploration geology and geochemistry and are used to ascertain genetic guestions, to solve tasks of the mineralogical-geochemical prediction and prospecting for mineral deposits in the local structures of oil- and gas-bearing areas and metallogenic provinces. The comparison of fluid inclusions of veinlets and host rocks based on the sections of a number of wells has shown the considerable possibilities of the developed technologies and prospects of the usage of thermobarogeochemical-mineralofluidological indicators in the complex with the geochemical and geophysical (petrophysical) methods, data of geological survey, deep-seated drilling while predicting hydrocarbon deposits in the local structures of the sedimentary strata promising for oil and gas and making necessary amendments in the directions of the following geological-prospecting works.

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Keywords

innovative technologies, fluid inclusions, geochemistry, thermobarometry, fluids, hydrocarbons, gold, mineral-ore-naphthidogenesis, Earth’s lithosphere

Referenses

Chebanenko, I. I., Shestopalov, V. M., Bahrii, I. D., & Palii, V. M. (2000). Rozlomni zony pidvyshchenoi pronyknosti hirskykh porid ta yikh znachennia dlia vyiavlennia ekolohonebezpechnykh dilianok. Dopovidi Natsionalnoi akademii nauk Ukrainy, 10, 136–139. [in Ukrainian]

Davydenko, M. M., & Svoren, Y. M. (1994). Sposib lokalnoho prohnozuvannia zbahachenykh dilianok zolotorudnykh poliv (Patent Ukrainy № 5G01V9/00). Promyslova vlasnist, 3, 27. [in Ukrainian]

Ermakov, N. P., & Dolgov, Yu. A. (1979). Termobarogeokhimiya. Moskva: Nedra. [in Russian]

Galimov, E. M. (1968). Geokhimiya stabil’nykh izotopov ugleroda. Moskva: Nedra. [in Russian]

Kadik, A. A. (1986). Fraktsionirovanie letuchikh komponentov pri plavlenii verkhnei mantii. Geologiya i geofizika, 7, 70–73. [in Russian]

Kalyuzhnyi, V. A. (1979). Dinamika mineralogeneza na osnove izucheniya mineraloobrazuyushchikh flyuidov (granitnye zanoryshevye pegmatity i rudonosnye gidrotermality Ukrainy) [Extended abstract of Doctorʼs thesis]. IGFM AN URSR. Kiev. [in Russian]

Kalyuzhnyi, V. A. (1982). Osnovy ucheniya o mineraloobrazuyushchikh flyuidakh. Kiev: Naukova dumka. [in Russian]

Kalyuzhnyi, V. A., Vynar, O. N., Zinchuk, I. N., Kovalishin, Z. I., & Matvienko, A. D. (1987). Geokhimicheskaya spetsializatsiya endogennykh mineraloobrazuyushchikh flyuidov i poiskovye kriterii na poleznye iskopaemye. Mineralogicheskii sbornik L’vovskogo universiteta, 41(2), 54–58. [in Russian]

Kovalishin, Z. I., & Bratus’, M. D. (1984). Flyuidnyi rezhim gidrotermal’nykh protsessov Zakarpat’ya. Kiev: Naukova dumka. [in Russian]

Kovalishin, Z. I., & Vishtalyuk, S. D. (1985). O sostave rudoobrazuyushchikh flyuidov severo-zapadnoi chasti Marmaroshskogo massiva. Mineralogicheskii sbornik, 39(2), 76–80. [in Russian]

Kovalyshyn, Z. I., & Naumko, I. M. (2001). The peculiarities of fluid composition in gold ore mineralization within metamorphic rocks of north-western part among Marmarosh massif (Ukrainian Carpathians). In Tezisy dokladov X mezhdunarodnoi konferentsii po termobarogeokhimii (Aleksandrov, 10–14 sentyabrya 2001 g.) (pp. 85–88). Aleksandrov: VNIISIMS.

Kovalyshyn, Z. I., Naumko, I. M., & Kovalevych, V. M. (1999). Metodyka ekspresnoho vyznachennia kaliiu v mineralotvornykh fliuidakh dlia rozbrakuvannia zbahachenykh zolotom i bezrudnykh utvoren. In Naukovi osnovy prohnozuvannia, poshukiv ta otsinky rodovyshch zolota: materialy mizhnarodnoi naukovoi konferentsii (Lviv, 27–30 veresnia 1999 r.) (pp. 65–66). Lviv: Vydavnychyi tsentr LDU im. Ivana Franka. [in Ukrainian]

Kulchetska, H. O. (2009). Letki komponenty mineraliv yak indykatory umov mineraloutvorennia [Extended abstract of Doctorʼs thesis]. Kyiv. [in Ukrainian]

Maliuk, B. I., Klochko, V. P., Dovzhok, Ye. M., Okrepkyi, R. M., Dvorianyn, Ye. S., Marukhniak, M. Y., Karavaieva, T. Ye., Ponomarenko, M. I., Tokovenko, V. S., Naumko, I. M., & Hladun, V. V. (1996). Kompleksna interpretatsiia ta naukove obgruntuvannia rezultativ poshukovo-rozviduvalnykh robit na naftu i haz u krystalichnykh kompleksakh Okhtyrskoho naftohazopromyslovoho raionu Dniprovsko-Donetskoi zapadyny [Preprint № 96-1]. Ukrainskyi naftohazovyi instytut. Kyiv. [in Ukrainian]

Mamchur, G. P., Svoren’, I. M., Kalyuzhnyi, V. A., Naumko, I. M., Yarynych, O. A., & Shnyukov, E. F. (1981). Izotopnyi sostav ugleroda svobodnoi uglekisloty iz bazal’ta dna Indiiskogo okeana. In Vsesoyuznoe soveshchanie po geokhimii ugleroda: tezisy dokladov (Moskva, 14–16 dekabrya 1981 g.) (pp. 234–235). Moskva: GEOKhI AN SSSR. [in Russian]

Naumko, I. M., Bekesha, S. M., & Svoren, Y. M. (2008). Fliuidy hlybynnykh horyzontiv litosfery: zviazok z rodovyshchamy nafty i hazu u zemnii kori (za danymy vyvchennia vkliuchen u mineralakh hlybynnoho pokhodzhennia). Dopovidi Natsionalnoi akademii nauk Ukrainy, 8, 117–120. [in Ukrainian]

Naumko, I. M., & Kaliuzhnyi, V. A. (2001). Pidsumky ta perspektyvy doslidzhen termobarometrii i heokhimii paleofliuidiv litosfery (za vkliuchenniamy u mineralakh). Heolohiia i heokhimiia horiuchykh kopalyn, 2, 162–175. [in Ukrainian]

Naumko, I., Kaliuzhnyi, V., Bratus, M., Zinchuk, I., Kovalyshyn, Z., Matviienko, O., Redko, L., & Svoren, Y. (2000). Uchennia pro mineralotvorni fliuidy: priorytetni zavdannia rozvytku na suchasnomu etapi. Mineralohichnyi zbirnyk, 50(2), 22–30. [in Ukrainian]

Naumko, I., Kaliuzhnyi, V., Svoren, Y., Zinchuk, I., Bekesha, S., Redko, L., Sakhno, B., Druchok, L., Telepko, L., Beletska, Yu., Matviishyn, Z., Sava, N., Bondar, R., & Stepaniuk, V. (2007). Fliuidy postsedymentohennykh protsesiv v osadovykh ta osadovo-vulkanohennykh verstvakh pivdenno-zakhidnoi okrainy Skhidnoievropeiskoi platformy i prylehlykh heostruktur (za vkliuchenniamy u mineralakh). Heolohiia i heokhimiia horiuchykh kopalyn, 4, 63–94. [in Ukrainian]

Naumko, I., Kovalyshyn, Z., Sava, N., Bratus, M., Shashorin, Yu., & Sakhno, B. (2007). Termometrychna i heokhemichna kharakterystyka fliuidiv mineraloutvoriuvalnoho seredovyshcha kvartsovo-zhylnykh rudoproiaviv pivdennoi chastyny Kirovohradskoho bloku Ukrainskoho shchyta. Pratsi Naukovoho tovarystva im. Shevchenka. Heolohichnyi zbirnyk, 19, 136–146. [in Ukrainian]

Naumko, I. M., Kurovets, I. M., Sakhno, B. E., & Chepusenko, P. S. (2009). Kompleksuvannia mineralofliuidolohichnykh i petrofizychnykh metodiv: netradytsiinyi pidkhid do vyvchennia porid-kolektoriv (na prykladi Lvivskoho paleozoiskoho prohynu). Dopovidi Natsionalnoi akademii nauk Ukrainy, 1, 106–113. [in Ukrainian]

Naumko, I. M., & Popivniak, I. V. (2008). Vahomyi vnesok u vidtvorennia protsesiv endohennoho mineraloutvorennia (retsenziia na monohrafiiu D. K. Vozniaka “Mikrovkliuchennia ta rekonstruktsiia umov endohennoho mineraloutvorennia”). Mineralohichnyi zhurnal, 30(4), 104–107. [in Ukrainian]

Naumko, I. M., & Svoren’, I. M. (2003). O vazhnosti glubinnogo vysokotemperaturnogo flyuida v sozdanii uslovii dlya formirovaniya mestorozhdenii prirodnykh uglevodorodov v zemnoi kore. In Novye idei v naukakh o Zemle: materialy VI mezhdunarodnoi konferentsii (Moskva, 8–12 aprelya 2003 g.) (Vol. 1, p. 249). Moskva. [in Russian]

Naumko, I. M., & Svoren, Y. M. (2008). Pro shliakhy vtilennia hlybynnoho vysokotemperaturnoho fliuidu u zemnu koru. Dopovidi Natsionalnoi akademii nauk Ukrainy, 9, 112–114. [in Ukrainian]

Naumko, I., & Svoren, Y. (2014). Novi tekhnolohii poshukiv korysnykh kopalyn, osnovani na doslidzhenniakh fliuidnykh vkliuchen u mineralakh. In Aktual’nye problemy poiskovoi i ekologicheskoi geokhimii: sbornik tezisov Mezhdunarodnoi nauchnoi konferentsii (Kiev, 1–2 iyulya 2014 g.) (s. 23–25). Kiev: Interservis. [in Ukrainian]

Naumko, I. M., Svoren, Y. M., Kovalyshyn, Z. I., & Krupskyi, Yu. Z. (2001). Peredumovy zastosuvannia kompleksu termobaroheokhimichnykh danykh dlia prohnozuvannia pokladiv vuhlevodniv na poshukovii stadii. In Henezys nafty i hazu ta formuvannia yikh rodovyshch v Ukraini yak naukova osnova prohnozu ta poshukiv novykh skupchen: tezy dopovidei Mizhnarodnoi naukovo-praktychnoi konferentsii (Chernihiv, liutyi 2001 r.) (pp. 208–209). Chernihiv. [in Ukrainian]

Naumko, I., Svoren, Y., & Stepaniuk, V. (2006). Pro kompleksuvannia mineralofliuidolohichnykh i heokhimichnykh metodiv poshukiv vuhlevodniv. In Problemy heolohii ta naftohazonosnosti Karpat: tezy dopovidei Mizhnarodnoi naukovoi konferentsii do 100-richchia vid dnia narodzhennia chlen-korespondenta Natsionalnoi akademii nauk Ukrainy Mykoly Romanovycha Ladyzhenskoho ta 55-richchia Instytutu heolohii i heokhimii horiuchykh kopalyn NAN Ukrainy (Lviv, 26–28 veresnia 2006 r.) (pp. 161–164). Lviv: PROMAN–Pres-Ekspres-Lviv. [in Ukrainian]

Naumko, I. M., Svoren, Y. M., Zinchuk, I. M., & Krupskyi, Yu. Z. (2004). Do obgruntuvannia budivnytstva sverdlovyn na naftu i haz za danymy analizu fliuidnykh vkliuchen u mineralakh. In Nafta i haz Ukrainy – 2004: materialy VIII mizhnarodnoi naukovo-praktychnoi konferentsii (Sudak, 29 veresnia–1 zhovtnia 2004 r.) (Vol. 1, pp. 203–204). Kyiv. [in Ukrainian]

Pavliuk, M. I., Rizun, B. P., Varichev, S. O., & Savchak, O. Z. (2002). Polia heodynamichnykh napruzhen, pronyknist hirskykh porid, hlybynni termalni fliuidy i naftohazonosnist. Heolohiia i heokhimiia horiuchykh kopalyn, 4, 3–13. [in Ukrainian]

Petrychenko, O. Y. (1973). Metody doslidzhennia vkliuchen u mineralakh halohennykh porid. Kyiv: Naukova dumka. [in Ukrainian]

Reshenie Mezhdunarodnoi konferentsii “Krym–2003” “Problemy geodinamiki i neftegazonosnosti Chernomorsko-Kaspiiskogo regiona”. (2004). In Problemy geodinamiki i neftegazonosnosti Chernomorsko-Kaspiiskogo regiona: sbornik dokladov V Mezhdunarodnoi konferentsii “Krym–2003” (pp. 11–13). Simferopol’. [in Russian]

Roedder, E. (1984). Fluid inclusions [Monograph]. Reviews in Mineralogy, 12, 1–644. https://doi.org/10.1515/9781501508271

Shnyukov, E. F., Kalyuzhnyi, V. A., Shchiritsa, A. S., Telepko, L. F., Kruglov, A. S., Svoren’, I. M., & Alaui, G. G. (1987). Gazovye flyuidy kontaktovykh bazal’tov dna Indiiskogo okeana (po reliktovym vklyucheniyam). Doklady Akademii nauk SSSR, 297(6), 1457–1460. [in Russian]

Svoren’, I. M. (1984). Primesi gazov v kristallakh mineralov i drugikh tverdykh telakh (ikh sposoby izvlecheniya, sostav, formy nakhozhdeniya i vliyanie na svoistva veshchestv) [Extended abstract of candidateʼs thesis]. Institut geologii i geokhimii goryuchikh iskopaemykh AN USSR. L’vov. [in Russian]

Svoren, Y. M., & Davydenko, M. M. (1994). Sposib vyznachennia perspektyvy naftohazonosnosti lokalnoi ploshchi (Patent Ukrainy № 5G01V9/00). Promyslova vlasnist, 4, 2.45. [in Ukrainian]

Svoren, Y. M., & Davydenko, M. M. (1998). Poshukove znachennia termobarometrii i heokhimii haziv prozhylkovo-vkraplenoi mineralizatsii u vidkladakh naftohazonosnykh oblastei i metalohenichnykh provintsii. In Nafta i haz Ukrainy–98: materialy V Mizhnarodnoi konferentsii (Poltava, 15–17 veresnia 1998 r.) (Vol. 1, pp. 110–111). Poltava: UNHA. [in Ukrainian]

Svoren, Y. M., & Naumko, I. M. (2000). Nova tekhnolohiia vyznachennia henezysu vuhlevodnevykh haziv. In Nafta i haz Ukrainy – 2000: materialy VI Mizhnarodnoi naukovo-praktychnoi konferentsii (Ivano-Frankivsk, 31 zhovtnia–3 lystopada 2000 r.) (Vol. 1, pp. 108). Ivano-Frankivsk: Fakel. [in Ukrainian]

Svoren’, I. M., & Naumko, I. M. (2002). Termobarometriya i geokhimiya gazov prozhilkovo-vkraplennoi mineralizatsii v otlozheniyakh neftegazonosnykh oblastei i metallogenicheskikh provintsii: problema genezisa i poiska uglevodorodov. In Novye idei v geologii i geokhimii nefti i gaza. K sozdaniyu obshchei teorii neftegazonosnosti nedr: materialy VI mezhdunarodnoi konferentsii (Moskva, 28–31 maya 2002 g.) (Vol. 2, pp. 156–159). Moskva: GEOS. [in Russian]

Svoren, Y. M., & Naumko, I. M. (2006). Nova teoriia syntezu i henezysu pryrodnykh vuhlevodniv: abiohenno-biohennyi dualizm. Dopovidi Natsionalnoi akademii nauk Ukrainy, 2, 111–116. [in Ukrainian]

Svoren, Y. M., Naumko, I. M., & Davydenko, M. M. (1998). Nova tekhnolohiia vyznachennia perspektyvy naftohazonosnosti lokalnoi ploshchi. In Nafta i haz Ukrainy–98: materialy V Mizhnarodnoi konferentsii (Poltava, 15–17 veresnia 1998 r.) (Vol. 1, pp. 111–112). Poltava: UNHA. [in Ukrainian]

Svoren’, J. M., Naumko I. M., Kovalyshyn, Z. I., Bratus’, M. D., & Davydenko, M. M. (1999). New technology of local forecast of enriched areas of gold ore fields. In Naukovi osnovy prohnozuvannia, poshukiv ta otsinky rodovyshch zolota: materialy mizhnarodnoi naukovoi konferentsii (Lviv, 27–30 veresnia 1999 r.) (pp. 120–121). Lviv: Vydavnychyi tsentr LDU im. Ivana Franka.

Svoren, Y. M., Naumko, I. M., Kurovets, I. M., & Krupskyi, Yu. Z. (2005). Termobarometriia i heokhimiia haziv prozhylkovo-vkraplenoi mineralizatsii u vidkladakh naftohazonosnykh oblastei i metalohenichnykh provintsii: problema henezysu ta poshuku vuhlevodniv. Dopovidi Natsionalnoi akademii nauk Ukrainy, 3, 115–120. [in Ukrainian]

Vozniak, D. K. (2003). Fliuidni vkliuchennia u mineralakh yak indykatory endohennoho mineraloutvorennia [Extended abstract of Doctorʼs thesis]. Kyiv. [in Ukrainian]

Posted on June 2021November 2021 by GGCMJournal

GEOCHEMICAL FEATURES OF EURASIAN EVAPORITES IN THE CONTEXT OF THE CHEMICAL EVOLUTION OF SEAWATER IN PHANEROZOIC

Home > Archive > No. 1–2 (183–184) 2021 > 110–129

Geology & Geochemistry of Combustible Minerals No. 1–2 (183–184) 2021, 110–129.

https://doi.org/10.15407/ggcm2021.01-02.110

Аnatoliy GALAMAY, Andriy POBEREZHSKYY, Sofiya HRYNIV, Serhiy VOVNYUK, Dariya SYDOR, Iaroslava IAREMCHUK, Sofiya MAKSYMUK, Oksana OLIYOVYCH-HLADKA, Lyudmila BILYK
Institute of Geology and Geochemistry of Combustible Minerals of National Academy of Sciences of Ukraine, Lviv, e-mail: igggk@mail.lviv.ua

Abstract

Studies of evaporites provide new data to characterize the seawater chemistry in the Early Paleozoic and Middle Mesozoic. In particular, we studied the fluid inclusions in halite from Ordovician (China) and Cretaceous (Laos) evaporites. The corresponding sections on the plot of Ca/SO₄ oscillations curve in the Phanerozoic seawater are updated. The calcium content in seawater concentrated to halite precipitation stage was 45.6 mol %, 485 million years ago and 24.3 mol % 112.2–93.5 million years ago.

By analyzing the previously published and new factual material, it is established that in Permian evaporites the sulfur isotopic composition is inversely correlated with the sulfate ion content in evaporite basin brines. Thus, the evolution of seawater chemistry in Permian is confirmed by the evolution of the isotopic composition of dissolved seawater sulfate.

According to the generalization of 38 Phanerozoic marine evaporite formations, it was found that the peculiarities of the clay minerals associations correlate with the change of the seawater chemical type. Clay minerals associations precipitated from the SO₄-rich seawater are characterized by a larger set of minerals, among which smectite and mixed- layered minerals often occur; Mg-rich clay minerals (corensite, paligorskite, sepiolite, talc) also occur. Instead, in the associations of evaporite clay minerals formed from the Ca-rich seawater are represented by the smaller amount of minerals, and Mg-rich minerals are extremely rare. The increased content of magnesium in seawater of SO₄-rich type is the main factor in the formation of Mg-rich silicates in evaporites.

The composition of clay minerals associations depends on the evaporate basin brine concentration; with its increase, unstable minerals are transformed, which theoretically leads to a decrease in the number of minerals in the associations. However, it was found that evaporite deposits of higher stages of brine concentration often still contain unstable clay minerals – products of incomplete transformation of a significant amount of pyroclastic material from coeval volcanic activity.

The main factor determining the composition of clay minerals associations of Phanerozoic evaporites was the seawater (and basin brines) chemical type.

Geochemical studies of scattered organic matter and fluid inclusions with hydrocarbon phase in evaporites of the Upper Pechora Basin (overlying oil and gas deposits) indicate the presence of allochthonous bitumoids and allow to use this method to predict oil and gas potential of other areas. Analysis of the results of oil and gas exploration in a number of areas of the Transcarpathian Trough indicates the presence of fluid-saturated reservoirs and the prospects for the discovery of new accumulations of hydrocarbons. Geochemical studies proved the effectiveness of gas-flow survey method for oil and gas exploration, assessing the prospects for fluid saturation of seismic structures.

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Keywords

fluid inclusions, halit, salt Basin, seawater.

Referenses

Bao, H. P., Yang, C. Y., & Huang, J. S. (2004). “Evaporation drying” and “reinfluxing and redissolving” – a new hypothesis concerning formation of the Ordovician evaporites in eastern Ordos Basin. Journal of Palaeogeography, 6, 279–288.

Berner, R. A., Vandenbrooks, J. M., & Ward, P. D. (2007). Oxygen and evolution. Science, 316, 557–558. https://doi.org/10.1126/science.1140273

Demicco, R. V., Lowenstein, T. K., Hardie, L. A., & Spencer, R. J. (2005). Model of seawater composition for the Phanerozoic. Geology, 33(11), 877–880. https://doi.org/10.1130/G21945.1

Duchuk, S. V., & Maksymuk, S. V. (2019). Naftohazovyi potentsial Zakarpatskoho prohynu. In Mineralno-syrovynni bahatstva Ukrainy: shliakhy optymalnoho vykorystannia: tezy dopovidei naukovo-praktychnoi konferentsii (4 zhovtnia 2019 r., smt Khoroshiv) (pp. 55–61). Kyiv. [in Ukrainian]

Dunoyer de Segonzac, G. (1970). The transformation of clay minerals during diagenesis and low-grade metamorphism: a review. Sedimentol., 15(3–4), 281–346. https://doi.org/10.1111/j.1365-3091.1970.tb02190.x

D’yakonov, A. I., Tskhadaya, N. D., Ovcharova, T. A., Yudin, V. M., Ivanov, V. V., & Kuznetsov, N. I. (2002). Sovremennyi evolyutsionno-dinamicheskii metod prognoza neftegazonosnosti geologo-ekologicheskikh regionov osobo slozhnogo stroeniya (na primere yuga Verkhnepechorskoi vpadiny). Ukhta: UGTU. [in Russian]

Frank-Kamenetskii, V. A., Kotov, N. V., & Goilo, E. L. (1983). Transformatsionnye preobrazovaniya sloistykh silikatov. Leningrad: Nedra. [in Russian]

Galamai, A. R., Shanina, S. N., & Ignatovich, O. O. (2013). Sostav mineraloobrazuyushchikh rassolov Verkhnepechorskogo solerodnogo basseina na stadii kristallizatsii galita. Zapiski Rossiiskogo mineralogicheskogo obshchestva, 142(4), 32–46. [in Russian]

Galamay, A. R., & Bukowski, K. (2011). Skład chemiczny badeńskich solanek z pierwotnych ciekłych inkluzji w halicie, basen Zakarpacki (Ukraina). Geologia (kwart. AGH), 37(2), 245–267.

Galamay, A. R., Meng, F., Bukowski, K., Ni, P., Shanina, S. N., & Ignatovich, O. O. (2016). The sulphur and oxygen isotopic composition of anhydrite from the Upper Pechora Basin (Russia): new data in the context of the evolution of the sulphur isotopic record of Permian evaporites. Geological Quarterly, 60(4), 990–999. https://doi.org/10.7306/gq.1309

Halamai, A. R. (2001). Fizyko-khimichni umovy formuvannia badenskykh evaporytovykh vidkladiv Karpatskoho rehionu [Extended abstract of сandidateʼs thesis]. Instytut heolohii i heokhimii horiuchykh kopalyn NAN Ukrainy. Lviv. [in Ukrainian]

Halamai, A. R., & Baranenko, O. B. (2004). Proiavy vuhlevodniv u badenskykh soliakh Peredkarpattia i Zakarpattia. Mineralohichnyi zbirnyk, 54(1), 132–136. [in Ukrainian]

Halamai, A. R., & Meng, F. (2020). Khimichnyi sklad pivdenno-skhidnoi chastyny kreidovoho Sakon Nakhon solerodnoho baseinu Laosu u konteksti evoliutsii skladu okeanichnoi vody. In Vid mineralohii i heohnozii do heokhimii, petrolohii, heolohii ta heofizyky: fundamentalni i prykladni trendy XXI stolittia (MinGeoIntegration XXI): tezy dopovidei Vseukrainskoi konferentsii (Kyiv, 23–25 veresnia 2020 r.) (pp. 20–24). Kyiv. [in Ukrainian]

Hardie, L. A. (1996). Secular variation in seawater chemistry: An explanation for the coupled secular variation in the mineralogies of marine limestones and potash evaporites over the past 600 m. y. Geology, 24, 279–283. https://doi.org/10.1016/S0016-7037(01)00884-5

Iaremchuk, Ya. V. (2010). Hlynysti mineraly evaporytiv fanerozoiu ta yikhnia zalezhnist vid stadii zghushchennia rozsoliv i khimichnoho typu okeanichnoi vody. Zbirnyk naukovykh prats Instytutu heolohichnykh nauk NAN Ukrainy, 3, 138–146. https://doi.org/10.30836/igs.2522-9753.2010.147301 [in Ukrainian]

Iaremchuk, I., Tariq, M., Hryniv, S., Vovnyuk, S., & Meng, F. (2017). Clay minerals from rock salt of Salt Range Formation (Late Neoproterozoic–Early Cambrian, Pakistan). Carbonates Evaporites, 32(1), 63–74. https://doi.org/10.1007/s13146-016-0294-5

Kossovskaya, A. G., & Drits, V. A. (1975). Kristallokhimiya dioktaedricheskikh slyud, khloritov i korrensitov kak indikatorov geologicheskikh obstanovok. In Kristallokhimiya mineralov i geologicheskie problemy (pp. 60–69). Moskva: Nauka. [in Russian]

Kovalevich, V. M. (1990). Galogenez i khimicheskaya evolyutsiya okeana v fanerozoe. Kiev: Naukova dumka. [in Russian]

Kovalevich, V. M., Peryt, T. M., & Petrichenko, O. I. (1998). Secular variation in seawater chemistry during the Phanerozoic as indicated by brine inclusions in halite. Geology, 106, 695–712. https://doi.org/10.1086/516054

Kovalevich, V. M., & Vovnyuk, S. V. (2010). Vekovye variatsii khimicheskogo sostava rassolov morskikh evaporitovykh basseinov i vod mirovogo okeana. Litologiya, 4, 95–109. [in Russian]

Kovalevych, V. M., Peryt, T. M., Carmona, V., Sydor, D. V., Vovnyuk, S. V., & Halas, S. (2002). Evolution of Permian seawater: evidence from fluid inclusions in halite. N. Jb. Miner. Abh., 178(1), 27–62. https://doi.org/10.1127/0077-7757/2002/0178-0027

Kovalevych, V. M., Peryt, T. M., Shanina, S. N., Wieclaw, D., & Lytvyniuk, S. F. (2008). Geochemical aureoles around oil and gas accumulations in the Zechstein (Upper Permian) of Poland: analysis of fluid inclusions in halite and bitumens in rock salt. Journal of Petrolium Geology, 31(3), 245–262. https://doi.org/10.1111/j.1747-5457.2008.00419.x

Кovalevych, V. M., & Vovnyuk, S. V. (2010). Fluid inclusions in halite from marine salt deposits: are they real microdroplets of ancient sea water? Geological Quarterly, 54(4), 401–410.

Large, R. R., Mukherjee, I., Gregory, D., Steadman, J., Corkrey, R., & Danyushevsky, L. V. (2019). Atmosphere oxygen cycling through the Proterozoic and Phanerozoic. Mineralium Deposita, 54, 485–506. https://doi.org/10.1007/s00126-019-00873-9

Lenton, T. M., Daines, S. J., & Mills, B. J. W. (2018). COPSE reloaded: an improved model of biogeochemical cycling over Phanerozoic time. Earth-Sci Rev., 178, 1–28. https://doi.org/10.1016/j.earscirev.2017.12.004

Lowenstein, T. K., Timofeeff, M. N., Brennan, S. T., Hardie, L. A., Demicco, R. V. (2001). Oscillations in Phanerozoic seawater chemistry: evidence from fluid inclusions. Science, 294, 1086–1088. https://doi.org/10.1126/science.1064280

Lowenstein, T. K., Timofeeff, M. N., Kovalevych, V. M., & Horita, J. (2005). The major-ion composition of Permian seawater. Geochimica et Cosmochimica Acta, 69(7), 1701–1719. https://doi.org/10.1016/j.gca.2004.09.015

Lytvyniuk, S. V. (2007). Heokhimichni oreoly u soliakh nad pokladamy vuhlevodniv. Heolohiia i heokhimiia horiuchykh kopalyn, 4, 95–111. [in Ukrainian]

Maksymuk, S. V. (2012). Osoblyvosti vidobrazhennia fliuidonasychenosti horyzontiv Vyshnianskoi ploshchi Zovnishnoi zony Peredkarpatskoho prohynu v heokhimichnykh poliakh prypoverkhnevykh vidkladiv. Heolohiia i heokhimiia horiuchykh kopalyn, 3–4(160–161), 109–117. [in Ukrainian]

Maksymuk, S. V., & Bodlak, P. M. (2015). Dosvid zastosuvannia heokhimichnykh metodiv u kompleksnykh poshukovykh robotakh na naftu i haz u Karpatskomu rehioni. In Fundamentalne znachennia i prykladna rol heolohichnoi osvity i nauky: tezy dopovidei Mizhnarodnoi naukovoi konferentsii, prysviachenoi 70-richchiu heolohichnoho fakultetu Lvivskoho natsionalnoho universytetu im. Ivana Franka (Lviv, 7–8 zhovtnia 2015 r.) (pp. 151–152). Lviv. [in Ukrainian]

McCaffrey, M. A., Lazar, B., & Holland, H. D. (1987). The evaporation path of seawater and the coprecipitation of Br and K with halite. Journal of Sedimentary Petrology, 57, 928–937. https://doi.org/10.1306/212F8CAB-2B24-11D7-8648000102C1865D

Moskovskii, G. A. (1983). Issledovaniya fiziko-khimicheskikh uslovii sedimentatsii kungurskikh galogennykh otlozhenii zapadnoi chasti Prikaspiiskoi sineklizy po vklyucheniyam v mineralakh [Extended abstract of сandidateʼs thesis]. Moskovskii gossudarstvennyi universitet. Moskva. [in Russian]

Petrychenko, O. Y. (1973). Metody doslidzhennia vkliuchen u mineralakh halohennykh porid. Kyiv: Naukova dumka. [in Ukrainian]

Pozo, M., & Calvo, J. P. (2018). An Overview of Authigenic Magnesian Clays. Minerals, 8(11), 520. https://doi.org/10.3390/min8110520

Raevskii, V. I., Fiveg, M. P., & Gerasimova, V. V. (1973). Mestorozhdeniya kaliinykh solei SSSR. Leningrad: Nedra. [in Russian]

Robinson, D., Schmidt, Th., & Santana de Zambora, A. (2002). Reaction pathways and reaction progress for the smectite-to chlorite transformation: evidence from hydrothermally altered metabasites. J. Metamorph. Geol., 20, 167–174. https://doi.org/10.1046/j.0263-4929.2001.00361.x

Schiffman, P., & Staudigel, H. (1995). The smectite to chlorite transition in a fossil seamount hydrothermal system: the Basement Complex of La Palma, Canary Islands. Journal of Metamorphic Geology, 13, 487–498. https://doi.org/10.1111/j.1525-1314.1995.tb00236.x

Sokolova, T. N. (1982). Autigennoe silikatnoe mineraloobrazovanie rannikh stadii osoloneniya. Moskva: Nauka. [in Russian]

Sone, M., & Metcalfe, I. (2008). Parallel Tethyan sutures in mainland South-East Asia: New insights for Palaeo-Tethys closure and implications for the Indosinian orogeny. Comptes Rendus Geoscience, 340, 166–179. https://doi.org/10.1016/j.crte.2007.09.008

Więcław, D., Lytvyniuk, S. F., Kovalevych, V. M., & Peryt, T. M. (2008). Incluzje w halicie oraz bituminy w solach ewaporatόw mioceńskich ukraińskiego Przedkarpacia jako wskaźnik występowania nagromadzeń węglowodorόw w niżey leżących utworach. Przegląd Geologiczny, 56(9), 837–841.

Yaremchuk, Y., Hryniv, S., Peryt, T., Vovnyuk, S., & Meng, F. (2020a). Controls on Associations of Clay Minerals in Phanerozoic Evaporite Formations: An Overview. Minerals, 10(11), 974. https://doi.org/10.3390/min10110974

Yaremchuk, Ya., Vovniuk, S., Hryniv, S., Tarik, M., Menh, F., Bilyk, L., & Kochubei, V. (2017). Umovy utvorennia hlynystykh mineraliv verkhnoneoproterozoisko-nyzhnokembriiskoi kamianoi soli formatsii Solianyi kriazh, Pakystan. Mineralohichnyi zbirnyk, 67(2), 72–90. [in Ukrainian]

Yaremchuk, Ya. V., Vovniuk, S. V., & Tariq, M. (2020b). Hlynysti mineraly eotsenovoi kamianoi soli formatsii Bakhadar Khel, Pakystan. Heolohiia i heokhimiia horiuchykh kopalyn, 1(182), 87–99. https://doi.org/10.15407/ggcm2020.01.087 [in Ukrainian]

Yaremchuk, Ya. V., Vovnyuk, S. V., & Hryniv, S. P. (2020c). The peculiarities of high-magnesium clay minerals occurrence in Phanerozoic evaporite formation. Geodynamics, 1(28), 52–61. https://doi.org/10.23939/jgd2020.01.052

Posted on June 2021November 2021 by GGCMJournal

GEOCHEMISTRY Of FLUIDS: INNOVATIVE SOLUTION OF THE FUNDAMENTAL PROBLEM

Home > Archive > No. 1–2 (183–184) 2021 > 130–148

Geology & Geochemistry of Combustible Minerals No. 1–2 (183–184) 2021, 130–148.

https://doi.org/10.15407/ggcm2021.01-02.130

Josyp SVOREN
Institute of Geology and Geochemistry of Combustible Minerals of National Academy of Sciences of Ukraine, Lviv, e-mail: igggk@mail.lviv.ua

Abstract

First of all, has developed a reliable mass spectrometric method for studying fluid inclusions in minerals (on the basis of the author’s certificate of the USSR No. 454446 of 1974 for the invention of the “device for cleaning the content inclusions of solid materials”). Were created and published new scientific directions: 1. Thermobarometry and geochemistry of gases of veinlet-impregnated mineralization in sediments of oil and gas regions and metallogenic provinces. 2. Bowels of the Earth – natural physicochemical reactor. Was developed a “method (technology) for determining the prospects of oil and gas bearing of the local area” and “a method (technology) of local forecasting of enriched areas of gold-ore fields” (together with M. M. Davydenko). Was established unknown before, but objectively existing phenomenon of the material world: 1) “lack of molecular hydrogen in inclusions in minerals in the bowels of the planet Earth” (together with V. A. Kaliuzhny). Independently were established: 2) previously unknown “property of deep abiogenic methane-termobar high-temperature fluid decompose-convert natural organic residues into layers of coal with their simultaneous methane saturation and its conservation in the earth’s crust of the planet Earth”; 3) previously unknown natural “phenomenon of arbitrary formation of natural carbon methane in the coal layers of the earth’s crust of the planet Earth under the influence of abiogenic methane-containing high-temperature fluid with their conservation in them”; 4) previously unknown different chemical properties of carbon isotopes in natural processes of synthesis-formation of various carbon-containing compounds …; 5) “previously unknown pattern of natural processes of synthesis of perfect diamond crystals from astenospheric carbon dioxide ions…”. Was justified “a new way to determine the calorification of natural gas supplied to consumers and its cubic-metre barometry”.

Full Text

Keywords

geochemistry, fluid inclusions, veinlet-impregnated mineralization, deep abiogenic methane-bearing high-termobaric fluid, searches, new technologies, cubic-metre-barometry, scientific discovery.

Referenses

Davydenko, M. M., & Svoren, Y. M. (1994). Sposib lokalnoho prohnozuvannia zbahachenykh dilianok zolotorudnykh poliv (Patent Ukrainy № 5G01V9/00). Promyslova vlasnist, 3, 27. [in Ukrainian]

Naumko, I. M. (2006). Fliuidnyi rezhym mineralohenezu porodno-rudnykh kompleksiv Ukrainy (za vkliuchenniamy u mineralakh typovykh parahenezysiv) [Extended abstract of Doctorʼs thesis]. Instytut heolohii i heokhimii horiuchykh kopalyn NAN Ukrainy. Lviv. [in Ukrainian]

Naumko, I., Pavliuk, M., & Poberezhskyi, A. (2020). Heokhimiia i termobarometriia mineraloutvoriuvalnykh fliuidiv ta termobaroheokhimiia evaporytiv – vsesvitno vidomi naukovi shkoly. Heolohiia i heokhimiia horiuchykh kopalyn, 1(182), 62–75. https://doi.org/10.15407/ggcm2020.01.062 [in Ukrainian]

Naumko, I. M., & Svoren, Y. M. (2008). Pro shliakhy vtilennia hlybynnoho vysokotemperaturnoho fliuidu u zemnu koru. Dopovidi Natsionalnoi akademii nauk Ukrainy, 9, 112–114. [in Ukrainian]

Pavlyshyn, V. I., Bondarenko, S. M., Bryk, O. B., Vozniak, D. K., Yelchenko, K. O., Kalinichenko, A. M., Kvasnytsia, V. M., Kulchytska, H. O., Lupashko, T. M., Naumko, I. M., Semenenko, V. P., Taran, M. M., Tarashchan, A. M., Khomenko, V. M., & Chernysh, D. S. (2018). Mineralohiia u Natsionalnii akademii nauk Ukrainy (do 100-richchia NAN Ukrainy). Mineralohichnyi zhurnal, 40(3), 3–22. https://doi.org/10.15407/mineraljournal.40.03.003 [in Ukrainian]

Svoren’, I. M. (1974). Ustroistvo dlya ochistki soderzhimogo vklyuchenii tverdykh materialov (Avtorskoe svidetel’stvo SSSR № 454446). Byulleten’, 47. [in Russian]

Svoren’, I. M. (1984). Primesi gazov v kristallakh mineralov i drugikh tverdykh telakh, ikh sposoby izvlecheniya, sostav, forma nakhozhdeniya i vliyanie na svoistva veshchestv [Extended abstract of сandidateʼs thesis]. Institut geologii i geokhimii goryuchikh iskopaemykh AN USSR. L’vov. [in Russian]

Svoren, Y. M. (1992). Pytannia teorii henezysu pryrodnykh vuhlevodniv ta shliakhy poshuku yikh pokladiv. In Tektohenez i naftohazonosnist nadr Ukrainy: tezy dopovidei naukovoi narady (20–22 zhovtnia 1992 r.) (pp. 143–145). Lviv. [in Ukrainian]

Svoren, Y. M. (2008). Termobarometriia i heokhimiia haziv prozhylkovo-vkraplenoi mineralizatsii u vidkladakh naftohazonosnykh oblastei i metalohenichnykh provintsii: pryroda vuhilnoho metanu. Ugol’ Ukrainy, 8(620), 42–46. [in Ukrainian]

Svoren, Y. (2011a). Nadra Zemli – pryrodnyi fizyko-khimichnyi reaktor: izotopy vuhletsiu pro pokhodzhennia planety Zemlia. Heolohiia i heokhimiia horiuchykh kopalyn, 1–2(154–155), 158–159. [in Ukrainian]

Svoren, Y. (2011b). Nadra Zemli – pryrodnyi fizyko-khimichnyi reaktor: pryroda zemletrusu. Heolohiia i heokhimiia horiuchykh kopalyn, 1–2(154–155), 160–162. [in Ukrainian]

Svoren, Y. (2017a). Nadra Zemli – pryrodnyi fizyko-khimichnyi reaktor: pryrodnyi vuhlevodnevyi fenomen. Heolohiia i heokhimiia horiuchykh kopalyn, 1–2(170–171), 157–160. [in Ukrainian]

Svoren, Y. (2017b). Yavyshche utvorennia pryrodnykh vuhlemetaniv pid diieiu abiohennoho metanovmistnoho vysokotermobarnoho hlybynnoho fliuidu. In Heolohiia horiuchykh kopalyn: dosiahnennia ta perspektyvy: materialy II Mizhnarodnoi naukovoi konferentsii (Kyiv, 6–8 veresnia 2017 r.) (pp. 225–229). Kyiv. [in Ukrainian]

Svoren, Y. (2019a). Nadra Zemli – pryrodnyi fizyko-khimichnyi reaktor: poshuk pryrodnoho metanu – fundamentalna nauka chy tekhnichna problema? Heolohiia i heokhimiia horiuchykh kopalyn, 4(181), 104–115. https://doi.org/10.15407/ggcm2019.04.104 [in Ukrainian]

Svoren, Y. (2019b). Pro novyi pidkhid do vyznachennia teplotvornosti pryrodnoho hazu, yakyi postachaiut spozhyvacham ta yoho kubometrobarometriiu. Heolohiia i heokhimiia horiuchykh kopalyn, 2(179), 84–89. https://doi.org/10.15407/ggcm2019.02.084 [in Ukrainian]

Svoren, Y. (2020a). Nadra Zemli – pryrodnyi fizyko-khimichnyi reaktor: pryroda vody naftovykh i hazovykh rodovyshch. In Naftohazova haluz: Perspektyvy naroshchuvannia resursnoi bazy: materialy dopovidei Mizhnarodnoi naukovo-tekhnichnoi konferentsii (Ivano-Frankivsk, 08–09 hrudnia 2020 r.) (pp. 158–160). [in Ukrainian]

Svoren, Y. (2020b). Pro znachennia kubometrobarometrii pryrodnoho hazu, yakyi postachaiut spozhyvacham. In Naftohazova haluz: Perspektyvy naroshchuvannia resursnoi bazy: materialy dopovidei Mizhnarodnoi naukovo-tekhnichnoi konferentsii (Ivano-Frankivsk, 08–09 hrudnia 2020 r.) (pp. 91–94). [in Ukrainian]

Svoren’, J. M. (2020c). Subsoil Natural Physico-Chemical Reactor: Regularity of Natural Processes of Synthesis of Perfect Diamond Crystals. Journal of Geological Resource and Engineering, 8, 133–136. https://doi.org/10.17265/2328-2193/2020.04.005

Svoren’, J. M. (2020d). Various Chemical Properties of Carbon Isotopes in Natural Synthesis of Different Compounds. Journal of Geological Resource and Engineering, 8, 20–23. https://doi.org/10.17265/2328-2193/2020.01.002

Svoren’, J. M. (2021). Subsoil Natural Physico-chemical Reactor: The Property of Deep Abiogenic Methane-Containing High-Thermobaric Fluid to Form Coal Seams. Journal of Geological Resource and Engineering, 9, 25–28. https://doi.org/10.17265/2328-2193/2021.01.003

Svoren, Y. M., & Davydenko, M. M. (1994). Sposib vyznachennia perspektyvy naftohazonosnosti lokalnoi ploshchi (Patent Ukrainy № 5G01V9/00). Promyslova vlasnist, 4. [in Ukrainian]

Svoren, Y. M., Davydenko, M. M., Haievskyi, V. H., Krupskyi, Yu. Z., & Pelypchak, B. P. (1994). Perspektyvy termobarometrii i heokhimii haziv prozhylkovo-vkraplenoi mineralizatsii u vidkladakh naftohazonosnykh oblastei i metalohenichnykh provintsii (novyi naukovyi napriamok v heolohii). Heolohiia i heokhimiia horiuchykh kopalyn, 3–4(88–89), 54–63. [in Ukrainian]

Svoren, Y. M., & Naumko, I. M. (2000). Nova tekhnolohiia vyznachennia henezysu vuhlevodnevykh haziv. In Nafta i haz Ukrainy–2000: materialy VI Mizhnarodnoi naukovo-praktychnoi konferentsii (Ivano-Frankivsk, 31 zhovtnia–3 lystopada 2000 r.) (Vol. 1, pp. 108). Ivano-Frankivsk: Fakel. [in Ukrainian]

Svoren, Y. M., & Naumko, I. M. (2006a). Nova teoriia syntezu i henezysu pryrodnykh vuhlevodniv: abiohenno-biohennyi dualizm. Dopovidi Natsionalnoi akademii nauk Ukrainy, 2, 111–116. [in Ukrainian]

Svoren, Y. M., & Naumko, I. M. (2006b). Rol riznykh form vodniu ta vuhletsiu v pryrodnykh protsesakh: novyi pohliad na pokhodzhennia vuhlevodniv. Dopovidi Natsionalnoi akademii nauk Ukrainy, 1, 131–134. [in Ukrainian]

Posted on January 2020May 2021 by GGCMJournal

GEOCHEMISTRY AND THERMOBAROMOMETRY OF MINERAL-FORMING FLUIDS AND THERMOBAROGEOCHEMISTRY OF EVAPORITES – WORLD-FAMOUS SCIENTIFIC SCHOOLS

Home > Archive > No. 1 (182) 2020 > 62-75

Geology & Geochemistry of Combustible Minerals No. 1 (182) 2020, 62-75.

https://doi.org/10.15407/ggcm2020.01.062

Ihor NAUMKO, Myroslav PAVLYUK, Andriy POBEREZHSKYY
Institute of Geology and Geochemistry of Combustible Minerals of National Academy of Sciences of Ukraine, Lviv, e-mail: igggk@mail.lviv.ua

Abstract

Fundamental and applied achievements in the fields of geochemistry and thermobarometry of mineral-forming fluids and thermobarogeochemistry of evaporites are summarized as the basis of the corresponding world-famous scientific thermobarogeochemical schools established by professors V. A. Kalyuzhny and O. Yo. Petrychenko at the Institute of Geology and Geochemistry of Combustible Minerals of the Academy of Sciences of Ukraine on the basis of creative development of ideas of predecessors with the support of academicians Ye. K. Lazarenko, V. S. Sobolyev, H. N. Dolenko. Emphasis is placed on the contribution of schools to geological science, which is determined by the formed knowledge base on geochemical and thermobaric parameters of fluid environments of mineral-ore- naphthidogenesis in the Earth’s lithosphere (according to data of fluid inclusions research). In this context, in view of the enormous array of available data, the composition, physicochemical properties, genesis of fluids of the upper mantle and crust are briefly discussed and it is shown that the course of processes of petro-, mineral-, ore-, naphthidogenesis and formation fields of hydrocarbon, ore and non-ore minerals is determined by the peculiarities of degassing (defluidization) of the Earth and its influence on the conversion of carbon compounds during terrigenous, organogenic, hemogenic sedimentation and on the processes of diagenesis of sediments of various origins. The obtained data on the reproduction of the evolution of the fluid regime of rock complexes contribute to solving the fundamental problem of geochemistry of carbon and hydrogen (hydrocarbon-hydrogen matter) and deep (endogenous) fluid flows in the Earth’s lithosphere as an important basis for mineralofluidological model of the planet. They played a decisive role in substantiating at the Institute on the basis of abiogenic-biogenic dualism universal approaches to the processes of synthesis and genesis of natural hydrocarbons in the form of a new fundamental paradigm of oil and gas geology and geochemistry, the polygenesis of natural hydrocarbons in the Earth’s bowels, which increases the potential of oil and gas resources of promising regions, including Ukraine. This creates the preconditions for the identification of promising rock complexes for hydrocarbon, ore and non-ore minerals by applying the obtained fundamental thermobarogeochemical data in forecasting, exploration and operational practice on the basis of developing of new non-traditional geotechnologies for assessment and exploration of hydrocarbons and minerals.

Full Text

Keywords

fluid inclusions, geochemistry, thermobarometry, fluids, fluid media, mineral-ore-naphthidogenesis, Earth’s lithosphere.

REFERENCES

Bratus’, M. D., Davidenko, M. M., Zinchuk, I. M., Kalyuzhnyi, V. A., Matvienko, O. D., Naumko, I. M., Pirozhik, H. E., Red’ko, L. R., & Svoren’, Yo. M. (1994). Fluid regime in mineral formation in lithosphere (in relation to prognosis in prospecting for economic deposits), Fluid inclusion research: Proceedings оf COFFІ, USA, 27, 173–174.

Chekalyuk, E. B. (1980). Problema genezisa nefti s pozitsii geotermodinamiki. In Teoreticheskie voprosy neftegazovoi geologii (s. 13–20). Kiev: Naukova dumka. [in Russian]

Davidenko, N. M. (1992). Istochniki zolotonosnykh rossypei kriolitozony severo-vostoka Azii (po flyuidnym vklyucheniyam v mineralakh). Kiev: Naukova dumka. [in Russian]

Dolenko, G. N. (1986). Proiskhozhdenie nefti i gaza i neftegazonakoplenie v zemnoi kore. Kiev: Naukova dumka. [in Russian]

Ermakov, N. P. (1950). Issledovaniya mineraloobrazuyushchikh rastvorov (temperatury i agregatnoe sostoyanie). Khar’kov: Izdatel’stvo Khar’kovskogo universiteta. [in Russian]

Ermakov, N. P. (1972). Geokhimicheskie sistemy vklyuchenii v mineralakh (vklyucheniya mineraloobrazuyushchikh sred – istochnik geneticheskoi informatsii). Moskva: Nedra. [in Russian]

Ermakov, N. P., & Dolgov, Yu. A. (1979). Termobarogeokhimiya. Moskva: Nedra. [in Russian]

Kadik, A. A. (1986). Fraktsionirovanie letuchikh komponentov pri plavlenii verkhnei mantii. Geologiya i geofizika, 7, 70–73. [in Russian]

Kaliuzhnyi, V. A. (1960). Metody doslidzhennia bahatofazovykh vkliuchen u mineralakh. Kyiv: Vydavnytstvo AN URSR. [in Ukrainian]

Kaliuzhnyi, V. A. (Red.). (1971). Mineraloutvoriuiuchi fliuidy ta parahenezysy mineraliv pehmatytiv zanoryshevoho typu Ukrainy (ridki vkliuchennia, termobarometriia, heokhimiia). Kyiv: Naukova dumka. [in Ukrainian]

Kalyuzhnyi, V. A. (1982). Osnovy ucheniya o mineraloobrazuyushchikh flyuidakh. Kiev: Naukova dumka. [in Russian]

Kalyuzhnyi, V. A. (1983). Problemy issledovaniya endogennykh (mineraloobrazuyushchikh) flyuidov po vklyucheniyam v mineralakh. Geologiya i geokhimiya goryuchikh iskopaemykh, 2, 73–78. [in Russian]

Kalyuzhnyi, V. A. (1988). Osnovnye dostizheniya i perspektivy razvitiya ucheniya o mineraloobrazuyushchikh flyuidakh (voprosy termobarometrii i geokhimii rudoobrazuyushchikh flyuidov). In Geokhimiya i termobarometriya endogennykh flyuidov (s. 3–10). Kiev: Naukova dumka. [in Russian]

Khokha, Yu., Yakovenko, M., & Liubchak, O. (2019). Termodynamika transformatsii kerohenu II typu. Heolohiia i heokhimiia horiuchykh kopalyn, 3 (180), 25–40. [in Ukrainian]

Kovalevich, V. M. (1978). Fiziko-khimicheskie usloviya formirovaniya Stebnikskogo kaliinogo mestorozhdeniya. Kiev: Naukova dumka. [in Russian]

Kovalevich, V. M. (1990). Galogenez i khimicheskaya evolyutsiya okeana v fanerozoe. Kiev: Naukova dumka. [in Russian]

Kovalevich, V. M., Peryt, T. M., & Petrichenko, O. I. (1998). Secular variation in seawater chemistry during the Phanerozoic as indicated by brine inclusions in halite. Journal of Geology, 106, 695–712.

Kovalevych, V., Dudok, I., Poberezhskyi, A., Vovniuk, S., Halamai, A., Hryniv, S., Lytvyniuk, C., Sydor, D., & Yaremchuk, Ya. (2012). Khimiko-paleookeanohrafichni indykatory prohnozu pokladiv vuhlevodniv ta korysnykh kopalyn u vidkladakh kontynentalnykh okrain (za rezultatamy mineraloho-heokhimichnykh doslidzhen sulfatno-karbonatnykh i solenosnykh tovshch fanerozoiu Tsentralnoi i Skhidnoi Yevropy). Heolohiia i heokhimiia horiuchykh kopalyn, 3–4 (160–161), 66–81. [in Ukrainian]

Kovalishin, Z. I., & Bratus’, M. D. (1984). Flyuidnyi rezhim gidrotermal’nykh protsessov Zakarpat’ya. Kiev: Naukova dumka. [in Russian]

Lazarenko, E. K. (1979). Opyt geneticheskoi klassifikatsii mineralov. Kiev: Naukova dumka. [in Russian]

Liakhov, Yu., Matkovskyi, O., Pavlun, M., & Sivoronov, A. (2013). Profesor Mykola Porfirovych Yermakov – teoretyk i zasnovnyk novoi haluzi heolohichnykh znan – termobaroheokhimii (do 100-richchia vid dnia narodzhennia). Mineralohichnyi zbirnyk, 63 (2), 4–13. [in Ukrainian]

Lukin, A. E., & Pikovskii, Yu. I. (2004). O roli glubinnykh i sverkhglubinnykh flyuidov v nefteobrazovanii. Geologicheskii zhurnal, 2, 21–33. [in Russian]

Matkovskyi, O., Naumko, I., & Pavlun, M. (2017). Termobaroheokhimichna shkola profesora Mykoly Yermakova ta yii vnesok u rozvytok henetychnoi mineralohii y uchennia pro rodovyshcha korysnykh kopalyn. Mineralohichnyi zbirnyk, 67 (1), 3–37. [in Ukrainian]

Matkovskyi, O., Naumko, I., & Pavlun, M. (2018a). Etapy ta periody rozvytku termobaroheokhimichnykh doslidzhen v Ukraini. Mineralohichnyi zbirnyk, 68 (1), 129–134. [in Ukrainian]

Matkovskyi, O. I., Naumko, I. M., & Pavlun, M. M. (2018b). Termobaroheokhimiia v Ukraini. In Heolohiia i korysni kopalyny Ukrainy (s. 142–145). Kyiv: IHMR NAN Ukrainy. [in Ukrainian]

Naumko, I. M. (2006). Fliuidnyi rezhym mineralohenezu porodno-rudnykh kompleksiv Ukrainy (za vkliuchenniamy u mineralakh typovykh parahenezysiv). (Extended abstract of Doctorʼs thesis). Lviv. [in Ukrainian]

Naumko, I. (2011). Mineralofliuidolohiia v Instytuti heolohii i heokhimii horiuchykh kopalyn NAN Ukrainy. Heolohiia i heokhimiia horiuchykh kopalyn, 1–2 (154–155), 114–115. [in Ukrainian]

Naumko, I. (2017). Vnesok akademika Hryhoriia Nazarovycha Dolenka u rozvytok termobaroheokhimii–mineralofliuidolohii v Instytuti heolohii i heokhimii horiuchykh kopalyn. Heolohiia i heokhimiia horiuchykh kopalyn, 1–2 (170–171), 120–121. [in Ukrainian]

Naumko, I. (2019). Pro litofliuidotermodynamichnu systemu v heolohii i heokhimii. Heolohiia i heokhimiia horiuchykh kopalyn, 2 (179), 28–36. [in Ukrainian]

Naumko, I., Bratus, M., Dudok, I., Kaliuzhnyi, V., Kovalyshyn, Z., Sakhno, B., Svoren, Y., & Telepko, L. (2004). Fliuidnyi rezhym katahenno-hidrotermalnoho protsesu periodu formuvannia zhylnoi, prozhylkovoi i prozhylkovo-vkraplenoi mineralizatsii v osadovykh tovshchakh. In V. V. Kolodii (Red.), Karpatska naftohazonosna provintsiia (s. 308–345). Lviv; Kyiv: Ukrainskyi vydavnychyi tsentr. [in Ukrainian]

Naumko, I., Bratus, M., Zinchuk, I., Svoren, Y., Batsevych, N., Vovk, O., Zankovych, H., Redko, L., Sakhno, B., Beletska, Yu., Druchok, L., Matviishyn, Z., Telepko, L., Bondar, R., Brynskyi, T., Zubyk, M., Sava, N., & Stepaniuk, V. (2019). Letki spoluky fliuidnykh vkliuchen i zakrytykh por porid yak vazhlyvyi pokaznyk fliuidonasychenosti nadr (na prykladi porodno-rudnykh kompleksiv Ukrainy). In Heofizyka i heodynamika: prohnozuvannia ta monitorynh heolohichnoho seredovyshcha (s. 134–136). Lviv: Rastr-7. [in Ukrainian]

Naumko, І. М., Kovalyshyn, Z. I., Svoren’, J. M., Sakhno, B. Е., & Telepko, L. F. (1999). Towards forming conditions of veinlet mineralization in sedimentary oil- and gas- bearing layers of Carpathian region (obtained by data of fluid inclusions research). Геологія і геохімія горючих копалин, 3 (108), 83–91.

Naumko, І. М., Кurovets’, І. М., Zubyk, М. І., Batsevych, N. V., Sakhno, B. Е., & Chepusenko, P. S. (2017). Hydrocarbon compounds and plausible mechanism of gas generation in “shale” gas prospective Silurian deposits of Lviv Paleozoic depression. Geodynamics, 1 (22), 26–41.

Naumko, I. M., Pavliuk, M. I., Svoren, Y. M., & Zubyk, M. I. (2015). Metan hazovuhilnykh rodovyshch – potuzhne dodatkove dzherelo vuhlevodniv v Ukraini. Visnyk NAN Ukrainy, 6, 43–54. [in Ukrainian]

Naumko, I. M., Pavliuk, M. I., Svoren, Y. M., & Zubyk, M. I. (2016). Hazy vuhilnykh rodovyshch: nove vyrishennia problemy syntezu–henezysu metanu. Dopovidi NAN Ukrainy, 3, 61–68. https://doi.org/10.15407/dopovidi2016.03.061 [in Ukrainian]

Naumko, I. M., & Svoren’, I. M. (2003). O vazhnosti glubinnogo vysokotemperaturnogo flyuida v sozdanii uslovii dlya formirovaniya mestorozhdenii prirodnykh uglevodorodov v zemnoi kore. In Novye idei v naukakh o Zemle: Materialy VI Mezhdunarodnoi konferentsii (Moskva, 8–12 aprelya 2003 g.) (T. 1, s. 249). Moskva. [in Russian]

Naumko, І., & Svoren’, Yo. (2010). Abiogenic-biogenic bases of the genesis and synthesis of natural hydrocarbons in the Earth’s lithosphere (by fluid inclusions research). Geochimica et Cosmochimica Acta, 74 (11, Suppl. 1), A747.

Naumko, I., & Svoren, Y. (2014). Novi tekhnolohii poshukiv korysnykh kopalyn, osnovani na doslidzhenniakh fliuidnykh vkliuchen u mineralakh. V Aktual’nye problemy poiskovoi i ekologicheskoi geokhimii: Sbornik tezisov Mezhdunarodnoi nauchnoi konferentsii (Kiev, 1–2 iyulya 2014 g.) (s. 23–25). Kiev: Іnterservіs. [in Ukrainian]

Pavliuk, M. I. (2014). Heodynamichna evoliutsiia ta naftohazonosnit Azovo-Chornomorskoho i Barentsevomorskoho perykontynentalnykh shelfiv. Lviv: PROMAN. [in Ukrainian]

Pavliuk, M. I. (2017). Heotektonichna evoliutsiia i naftohazonosnyi potentsial Ukrainy (stenohrama naukovoi dopovidi na zasidanni Prezydii NAN Ukrainy 5 lypnia 2017 r.). Visnyk NAN Ukrainy, 9, 11–21. [in Ukrainian]

Pavlyshyn, V. I., Bondarenko, S. M., Bryk, O. B., Vozniak, D. K., Ilchenko, K. O., Kalinichenko, A. M., Kvasnytsia, V. M., Kulchytska, H. O., Lukashko, T. M., Naumko, I. M., Semenenko, V. P., Taran, M. M., Tarashchan, A. M., Khomenko, V. M., & Chernysh, D. S. (2018). Mineralohiia u Natsionalnii akademii nauk Ukrainy (do 100-richchia NAN Ukrainy). Mineralohichnyi zhurnal, 40 (3), 3–22. https://doi.org/10.15407/mineraljournal. 40.03.003 [in Ukrainian]

Pavlyuk, M. I., Varichev, S. A., & Rizun, B. P. (2003). Novye predstavleniya o genezise nefti i gaza i formirovanii neftegazonosnykh provinnii. In Genezis nefti i gaza (s. 441–442). Moskva: GEOS. [in Russian]

Petrichenko, O. I. (1977). Atlas mikrovklyuchenii v mineralakh galogennykh porod. Kiev: Naukova dumka. [in Russian]

Petrichenko, O. I. (1988). Fiziko-khimicheskie usloviya osadkoobrazovaniya v drevnikh solerodnykh basseinakh. Kiev: Naukova dumka. [in Russian]

Petrichenko, O. I. (1989). Epigenez evaporitov. Kiev: Naukova dumka. [in Russian]

Petrychenko, O. Y. (1973). Metody doslidzhennia vkliuchen u mineralakh halohennykh porid. Kyiv: Naukova dumka. [in Ukrainian]

Petrychenko, O., Kovalevych, V., Poberezhskyi, A., Vovniuk, S., Halamai, A., Dudok, I., Hryniv, S., Khmelevska, O., Sydor, D., Yaremchuk, Ya., Oliiovych, O., & Lytvyniuk, C. (2006). Vikovi zminy khimichnoho skladu okeanichnoi vody ta yikhnii vplyv na formuvannia halohennykh i bituminoznykh vidkladiv. Heolohiia i heokhimiia horiuchykh kopalyn, 3–4, 97–118. [in Ukrainian]

Poberezhskyi, A. V., & Kovalevych, V. M. (2001). Khimichnyi sklad morskoi vody v kainozoi (za rezultatamy doslidzhennia vkliuchen u sedymentatsiinomu haliti). Heolohiia i heokhimiia horiuchykh kopalyn, 2, 90–109. [in Ukrainian]

Roedder, E. (1984). Fluid inclusions. Reviews in Mineralogy (Vol. 12). Virginia: Mineralogical Society of America.

Shestopalov, V. M., Lukin, A. E., Zgonnik, V. A., Makarenko, A. N., Larin, N. V., & Boguslavskii, A. S. (2018). Ocherki degazatsii Zemli. Kiev. [in Russian]

Smit, F. G. (1956). Geologicheskaya termometriya po vklyucheniyam v mineralakh. Moskva: Izdatel’stvo inostrannoi literatury. [in Russian]

Sorby, H. C. (1858). On the Microscopic, Structure of Crystals, Indicating the Origin of Minerals and Rocks. Quarterly Journal of the Geological Society of London, 14 (1), 453–500. https://jgs.lyellcollection.org/content/14/1-2/453

Svoren, Y. M., & Naumko, I. M. (2006). Nova teoriia syntezu i henezysu pryrodnykh vuhlevodniv: abiohenno-biohennyi dualizm. Dopovidi NAN Ukrainy, 2, 111–116. [in Ukrainian]

Vovniuk, S., Halamai, A., Hryniv, S., Dudok, I., Maksymuk, S., Poberezhskyi, A., Sydor, D., & Yaremchuk, Ya. (2017). Heokhimichni kryterii zviazku evaporytovykh i osadovykh formatsii fanerozoiu ta pokladiv vuhlevodniv (na prykladi naftohazonosnykh baseiniv Tsentralnoi i Skhidnoi Yevropy). Heolohiia i heokhimiia horiuchykh kopalyn, 3–4 (172–173), 56–75. [in Ukrainian]

Vozniak, D. K. (2005). Rozvytok v Ukraini vchennia pro fliuidni vkliuchennia v mineralakh. Zapysky Ukrainskoho mineralohichnoho tovarystva, 2, 34–43. [in Ukrainian]

Vozniak, D. K., Kulchytska, H. O., Chernysh, D. S., & Belskyi, V. M. (2019). Nauka pro fliuidni vkliuchennia u mineralakh v Ukraini (do 100-richchia NAN Ukrainy). Mineralohichnyi zhurnal, 41 (1), 23–34. [in Ukrainian]

Vynar, O. M., Kaliuzhnyi, V. A., Naumko, I. M., & Matviienko, O. D. (1987). Mineraloutvoriuiuchi fliuidy postmahmatychnykh utvoren hranitoidiv Ukrainskoho shchyta. Kyiv: Naukova dumka. [in Ukrainian]

Zinchuk, I. N., Kalyuzhnyi, V. A., & Shchiritsa, A. S. (1984). Flyuidnyi rezhim mineraloobrazovaniya Tsentral’nogo Donbassa. Kiev: Naukova dumka. [in Russian]

Posted on December 2019May 2021 by GGCMJournal

BOWELS OF THE EARTH – NATURAL PHYSICAL-CHEMICAL REACTOR: IS THE SEARCH FOR NATURAL METHANE A FUNDAMENTAL SCIENCE OR A TECHNICAL PROBLEM?

Home > Archive > No. 4 (181) 2019 > 104-115

Geology & Geochemistry of Combustible Minerals No. 4 (181) 2019, 104-115.

https://doi.org/10.15407/ggcm2019.04.104

Yosyp Svoren
Institute of Geology and Geochemistry of Combustible Minerals of National Academy of Sciences of Ukraine, Lviv, Ukraine,
e-mail: igggk@mail.lviv.ua

Abstract

It is shown that the hypothesis of organic origin of hydrocarbons doesn’t respond to the presence of a dominant concentration of methane in sediments, deposits, “shale’ series and so on, hence prospecting and exploration for hydrocarbon deposits in them are conducted in most cases intuitively, but not on the fundamental scientific basis.

Experimental studies based on the heating of slightly modified organic matter (peat) show that up to 200 °C in the process of its decomposition the following gases were delivered (vol. %): CO₂ = 49.5; H₂O = 49.3; CH₄, C₂H₆, C₃H₈, N₂, H₂, SO₂, H₂S within 1.2 % in total.

It is confirmed that there is no coal methane, there is no shale gas-methane, but there is methane of one genesis with slightly different isotope composition of carbon, but synthesized according to the same mechanism in the high-thermobaric processes that after migration into the earth’s crust accumulated in the form of deposits in cavities of coal seams, terrigenous units, sandstones and so on.

Prospecting for pool-deposits of hydrocarbons should be carried out in conformity with developed “new technology of determination of prospects for oil and gas presence in the local area”, “physical-chemical model of synthesis of hydrocarbons and the way of geochemical searching for their occurrences”, “new theory of hydrocarbon synthesis and genesis in the earth’s lithosphere: abiogenic-biogenic dualism”.

Full Text

Keywords

fluid inclusions, minerals, methane, origin of hydrocarbons, exploration, pool-deposits, new technologies.

REFERENCES

Davydenko, M. M., & Svoren, Y. M. (1994). Sposib lokalnoho prohnozuvannia zbahachenykh dilianok zolotorudnykh poliv. Promyslova vlasnist. Ofitsiinyi biuleten, 3. [in Ukrainian]

Naumko, I. M. (2006). Fliuidnyi rezhym mineralohenezu porodno-rudnykh kompleksiv Ukrainy (za vkliuchenniamy u mineralakh typovykh parahenezysiv). (Extended abstract of Doctorʼs thesis). Instytut heolohii i heokhimii horiuchykh kopalyn NAN Ukrainy, Lviv. [in Ukrainian]

Naumko, I. M., Pavliuk, M. I., Svoren, I. M., Zubyk, M. I. (2016). Hazy vuhilnykh rodovyshch: nove vyrishennia problemy syntezu-henezysu metanu. Dopovidi NAN Ukrainy, 3, 61-68. [in Ukrainian]
https://doi.org/10.15407/dopovidi2016.03.061

Naumko, I. M., & Svoren, I. M. (2003). O vazhnosti glubinnogo vysokotemperaturnogo flyuida v sozdanii usloviy dlya formirovaniya mestorozhdeniy prirodnykh uglevodorodov v zemnoy kore. In Novyye idei v naukakh o Zemle: Materialy VI Mezhdunarodnoy konferentsii (Moskva. 8-12 aprelya 2003 g.) (T. 1. s. 249). Moskva. [in Russian]

Naumko, I., & Svoren, I. (2014). Novi tekhnolohii poshukiv korysnykh kopalyn, osnovani na doslidzhenniakh fliuidnykh vkliuchen u mineralakh. In Aktualnyye problemy poiskovoy i ekologicheskoy geokhimii: Sbornik tezisov Mezhdunarodnoy nauchnoy konferentsii (Kiyev. 1-2 iyulya 2014 g.) (s. 23-25). Kiev: Interservis. [in Ukrainian]

Svoren, I. M. (1984). Primesi gazov v kristallakh mineralov i drugikh tverdykh telakh, ikh sposoby izvlecheniya, sostav, forma nakhozhdeniya i vliyaniye na svoystva veshchestv. (Extended abstract of candidateʼs thesis). Institut geologii i geokhimii goryuchikh iskopayemykh AN USSR, Lvov. [in Russian]

Svoren, Y. M. (1992). Pytannia teorii henezysu pryrodnykh vuhlevodniv ta shliakhy poshuku yikh pokladiv. In Tektohenez i naftohazonosnist nadr Ukrainy: tezy dopovidei naukovoi narady (20-22 zhovtnia 1992 r.) (s. 143-145). Lviv. [in Ukrainian]

Svoren, Y. (2013). Termobarometriia ta heokhimiia haziv prozhylkovo-vkraplenoi mineralizatsii u vidkladakh naftohazonosnykh oblastei i metalohenichnykh provintsii: defekty v mineralakh – dzherelo informatsii pro protsesy mineraloutvorennia. Mineralohichnyi zbirnyk, 63 (2), 91-97. [in Ukrainian]

Svoren, Y. (2018). Vlastyvist hlybynnoho abiohennoho metanovmisnoho vysokotermobarnoho fliuidu utvoriuvaty vuhillia. Heolohiia i heokhimiia horiuchykh kopalyn, 3-4 (176-177), 105-109. [in Ukrainian]

Svoren, I. (2019). Pro novyi pidkhid do vyznachennia teplotvornosti pryrodnoho hazu, yakyi postachaiut spozhyvacham, ta yoho kubometrobarometriiu. Heolohiia i heokhimiia horiuchykh kopalyn, 2 (179), 84-89. [in Ukrainian]

Svoren, Y. M., & Davydenko, M. M. (1994). Sposib vyznachennia perspektyvy naftohazonosnosti lokalnoi ploshchi. Promyslova vlasnist. Ofitsiinyi biuleten, 4. [in Ukrainian]

Svoren, Y. M., Davydenko, M. M., Haievskyi, V. H., Krupskyi, Yu. Z., & Pelypchak, B. P. (1994). Perspektyvy termobarometrii i heokhimii haziv prozhylkovo-vkraplenoi mineralizatsii u vidkladakh naftohazonosnykh oblastei i metalohenichnykh provintsii (novyi naukovyi napriamok v heolohii). Heolohiia i heokhimiia horiuchykh kopalyn, 3-4 (88-89), 54-63. [in Ukrainian]

Svoren, Y. M., & Naumko, I. M. (2000). Nova tekhnolohiia vyznachennia henezysu vuhlevodnevykh haziv. In Nafta i haz Ukrainy (T. 1, s. 118). Ivano-Frankivsk: UNHA. [in Ukrainian]

Svoren, I. M., & Naumko, I. M. (2003). Rol adiabaticheskikh yavleniy v protsessakh nakopleniya-kontsentratsii i prevrashcheniya uglevodorodsoderzhashchikh veshchestv v litosfere Zemli. In Novyye idei v naukakh o Zemle: Materialy VI Mezhdunarodnoy konferentsii (Moskva. 8-12 aprelya 2003 g.) (T. 1. s. 257). Moskva. [in Russian]

Svoren, Y. M., & Naumko, I. M. (2006). Nova teoriia syntezu i henezysu pryrodnykh vuhlevodniv: abiohenno-biohennyi dualizm. Dopovidi NAN Ukrainy, 2, 111-116. [in Ukrainian]

Svoren, Y., & Naumko, I. (2012). Boryslavske vuhlevodneve rodovyshche: problemy dlia rozdumiv. In Stan, problemy ta perspektyvy naftohazovoi promyslovosti Ukrainy: Zbirnyk tez dopovidei Mizhnarodnoi naukovo-praktychnoi konferentsii (Lviv, 7-9 veresnia 2012 r.) (s. 16). Lviv: Vydavnytstvo Lvivskoi politekhniky. [in Ukrainian]

Svoren, I. M., Naumko, I. M., & Davydenko, M. M. (1998). Nova tekhnolohiia vyznachennia perspektyvy naftohazonosnosti lokalnoi ploshchi. In Nafta-Haz Ukrainy – 1998: Materialy V Mizhnarodnoi konferentsii (Poltava, 15-17 veresnia 1998 r.) (T. 1, s. 111-112). Poltava: UNHA. [in Ukrainian]

Svoren’, J. M., Naumko, І. М., Kovalyshyn, Z. I., Bratus’, M. D., & Davydenko, M. M. (1999). New technology of local forecast of enriched areas of gold ore fields. In Naukovi osnovy prohnozuvannia, poshukiv ta otsinky rodovyshch zolota: Materialy Mizhnarodnoi naukovoi konferentsii (Lviv, 27-30 veresnia 1999 r.) (s. 121-125). Lviv: Vydavnychyi tsentr LDU im. I. Franka.